Journal ArticleDOI
Water oxidation catalysts based on abundant 1st row transition metals
Archana Singh,Leone Spiccia +1 more
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TLDR
In this article, a review of water oxidation catalysts incorporating inexpensive first row transition metals, e.g., Fe, Mn, Co and Cu, is presented, with a focus on the application of cheap and abundant metal oxides, based mainly on manganese, cobalt and nickel oxides in electrocatalytic and photoelectrochemical devices.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2013-09-01. It has received 363 citations till now. The article focuses on the topics: Industrial catalysts & Water splitting.read more
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Cobalt-iron (oxy)hydroxide oxygen evolution electrocatalysts: the role of structure and composition on activity, stability, and mechanism.
TL;DR: It is hypothesized that Fe is the most-active site in the catalyst, while CoOOH primarily provides a conductive, high-surface area, chemically stabilizing host.
Journal ArticleDOI
Ni2P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni2P nanoparticles
TL;DR: In this paper, the Ni2P nanoparticles were used as both cathode and anode catalysts for an alkaline electrolyzer, which generated 10 mA cm−2 at 1.63 V.
Journal ArticleDOI
Cocatalysts for Selective Photoreduction of CO2 into Solar Fuels.
TL;DR: Various cocatalysts, such as the biomimetic, metal-based,Metal-free, and multifunctional ones, and their selectivity for CO2 photoreduction are summarized and discussed, along with the recent advances in this area.
Journal ArticleDOI
Transition-Metal (Co, Ni, and Fe)-Based Electrocatalysts for the Water Oxidation Reaction
Lei Han,Shaojun Dong,Erkang Wang +2 more
TL;DR: Recent progress on the design, synthesis, and application of OER electrocatalysts based on transition-metal elements, including Co, Ni, and Fe, is summarized, and some invigorating perspectives on the future developments are provided.
Journal ArticleDOI
Transition Metal Oxides as Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Solutions: An Application-Inspired Renaissance
TL;DR: This Perspective presents major progress in several key areas of the OER field such as theoretical understanding, activity trend, in situ and operando characterization, active site determination, and novel materials.
References
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Book
Electrochemical Methods: Fundamentals and Applications
Allen J. Bard,Larry R. Faulkner +1 more
TL;DR: In this paper, the authors present a comprehensive overview of electrode processes and their application in the field of chemical simulation, including potential sweep and potential sweep methods, coupled homogeneous chemical reactions, double-layer structure and adsorption.
Journal Article
Photoelectrochemical cells : Materials for clean energy
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
Journal ArticleDOI
A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production
TL;DR: In this article, the up-to-date development of the above-mentioned technologies applied to TiO 2 photocatalytic hydrogen production is reviewed, based on the studies reported in the literature, metal ion-implantation and dye sensitization are very effective methods to extend the activating spectrum to the visible range.
Journal ArticleDOI
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+
TL;DR: A catalyst that forms upon the oxidative polarization of an inert indium tin oxide electrode in phosphate-buffered water containing cobalt (II) ions is reported that not only forms in situ from earth-abundant materials but also operates in neutral water under ambient conditions.
Journal ArticleDOI
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å.
TL;DR: The crystal structure of photosystem II is reported, finding that five oxygen atoms served as oxo bridges linking the five metal atoms, and that four water molecules were bound to the Mn4CaO5 cluster; some of them may therefore serve as substrates for dioxygen formation.
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