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Ultracapacitors: Why, How, and Where is the Technology

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TLDR
In this paper, the authors compared the power density characteristics of ultracapacitors and batteries with respect to the same charge/discharge efficiency, and showed that the battery can achieve energy densities of 10 Wh/kg or higher with a power density of 1.2 kW/kg.
Abstract
The science and technology of ultracapacitors are reviewed for a number of electrode materials, including carbon, mixed metal oxides, and conducting polymers. More work has been done using microporous carbons than with the other materials and most of the commercially available devices use carbon electrodes and an organic electrolytes. The energy density of these devices is 3¯5 Wh/kg with a power density of 300¯500 W/kg for high efficiency (90¯95%) charge/discharges. Projections of future developments using carbon indicate that energy densities of 10 Wh/kg or higher are likely with power densities of 1¯2 kW/kg. A key problem in the fabrication of these advanced devices is the bonding of the thin electrodes to a current collector such the contact resistance is less than 0.1 cm2. Special attention is given in the paper to comparing the power density characteristics of ultracapacitors and batteries. The comparisons should be made at the same charge/discharge efficiency.

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Citations
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Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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A review of electrode materials for electrochemical supercapacitors

TL;DR: Two important future research directions are indicated and summarized, based on results published in the literature: the development of composite and nanostructured ES materials to overcome the major challenge posed by the low energy density.
Journal ArticleDOI

Graphene-Based Ultracapacitors

TL;DR: CMG materials are made from 1-atom thick sheets of carbon, functionalized as needed, and here their performance in an ultracapacitor cell is demonstrated, illustrating the exciting potential for high performance, electrical energy storage devices based on this new class of carbon material.
Journal ArticleDOI

Carbon-based materials as supercapacitor electrodes

TL;DR: This tutorial review provides a brief summary of recent research progress on carbon-based electrode materials forsupercapacitors, as well as the importance of electrolytes in the development of supercapacitor technology.
Journal ArticleDOI

Carbon properties and their role in supercapacitors

TL;DR: Supercapacitors are able to store and deliver energy at relatively high rates (beyond those accessible with batteries) because the mechanism of energy storage is simple charge-separation (as in conventional capacitors) as discussed by the authors.
References
More filters
Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
Journal ArticleDOI

A review of electrode materials for electrochemical supercapacitors

TL;DR: Two important future research directions are indicated and summarized, based on results published in the literature: the development of composite and nanostructured ES materials to overcome the major challenge posed by the low energy density.
Journal ArticleDOI

Graphene-Based Ultracapacitors

TL;DR: CMG materials are made from 1-atom thick sheets of carbon, functionalized as needed, and here their performance in an ultracapacitor cell is demonstrated, illustrating the exciting potential for high performance, electrical energy storage devices based on this new class of carbon material.
Journal ArticleDOI

Carbon-based materials as supercapacitor electrodes

TL;DR: This tutorial review provides a brief summary of recent research progress on carbon-based electrode materials forsupercapacitors, as well as the importance of electrolytes in the development of supercapacitor technology.
Book

Electrochemical Supercapacitors : Scientific Fundamentals and Technological Applications

TL;DR: In this paper, the double-layer and surface functionalities at Carbon were investigated and the double layer at Capacitor Electrode Interfaces: its structure and Capacitance.