Ultralight, super-elastic and volume-preserving cellulose fiber/graphene aerogel for high-performance electromagnetic interference shielding
TL;DR: In this paper, the effects of RGO content and annealing conditions on EMI shielding and mechanical properties were investigated, and the results demonstrate a promising and facile approach to fabricate low-cost and volume-preserving porous carbon material with superior and tunable electromagnetic interference shielding performance for potential applications in aerospace and wearable electronic devices.
About: This article is published in Carbon.The article was published on 2017-05-01. It has received 212 citations till now. The article focuses on the topics: Electromagnetic shielding & Aerogel.
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TL;DR: In this article, the authors discussed the factors of microstructural defects, filler concentration, filler alignment, filler inherent conductivity and the surrounding temperature of carbon nanostructures and their composites.
531 citations
TL;DR: In this paper, the authors systematically combed the structures and electromagnetic functions of graphene hybrids, and demonstrated the advances in the microwave response mechanism, including relaxation, charge transport, magnetic resonance, and eddy currents, as well as magnetic-dielectric synergistic effects.
Abstract: Graphene has been long sought-after over the past few decades because of its multiple functions and broad applications in various fields, such as energy, information, medicine, military equipments, and aerospace. In particular, it has been significantly reported in electromagnetic wave absorbing and shielding fields, promoting it as the most cutting-edge topic. Herein, we systematically comb the structures and electromagnetic functions of graphene hybrids. We demonstrate the advances in the microwave response mechanism, including relaxation, charge transport, magnetic resonance, and eddy currents, as well as magnetic-dielectric synergistic effects. Furthermore, our review mainly focuses on graphene-dispersed systems, flexible graphene papers, graphene hybrids, and 3D graphene architectures.
468 citations
TL;DR: In this paper, the cellulose carbon aerogel@reduced graphene oxide aerogels (CCA@rGO) and polydimethylsiloxane (PDMS) EMI shielding composites are prepared by backfilling with PDMS.
Abstract: In order to ensure the operational reliability and information security of sophisticated electronic components and to protect human health, efficient electromagnetic interference (EMI) shielding materials are required to attenuate electromagnetic wave energy. In this work, the cellulose solution is obtained by dissolving cotton through hydrogen bond driving self-assembly using sodium hydroxide (NaOH)/urea solution, and cellulose aerogels (CA) are prepared by gelation and freeze-drying. Then, the cellulose carbon aerogel@reduced graphene oxide aerogels (CCA@rGO) are prepared by vacuum impregnation, freeze-drying followed by thermal annealing, and finally, the CCA@rGO/polydimethylsiloxane (PDMS) EMI shielding composites are prepared by backfilling with PDMS. Owing to skin-core structure of CCA@rGO, the complete three-dimensional (3D) double-layer conductive network can be successfully constructed. When the loading of CCA@rGO is 3.05 wt%, CCA@rGO/PDMS EMI shielding composites have an excellent EMI shielding effectiveness (EMI SE) of 51 dB, which is 3.9 times higher than that of the co-blended CCA/rGO/PDMS EMI shielding composites (13 dB) with the same loading of fillers. At this time, the CCA@rGO/PDMS EMI shielding composites have excellent thermal stability (THRI of 178.3 °C) and good thermal conductivity coefficient (λ of 0.65 W m-1 K-1). Excellent comprehensive performance makes CCA@rGO/PDMS EMI shielding composites great prospect for applications in lightweight, flexible EMI shielding composites.
381 citations
TL;DR: The achieved performance illustrates that the as-prepared porous Co-C core-shell composite shows considerable potential as an effective microwave absorber.
Abstract: The combination of carbon materials and ferrite materials has recently attracted increased interest in microwave absorption applications. Herein, a novel composite with cobalt cores encapsulated in a porous carbon shell was synthesized via a facile sintering process with a cobaltic metal–organic framework (Co-MOF-74) as the precursor. Because of the magnetic loss caused by the Co cores and dielectric loss caused by the carbon shell with a unique porous structure, together with the interfacial polarization between two components, the ferromagnetic composite exhibited enhanced electromagnetic wave absorption performance compared to traditional ferrite materials. With the thermal decomposition temperature of 800 °C, the optimal reflection loss value achieved −62.12 dB at 11.85 GHz with thin thickness (2.4 mm), and the bandwidth ranged from 4.1 to 18 GHz with more than 90% of the microwave that could be absorbed. The achieved performance illustrates that the as-prepared porous Co–C core–shell composite shows ...
313 citations
TL;DR: In this article, the synthesis and EMI shielding performances of carbon-based materials in X-band (8.2-12.4 GHz) have been reviewed and their shielding mechanisms are discussed.
306 citations
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26,456 citations
TL;DR: The direct synthesis of three-dimensional foam-like graphene macrostructures, which are called graphene foams (GFs), by template-directed chemical vapour deposition is reported, demonstrating the great potential of GF/poly(dimethyl siloxane) composites for flexible, foldable and stretchable conductors.
Abstract: [Chen, Zongping; Ren, Wencai; Gao, Libo; Liu, Bilu; Pei, Songfeng; Cheng, Hui-Ming] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China.;Cheng, HM (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China;cheng@imr.ac.cn
3,517 citations
TL;DR: The mechanical flexibility and easy coating capability offered by MXenes and their composites enable them to shield surfaces of any shape while providing high EMI shielding efficiency.
Abstract: Materials with good flexibility and high conductivity that can provide electromagnetic interference (EMI) shielding with minimal thickness are highly desirable, especially if they can be easily processed into films. Two-dimensional metal carbides and nitrides, known as MXenes, combine metallic conductivity and hydrophilic surfaces. Here, we demonstrate the potential of several MXenes and their polymer composites for EMI shielding. A 45-micrometer-thick Ti3C2Tx film exhibited EMI shielding effectiveness of 92 decibels (>50 decibels for a 2.5-micrometer film), which is the highest among synthetic materials of comparable thickness produced to date. This performance originates from the excellent electrical conductivity of Ti3C2Tx films (4600 Siemens per centimeter) and multiple internal reflections from Ti3C2Tx flakes in free-standing films. The mechanical flexibility and easy coating capability offered by MXenes and their composites enable them to shield surfaces of any shape while providing high EMI shielding efficiency.
3,251 citations
TL;DR: Graphene platelets significantly out-perform carbon nanotube additives in terms of mechanical properties enhancement, and may be related to their high specific surface area, enhanced nanofiller-matrix adhesion/interlocking arising from their wrinkled (rough) surface, as well as the two-dimensional geometry of graphene platelets.
Abstract: In this study, the mechanical properties of epoxy nanocomposites with graphene platelets, single-walled carbon nanotubes, and multi-walled carbon nanotube additives were compared at a nanofiller weight fraction of 0.1 ± 0.002%. The mechanical properties measured were the Young’s modulus, ultimate tensile strength, fracture toughness, fracture energy, and the material’s resistance to fatigue crack propagation. The results indicate that graphene platelets significantly out-perform carbon nanotube additives. The Young’s modulus of the graphene nanocomposite was ∼31% greater than the pristine epoxy as compared to ∼3% increase for single-walled carbon nanotubes. The tensile strength of the baseline epoxy was enhanced by ∼40% with graphene platelets compared to ∼14% improvement for multi-walled carbon nanotubes. The mode I fracture toughness of the nanocomposite with graphene platelets showed ∼53% increase over the epoxy compared to ∼20% improvement for multi-walled carbon nanotubes. The fatigue resistance resu...
2,367 citations
TL;DR: All carbon aerogels with ultralow density and temperature-invariant super-elasticity are fabricated by facile assembling of commercial carbon nanotubes and chemically-converted giant graphene sheets, on the basis of the synergistic effect between elastic CNTs ribs and giant graphene cell walls.
Abstract: All carbon aerogels (up to 1000 cm(3)) with ultralow density (down to 0.16 mg cm(-3)) and temperature-invariant (-190-900 °C) super-elasticity are fabricated by facile assembling of commercial carbon nanotubes (CNTs) and chemically-converted giant graphene sheets, on the basis of the synergistic effect between elastic CNTs ribs and giant graphene cell walls.
1,680 citations