Tunable Diode-Laser Spectroscopy With Wavelength Modulation: A Calibration-Free Approach to the Recovery of Absolute Gas Absorption Line Shapes
TL;DR: In this article, an alternative approach to tunable diode-laser spectroscopy with wavelength modulation is described, which offers the simplicity of signal analysis of direct detection while providing all the advantages of phase-sensitive electronic detection.
Abstract: The principles and implementation of an alternative approach to tunable diode-laser spectroscopy with wavelength modulation are described. This new technique uses the inherent phase shift between diode-laser power modulation and frequency modulation to separate the residual amplitude modulation and the first derivative signals recovered at the fundamental modulation frequency. The technique, through analysis of the residual-amplitude-modulation signal, is absolute, yielding gas-absorption-line-shape functions, concentrations, and pressures without the need for calibration under certain defined operating conditions. It offers the simplicity of signal analysis of direct detection while providing all the advantages of phase-sensitive electronic detection. Measurements of the 1650.96-nm rotation/vibration-absorption-line-shape function for 1% and 10% methane in nitrogen at various pressures are compared to theoretical predictions derived from HITRAN data, and the excellent agreement confirms the validity of the new technique. Further measurements of concentration and pressure confirm the efficacy of the technique for determining concentration in industrial-process environments where the pressure may be unknown and changing. An analysis of signal strength demonstrates that sensitivity comparable to that of conventional approaches is achievable. The new approach is simpler and more robust in coping with unknown pressure variations and drift in instrumentation parameters (such as laser characteristics) than the conventional approach. As such, it is better suited to stand-alone instrumentation for online deployment in industrial processes and is particularly useful in high-temperature applications, where the background infrared is strong.
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TL;DR: In this paper, a calibration-free wavelength-modulation spectroscopy with second harmonic detection (WMS-2f) for measurements of gas temperature and concentration in harsh environments is presented.
Abstract: We present a practical implementation of calibration-free wavelength-modulation spectroscopy with second harmonic detection (WMS-2f) for measurements of gas temperature and concentration in harsh environments. The method is applicable to measurements using lasers with synchronous wavelength and intensity modulation (such as injection current-tuned diode lasers). The key factors that enable measurements without the on-site calibration normally associated with WMS are (1) normalization of the WMS-2f signal by the first harmonic (1f) signal to account for laser intensity, and (2) the inclusion of laser-specific tuning characteristics in the spectral-absorption model that is used to compare with measured 1f-normalized, WMS-2f signals to infer gas properties. The uncertainties associated with the calibration-free WMS method are discussed, with particular emphasis on the influence of pressure and optical depth on the WMS signals. Many of these uncertainties are also applicable to calibrated WMS measurements. An example experimental setup that combines six tunable diode laser sources between 1.3 and 2.0 mum into one probe beam for measurements of temperature, H(2)O, and CO(2) is shown. A hybrid combination of wavelength and frequency demultiplexing is used to distinguish among the laser signals, and the optimal set of laser-modulation waveforms is presented. The system is demonstrated in the harsh environment of a ground-test scramjet combustor. A comparison of direct absorption and 1f-normalized, WMS-2f shows a factor of 4 increase in signal-to-noise ratio with the WMS technique for measurements of CO(2) in the supersonic flow. Multidimensional computational fluid-dynamics (CFD) calculations are compared with measurements of temperature and H(2)O using a simple method that accounts for the influence of line-of-sight (LOS) nonuniformity on the absorption measurements. The comparisons show the ability of the LOS calibration-free technique to gain useful information about multidimensional CFD models.
446 citations
TL;DR: In this paper, the fundamental concepts involved in various sensing approaches, and the differentiators which have led to commercial impact are discussed, as well as the future of fiber-optic sensors.
Abstract: Sensing via fiber optics has occupied R&D groups for over 40 years, and some important transitions into the commercial sector have been achieved. We look at the fundamental concepts involved in the various sensing approaches, and the differentiators which have led to commercial impact. We also look to the future of fiber-optic sensors.
372 citations
01 Jan 2009
TL;DR: Comparisons show the ability of the LOS calibration-free technique to gain useful information about multidimensional CFD models regarding temperature and H(2)O using a simple method that accounts for the influence of line-of-sight (LOS) nonuniformity on the absorption measurements.
Abstract: We present a practical implementation of calibration-free wavelength-modulation spectroscopy with second harmonic detection (WMS-2f) for measurements of gas temperature and concentration in harsh environments. The method is applicable to measurements using lasers with synchronous wavelength and intensity modulation (such as injection current-tuned diode lasers). The key factors that enable measurements without the on-site calibration normally associated with WMS are (1) normalization of the WMS-2f signal by the first harmonic (1f) signal to account for laser intensity, and (2) the inclusion of laser-specific tuning characteristics in the spectral-absorption model that is used to compare with measured 1f-normalized, WMS-2f signals to infer gas properties. The uncertainties associated with the calibration-free WMS method are discussed, with particular emphasis on the influence of pressure and optical depth on the WMS signals. Many of these uncertainties are also applicable to calibrated WMS measurements. An example experimental setup that combines six tunable diode laser sources between 1.3 and 2.0 mum into one probe beam for measurements of temperature, H(2)O, and CO(2) is shown. A hybrid combination of wavelength and frequency demultiplexing is used to distinguish among the laser signals, and the optimal set of laser-modulation waveforms is presented. The system is demonstrated in the harsh environment of a ground-test scramjet combustor. A comparison of direct absorption and 1f-normalized, WMS-2f shows a factor of 4 increase in signal-to-noise ratio with the WMS technique for measurements of CO(2) in the supersonic flow. Multidimensional computational fluid-dynamics (CFD) calculations are compared with measurements of temperature and H(2)O using a simple method that accounts for the influence of line-of-sight (LOS) nonuniformity on the absorption measurements. The comparisons show the ability of the LOS calibration-free technique to gain useful information about multidimensional CFD models.
329 citations
TL;DR: The development and initial demonstration of a scanned-wavelength, first-harmonic-normalized, wavelength-modulation spectroscopy with nf detection (scanned-WMS-nf/1f) strategy for calibration-free measurements of gas conditions are presented.
Abstract: The development and initial demonstration of a scanned-wavelength, first-harmonic-normalized, wavelength-modulation spectroscopy with nf detection (scanned-WMS-nf/1f) strategy for calibration-free measurements of gas conditions are presented. In this technique, the nominal wavelength of a modulated tunable diode laser (TDL) is scanned over an absorption transition to measure the corresponding scanned-WMS-nf/1f spectrum. Gas conditions are then inferred from least-squares fitting the simulated scanned-WMS-nf/1f spectrum to the measured scanned-WMS-nf/1f spectrum, in a manner that is analogous to widely used scanned-wavelength direct-absorption techniques. This scanned-WMS-nf/1f technique does not require prior knowledge of the transition linewidth for determination of gas properties. Furthermore, this technique can be used with any higher harmonic (i.e., n>1), modulation depth, and optical depth. Selection of the laser modulation index to maximize both signal strength and sensitivity to spectroscopic parameters (i.e., gas conditions), while mitigating distortion, is described. Last, this technique is demonstrated with two-color measurements in a well-characterized supersonic flow within the Stanford Expansion Tube. In this demonstration, two frequency-multiplexed telecommunication-grade TDLs near 1.4 μm were scanned at 12.5 kHz (i.e., measurement repetition rate of 25 kHz) and modulated at 637.5 and 825 kHz to determine the gas temperature, pressure, H2O mole fraction, velocity, and absorption transition lineshape. Measurements are shown to agree within uncertainty (1%–5%) of expected values.
186 citations
TL;DR: Tunable diode laser absorption spectroscopy (TDLAS) has become a proven method of rapid gas diagnostics as mentioned in this paper, and the state of the art of TDL-based sensors and their applications for measurements of temperature, pressure, and species concentrations of gas components in harsh environments is given.
165 citations
References
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Harvard University1, University of Reims Champagne-Ardenne2, College of William & Mary3, Old Dominion University4, University of Lisbon5, University of Burgundy6, California Institute of Technology7, Centre national de la recherche scientifique8, Université catholique de Louvain9, University of York10, University College London11, National Institute of Standards and Technology12, University of Waterloo13, National Center for Atmospheric Research14, University of Cologne15, Karlsruhe Institute of Technology16, Langley Research Center17
TL;DR: The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity, and molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth.
Abstract: This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity. Moreover, molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth. Of considerable note, experimental IR cross-sections for almost 300 additional molecules important in different areas of atmospheric science have been added to the database. The compilation can be accessed through www.hitran.org. Most of the HITRAN data have now been cast into an underlying relational database structure that offers many advantages over the long-standing sequential text-based structure. The new structure empowers the user in many ways. It enables the incorporation of an extended set of fundamental parameters per transition, sophisticated line-shape formalisms, easy user-defined output formats, and very convenient searching, filtering, and plotting of data. A powerful application programming interface making use of structured query language (SQL) features for higher-level applications of HITRAN is also provided.
7,638 citations
"Tunable Diode-Laser Spectroscopy Wi..." refers background in this paper
..., from the HITRAN database [35]) to the measured absolute absorption-line function....
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TL;DR: In this paper, a series of experiments are carried out by current modulating a tunable diode laser, and slowly ramping the wavelength to scan weak absorption lines in gases at pressures ranging from 2 to 60 Torr.
Abstract: A series of experiments are carried out by current modulating a tunable diode laser, and slowly ramping the wavelength to scan weak absorption lines in gases at pressures ranging from 2 to 60 Torr. A lock-in amplifier detects the second harmonic (2f) of the modulation frequency, and the experimental 2f signals are compared with theory. Detailed measurements are made on Lorentzian, Voigt, and Gaussian line profiles, over a wide range of modulation amplitudes. Excellent agreement between experiment and calculation is obtained in all cases. This quantitative understanding enables one to derive true lineshapes and linewidths of very weak absorption lines from measurements of 2f lineshapes only. Results are applicable to trace gas detection using tunable diode lasers, and to other areas of spectroscopy and magnetic resonance where harmonic detection techniques are routinely employed to monitor weak signals.
624 citations
"Tunable Diode-Laser Spectroscopy Wi..." refers background or methods in this paper
...In practice, modulation indexes greater than unity are used to maximize the recovered signals, bringing all the consequences of more complex signal analysis [20]–[24], [28]....
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...on Fourier decomposition of the absorption-line function have been developed to deal with such large modulation indexes (m) [20]–[22], [24], [28] and later extensions take account of the effects of unwanted RAM signals [22], [28] and etalon fringes [24]....
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...TDLS with wavelength-modulation spectroscopy (WMS) enables ac detection at some frequency of choice and the use of a lockin amplifier for better signal recovery [7]–[12], [20]–[28]....
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TL;DR: In this paper, the main features and applications of tunable diode laser absorption spectroscopy are reviewed and the main characteristics of the currently available semiconductor diode lasers with respect to spectroscopic applications and sensitive detection techniques are discussed.
473 citations
Additional excerpts
...[15] P. Werle, “A review of recent advances in semiconductor laser based gas monitors,” Spectrochim....
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...Furthermore, the laser and detector components developed for communications systems are fully compatible with single-mode optical fiber, and this has been exploited to remotely address multiplesensing points over single-mode optical-fiber networks [13], [14] (a useful review of work in the field prior to 1998 was published by Werle [15])....
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TL;DR: In this paper, the frequency modulation characteristics of three different AlGaAs lasers, a channeled-substrate planar (CSP), a buried-heterostructure (BH) and a transverse-junction-stripe (TJS) laser, were studied theoretically and experimentally.
Abstract: Direct frequency modulation characteristics in three different AlGaAs lasers-a channeled-substrate planar (CSP) laser, a buried-heterostructure (BH) laser, and a transverse-junction-stripe (TJS) laserare studied theoretically and experimentally. Experimental FM responses are measured by using the Fabry-Perot interferometer and birefringent optical filters in the 0-5.2 GHz modulation frequency region. Experimental FM response dependences on modulation frequency, dc bias level, and stripe structure are successfully explained by the theoretical analyses considering both the carrier density modulation effect and the temperature change effect. FM response in the low modulation frequency regin from 0 to 10 MHz, gradually decreasing with the modulation frequency, stems from the thermal effect. FM response in the high modulation frequency region from 10 MHz to 5.2 GHz is caused by the carrier effect. A flat FM response of several hundred MHz per 1 mA is observed in the CSP and TJS lasers, but a V-shaped FM response is obtained in the BH laser. Resonance peak due to relaxation oscillation and cutoff characteristics are observed in several gigahertz regions. Weak lateral mode confinement, strong vertical mode confinement, carrier injection outside the effective core region, and p-side down mounts are effective ways to achieve a flat and efficient FM response with a small spurious intensity modulation.
438 citations
TL;DR: Both of the FMS methods, which require modulating the laser at frequencies >/= 150 MHz, give relatively poor results due to inefficient coupling of the modulation waveform to the laser current, and the re ults obtained agree well with theory.
Abstract: Wavelength modulation spectroscopy (WMS) and one-tone and two-tone frequency modulation spectroscopy (FMS) are compared by measuring the minimum detectable absorbances achieved using a mid-IR lead-salt diode laser. The range of modulation and detection frequencies spans over 5 orders of magnitude. The best results, absorbances in the low-to-mid 10−7 range in a 1-Hz bandwidth, are obtained by using high-frequency WMS (10-MHz detection frequency) and are limited by detector thermal noise. This sensitivity can provide species detection limits well below 1 part per billion for molecules with moderate line strengths if multiple-pass cells are used. High-frequency WMS is also tested by measuring the absorbance due to tropospheric N2O at 1243.795 cm−1. WMS at frequencies <100 kHz is limited by laser excess (1/f) noise. Both of the FMS methods, which require modulating the laser at frequencies ≥150 MHz, give relatively poor results due to inefficient coupling of the modulation waveform to the laser current. The results obtained agree well with theory. We also discuss the sensitivity limitations due to interference fringes from unintentional etalons and the effectiveness of etalon reduction schemes.
378 citations
"Tunable Diode-Laser Spectroscopy Wi..." refers methods in this paper
...The technique was first developed using mid-infrared (IR) lasers [1]–[6] to address strong fundamental rotation/vibration absorption lines, but the...
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