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Journal ArticleDOI

Understanding the influence of water droplet initiated discharges on damage caused to corona-aged silicone rubber

TL;DR: In this paper, surface charge accumulation studies indicate that the charge retention capability of the insulating material gets reduced drastically with silicone rubber damaged due to corona, causing degradation of surface.
Abstract: Corona activity on the surface of silicone rubber has high impact on variation in hydrophobicity of the material, and on corona inception voltage (CIV) of water droplet sitting on the corona degraded surface. The CIV is high under negative DC as compared to positive DC/AC voltages. Increase in conductivity of water droplet reduces CIV. Surface charge accumulation studies indicate that the charge retention capability of the insulating material gets reduced drastically with silicone rubber damaged due to corona causing degradation of surface. Irrespective of the number of cycles of corona discharge activities carried out, the time constant of charge decay, after the removal of charge injection, remains the same. The water droplet initiated discharges under AC and DC voltages radiate UHF signal in the bandwidth 0.3–1.2 GHz. With single droplet sitting on top of the corona damaged silicone rubber, the amount of charge retained by the water droplet is low when the droplet is placed and charged immediately after corona discharge activity to surface of the insulating material. When the water droplet is placed after a certain time period, the charge accumulation characteristics of silicone rubber are regained. Leakage current measured during water droplet discharge studies through recurrent plot (RP) analysis reveals that, under AC voltage, it is possible to classify corona inception, arcing and bridging of water droplet between high voltage and ground electrode. The RP obtained for the current signals generated due to water droplet discharges under positive and negative DC voltages are different. The amount of damage caused to silicone rubber due to water droplet is high under negative DC voltage as compared to positive/AC voltages. While correlating the level of damage to the insulating material due to water droplet and the RQA parameters of RP, it is observed that higher the recurrence rate along with high determinism can cause severe damage to the insulating material. Structural analysis using ATR-FTIR and pyrolysis-GC/MS studies reveal significant functional group variation on surface of silicone rubber, especially when the number of cycles of corona ageing is more.
Citations
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Journal ArticleDOI
TL;DR: In this article, an epoxy nano passivated aluminium composites with optimised size and filler contents were fabricated and shown to show a drastic reduction on corona ageing. But the reduction in corona aging was not due to the increase in the filler content, but due to a reduction in the contact angle and surface roughness.
Abstract: Epoxy nano passivated aluminium composites with optimised size and filler contents were fabricated. Variation in contact angle and surface roughness is insignificant with increasing filler into nanocomposites but it showed a drastic reduction on corona ageing. Water droplet initiated corona inception voltage (CIV) is high under the negative DC voltage followed with positive DC and AC voltages. The bandwidth of ultra-high frequency signal generated due to water droplet initiated corona discharge lies in the range of 0.5–1.2 GHz. Surface potential measurements have shown that the decay in the potential was fast initially, and it became slower and sluggish subsequently. The trap energy density versus trap depth plot exhibits shallow traps and deep traps at around 0.8 and 0.87 eV, respectively. Permittivity, conductivity and loss factor have increased with an increase in the filler content in nanocomposites. The bulk resistance and capacitance of samples were determined for obtaining the equivalent parallel RC circuit model. Incorporation of nanofillers increases the glass transition temperature and reduces the tan δ with increasing frequencies as evident from dynamic mechanical analysis studies. A direct correlation is observed between the plasma temperature measured through laser-induced breakdown spectroscopy spectra and hardness of the material.

8 citations

Journal ArticleDOI
02 Apr 2020
TL;DR: In this article, the authors proposed to improve insulation properties of silicone rubber by adding an optimised quantity of nanofillers, where the fundamental space charge and charge trap characteristics were studied by adopting the pulsed electroacoustic analysis technique and through surface potential measurement.
Abstract: Silicone rubber is widely used for electrical insulation and may be exposed to a harsh environment. The present study envisaged to improve insulation properties of silicone rubber by adding an optimised quantity of nanofillers. The fundamental space charge and charge trap characteristics were studied by adopting the pulsed electroacoustic analysis technique and through surface potential measurement. The dielectric properties of the materials were analysed through measurement of permittivity and loss factor of the material at different frequencies and temperatures. The influence of gamma irradiation on variations in fundamental properties of the material was characterised. The results of the study indicate that 5 wt.% alumina added nanocomposites had better space charge performance under gamma irradiation compared with virgin silicone rubber.

7 citations

Journal ArticleDOI
TL;DR: In this article, a solar-blind ultraviolet imager was used to evaluate the corona inception voltage and flashover voltage of water droplets on a 110-kV composite insulator and found that the relative permittivity of the water droplet decreases with the increase of the conductivity and then reduces the electric field intensity.
Abstract: Water droplets on the surface of insulators can distort the electric field and cause the generation of surface partial discharge or flashover. In this study, the inception and the development of surface partial discharges on a 110 kV composite insulator were evaluated by using a solar-blind ultraviolet imager. Several experiments were conducted by using water droplets differing in volume, conductivity, and position on an insulator housing. The results showed that the corona inception voltage decreases with the increasing volume of the water droplets. The relative permittivity of the water droplet decreases with the increase of the conductivity and then reduces the electric field intensity and increases the corona inception voltage. Installing the grading ring can increase the value of the corona inception voltage by 38% at most. To investigate the influence of the water droplets on the corona inception characteristics of the insulator, the sheath and shed models were proposed according to the feature of the electric field distribution. By changing the parameters of the water droplets, the corona inception voltage, discharge position, and electric field were analysed. Furthermore, the flashover voltage of the water droplets is influenced by its conductivity, while the corona inception voltage by its relative permittivity.

7 citations

Journal ArticleDOI
18 Jul 2019-Energies
TL;DR: In this article, an experimental procedure is established to evaluate long-term surface erosion caused only by partial discharge, where silicone rubber is subjected to partial discharge for 8 h using an electrode system with air gap. Voltage application is stopped for subsequent 16 h for recovery of hydrophobicity.
Abstract: This paper reports experimental and analytical results of partial discharge degradation of silicone rubber sheets in accordance with proposed procedures. Considering the actual usage condition of silicone rubber as an insulating material of polymer insulators, an experimental procedure is established to evaluate long-term surface erosion caused only by partial discharge. Silicone rubber is subjected to partial discharge for 8 h using an electrode system with air gap. Voltage application is stopped for subsequent 16 h for recovery of hydrophobicity. The 24 h cycle is repeated 50 or 100 times. Deterioration of sample surface is evaluated in terms of contact angle and surface roughness. It is confirmed the proposed experimental procedure has advantage of no arc discharge occurrence, good repeatability of results, and possible acceleration of erosion. Surface erosion of silicone rubber progresses gradually and finally breakdown of silicone rubber occurs. Alumina trihydrate (ATH), an additive to avoid tracking and erosion by discharge, is not necessarily effective to prevent breakdown caused by partial discharge when localized electric field in air is enhanced by adding ATH. In such a situation, lower permittivity and higher resistance of silicone rubber seem dominant factors to prevent partial discharge breakdown and a careful insulation design should be required.

4 citations


Additional excerpts

  • ...silicone rubber/water droplet/air [3,4]....

    [...]

Proceedings ArticleDOI
01 Dec 2018
TL;DR: Results indicate that surface potential and its decay time constant reduces drastically after the corona ageing, as compared to the virgin specimen, however, the test specimens regain their hydrophobicity, though at a different rate, with time.
Abstract: Surface hydrophobicity recovery of silicone rubber insulating material post corona ageing is reported in the present work. Recovery rate of hydrophobicity of uncleaned (S1) and cleaned sample (S2) after the corona ageing are compared. Results indicate that surface potential and its decay time constant reduces drastically after the corona ageing, as compared to the virgin specimen. However, the test specimens regain their hydrophobicity, though at a different rate, with time. Trap distribution characteristic shows that the characteristic time and charge trap depth reduces with the corona aged specimens and regain with rest period. A similar trend is observed with contact angle and corona inception voltage (CIV) of the test specimens. Pattern classification of Ultra High Frequency (UHF) discharge signal is done using modified Chaotic Analysis (CA).

3 citations

References
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Journal ArticleDOI
01 Mar 2001-Polymer
TL;DR: In this paper, a combination of traditional kinetic formal treatments and computer simulation has been made to analyze polydimethylsiloxane (PDMS) thermal degradation, and it was shown that PDMS thermally decomposes to cyclic oligomers through Si-O bond scission in a chain-folded cyclic conformation energetically favored by overlapping of empty silicon d-orbitals with orbitals of oxygen and carbon atoms.

635 citations

Journal ArticleDOI
01 Mar 2002-Polymer
TL;DR: In this paper, the products of the thermal degradation of polydimethylsiloxane (PDMS) are determined by the heating conditions, since two competing mechanisms are involved: molecular splitting of oligomers from loop conformations of the PDMS chain and assistance on the part of empty silicon d-orbitals.

430 citations

Journal ArticleDOI
01 May 1998-Polymer
TL;DR: In this paper, contact angle measurements of a high-temperature-vulcanized polydimethylsiloxane (PDMS) elastomer have been obtained for different periods of time in dry air.

406 citations

Journal ArticleDOI
TL;DR: In this article, the evolution of volatile materials from pure poly(dimethylsiloxane) heated under temperature programmed conditions (10° min−1 under vacuum) is detectable at 343° and reaches a maximum at 443°.

347 citations

Journal ArticleDOI
TL;DR: In this article, a critical evaluation of the chemical and physical mechanisms responsible for hydrophobicity loss and recovery is presented, where the authors evaluate the properties of silicone rubbers based on polydimethylsiloxane (PDMS).
Abstract: Water repellency, high surface resistivity, vandalism resistance, low density and good processability have made silicone rubbers based on polydimethylsiloxane (PDMS) very attractive materials in housings for outdoor insulation. Their ability to recover hydrophobicity after oxida. tion or contamination is of paramount importance and this is the topic of this review. A critical evaluation of the chemical and physical mechanisms responsible for hydrophobicity loss and recovery is presented.

318 citations