Utilization of sewage sludge in EU application of old and new methods—A review
TL;DR: In this article, the authors review past and future trends in sludge handling, focusing mainly at thermal processes (e.g. pyrolysis, wet oxidation, gasification) and the utilization of sewage sludge in cement manufacture as a co-fuel.
Abstract: The European Union has made progress in dealing with municipal wastewater in individual countries and as a corporate entity. However, it intends to make still further and substantial progress over the next 15 years. Currently, the most widely available options in the EU are the agriculture utilization, the waste disposal sites, the land reclamation and restoration, the incineration and other novel uses. The selection of an option on a local basis reflects local or national, cultural, historical, geographical, legal, political and economic circumstances. The degree of flexibility varies from country to country. In any case sludge treatment and disposal should always be considered as an integral part of treatment of wastewater. There is a wide range of other uses for sludge, which exploit its energy or chemical content, namely the thermal processes. The present paper sought to review past and future trends in sludge handling, focusing mainly at thermal processes (e.g. pyrolysis, wet oxidation, gasification) and the utilization of sewage sludge in cement manufacture as a co-fuel.
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TL;DR: In this paper, an overview of the use of biochar in the immobilization of heavy metal (HM)-contaminated soils to reduce HM bioavailability to plants is presented, including the specific soil HM immobilization mechanisms, longterm beneficial effects, and potential environmental risks associated with BC application.
118 citations
TL;DR: Results showed that organic matter, including both of particulateorganic matter (POM) and dissolved organic matter (DOM) were critical factors influencing heavy metal leaching from both of SSC and the soil.
118 citations
Cites background from "Utilization of sewage sludge in EU ..."
...Sewage sludge containing plant nutrients and humic substances can be reused as fertilizer or soil amendments for land application after composting [1, 2]....
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TL;DR: In this paper, a review of the potential advantages and pitfalls associated with the application of alkali-activation technology to a wide variety of wastes that have been claimed to be suitable for the production of construction materials is presented.
Abstract: There is growing global interest in maximising the re-use and recycling of waste, to minimise the environmental impacts associated with waste treatment and disposal. Use of high-volume wastes in the production of blended or novel cements (including alkali-activated cements) is well known as a key pathway by which these wastes can be re-used. This paper presents a critical overview of the urban, agricultural, mining and industrial wastes that have been identified as potential precursors for the production of alkali-activated cement materials, or that can be effectively stabilised/solidified via alkali activation, to assure their safe disposal. The central aim of this review is to elucidate the potential advantages and pitfalls associated with the application of alkali-activation technology to a wide variety of wastes that have been claimed to be suitable for the production of construction materials. A brief overview of the generation and characteristics of each waste is reported, accompanied by identification of opportunities for the use of alkali-activation technology for their valorisation and/or management. © 2016 Society of Chemical Industry
118 citations
TL;DR: In this article, non-isothermal thermogravimetric data were used to assess the kinetics of the combustion of these carbonaceous materials and the activation energy related to AM combustion was similar to that corresponding to sewage sludge (SS), animal manure (AM) and organic fraction of municipal solid waste (OFMSW).
116 citations
TL;DR: In this paper, the main oxides in sewage sludge are SiO2 (10−25 %), Al2O3 (5−10 %) and CaO(10−30 %) which are increased in sludge ash after incineration to 25−50 %, 10−20 % and 15−30 percent.
Abstract: With increasing amount of sewage sludge becoming an urgent and inevitable issue for every country, its applications in the production of construction and building materials provide an alternative solution for sludge disposal and resource recovery. Similar to clay and Portland cement, the main oxides in sewage sludge are SiO2 (10–25 %), Al2O3 (5–10 %) and CaO (10–30 %) which are increased in sludge ash after incineration to 25–50 %, 10–20 % and 15–30 %. Therefore, this solid waste can be utilized not only as raw material for the production of eco-cement, bricks, ceramic materials and lightweight aggregates through sintering process, but also as supplementary admixtures in cementitious materials such as pozzolanic component, fine aggregate or filling material. By critically reviewing current utilizations of sewage sludge, it is feasible to replace up to 15 % natural raw materials with sewage sludge in cement production and the manufactured eco-cement clinkers show comparable performance to traditional Portland cement. Whilst as raw feed in the fabrication of bricks, ceramic materials and lightweight aggregates, 20 % of sewage sludge substitution is acceptable to produce good quality products (within 8 % firing shrinkage and 15 % water absorption). Though high content of organic matter in raw sludge causes a decrease in mechanical strength and delay in hydration process, controlled low-strength materials offer an innovative reuse with large amount of sludge. The immobilization of heavy metals in products prevents sewage sludge causing secondary environmental pollution. Furthermore, suggestions for future research are proposed in order to strengthen the high value-added applications of sewage sludge.
115 citations
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TL;DR: In this paper, an analytical procedure involving sequential chemicai extractions was developed for the partitioning of particulate trace metals (Cd, Co, Cu, Ni, Pb, Zn, Fe, and Mn) into five fractions: exchangeable, bound to carbonates, binding to Fe-Mn oxides and bound to organic matter.
Abstract: An analytical procedure involving sequential chemicai extractions has been developed for the partitioning of particulate trace metals (Cd, Co, Cu, Ni, Pb, Zn, Fe, and Mn) into five fractions: exchangeable, bound to carbonates, bound to Fe-Mn oxides, bound to organic matter, and residual. Experimental results obtained on replicate samples of fluvial bottom sediments demonstrate that the relative standard deviation of the sequential extraction procedure Is generally better than =10%. The accuracy, evaluated by comparing total trace metal concentrations with the sum of the five Individual fractions, proved to be satisfactory. Complementary measurements were performed on the Individual leachates, and on the residual sediments following each extraction, to evaluate the selectivity of the various reagents toward specific geochemical phases. An application of the proposed method to river sediments is described, and the resulting trace metal speciation is discussed.
10,518 citations
"Utilization of sewage sludge in EU ..." refers background in this paper
...Over the last decades, a great variety of extraction schemes, both simple and sequential have been developed and, although some methods have been widely used [12,13] none has been unreservedly accepted by the scientific community....
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Book•
01 Jan 1972
TL;DR: Wastewater Engineering: An Overview of Wastewater Engineering, Methods and Implementation Considerations as mentioned in this paper is a good starting point for a discussion of the issues of wastewater engineering. But, it is not a complete survey of the entire literature.
Abstract: Wastewater Engineering: An Overview. Wastewater Flowrates. Wastewater Characteristics. Wastewater Treatment Objective, Methods, and Implementation Considerations. Introduction to Wastewater Treatment Plant Design. Physical Unit Operations. Chemical Unit Processes. Biological Unit Processes. Design of Facilities for Physical and Chemical Treatment of Wastewater. Design of Facilities for the Biological Treatment of Wastewater. Advanced Wastewater Treatment. Design of Facilities for the Treatment and Disposal of Sludge. Natural-Treatment Systems. Small Wastewater Treatment Systems. Management of Wastewater from Combined Sewers. Wastewater Reclamation and Reuse.
3,826 citations
TL;DR: In this article, a review of the current and future issues related to the combustion of sewage sludge is presented, and a number of technologies for thermal processing of sludge are discussed in three groups, i.e., mono-combustion, cocombustions and alternative processes.
1,026 citations
"Utilization of sewage sludge in EU ..." refers background in this paper
...Multiple hearth and fluidized bed furnaces are the most popular and the latter is becoming widely applied [24]....
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...Analysis has shown that about 78–98% of Cd, Cr, Cu, Ni, Pb and Zn present in the sewage sludge are retained in the ash, whereas up to 98% of the Hg may be released into the atmosphere with the flue gas [24]....
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...The whole process is occurring in two distinctive regimes [24]:...
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TL;DR: In this article, the authors proposed a standardization with respect to grain size effects, commonly achieved by analyzing the sieve fraction <63μm, which is used to pin point major sources of metal pollution and to estimate the toxicity potential of dredged materials.
Abstract: Sediment analyses are used to pin‐point major sources of metal pollution and to estimate the toxicity potential of dredged materials on agricultural land. For source assessments (Part I of the present review) standardization is needed with respect to grain size effects, commonly achieved by analyzing the sieve fraction <63μm. Further aspects include sampling methods, evaluation of background data and extent of anthropogenic metal enrichment.
530 citations