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The results indicate that the support influences the stability of palladium NPs.
This may be attributed to the enrichment of palladium in the copper-rich phase.
The values for palladium in W-1 are in reasonable agreement with previously published data.
Both results can be explained by assuming that hydrogen occupies the subsurface sites of the palladium clusters.
Such results have been explained by different interactions between palladium and the support.
The method is satisfactorily applied to the determination of palladium in some palladium catalysts.
This research reveals the importance of the methodology used for the incorporation of palladium.

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