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The features demonstrated by NF270 in separating the pollutants from the car wash effluent coupled with stable water production make the membrane a good candidate to be employed and offer an environmentally sustainable option to car wash industry.
Unlike the smooth graphene-coated surfaces, dynamic wetting on the patterned graphene-coated surfaces depends on ...
Improvements in cleaning processes, development of available technologies, and utilization of cleaning products containing natural and various benign polymers and surfactants are healthy and environmentally sound alternatives to HF for car wash applications.
Our results suggest a viable way to modify water adsorption on a graphene-coated surface and unveil the role of graphene as a passivation layer for the wetting of a charged substrate.
Open accessJournal ArticleDOI
Jie Zhou, Qiulan Luo, Gao Pu, Ma Hui 
19 Mar 2020-RSC Advances
14 Citations
The results show that, the fabrics coated with graphene had excellent fastness to washing, friction and bending.
This material can be easily spin coated on graphene and assist the transfer, leaving no residues and requiring no further removal processes.
Characterization results show that graphene coated on the B4C surface was successfully achieved by semi-powder method.
This work opens up a whole new vista on how to disperse graphene.
Thanks to a passivating effect, the metal surfaces coated by graphene become almost inert and present very low adhesion and shear strength when mated in a sliding contact.
Such 'wetting transparency' could lead to superior conducting and hydrophobic graphene-coated surfaces with tunable electronic properties.

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How strain is defined in graphene at the atomic level?
5 answers
Strain in graphene at the atomic level refers to the deformation of the lattice structure due to external forces or defects. The atomic-scale response of graphene to strain can be observed through techniques like nanoindentation and transmission electron microscopy, allowing for precise measurements of bond lengths and strain distribution. By creating strain patterns in graphene, researchers can manipulate its properties and study the effects on charge carriers. While previous approaches focused on small strains, new discrete frameworks enable accurate calculations of strain-induced gauge fields even under large strains, providing insights into the mechanical and electrical behavior of strained graphene at the atomic level.
What are the potential applications and advantages of graphene-based membranes versus zeolite-based membranes in carbon dioxide separation, and?
4 answers
Graphene-based membranes and zeolite-based membranes each offer unique advantages for carbon dioxide separation, with potential applications that leverage their distinct properties. Graphene-based membranes are celebrated for their high separation potential, attributed to their tunable nanosized channels, high surface area, and porosity, which are crucial for efficient ion and molecule separation. The solvent-ink-jet printing technique described for graphene layers indicates a novel approach to overcoming challenges in scalable manufacturing, showing promising CO2 separation performance with a significant decrease in CO2 composition in permeate. Graphene oxide (GO), in particular, has shown great potential in membrane-based separation, with its incorporation into membranes enhancing permeation and metal ions rejection rates, indicating its versatility beyond gas separation to applications like heavy metals removal from polluted water. On the other hand, zeolite membranes, as compiled in a review, have seen recent advancements that significantly improve selectivities and permeances for CO2 and N2, suggesting reduced energy demand and lower operational costs. However, their commercial deployment requires further studies to assess long-term operation and separation performance in multicomponent systems. Zeolitic imidazolate frameworks (ZIFs), a subset of zeolite membranes, when modified with graphene nanoribbons (GNRs), have shown to rigidify the framework, leading to high H2/CO2 separation performance, indicating their potential application in blue hydrogen production. Comparatively, graphene-based membranes offer broader application potential due to their mechanical properties and tunability, which are advantageous for both gas separation and water treatment. Zeolite membranes, with their improved selectivity and permeance for specific gases, present a cost-effective option for industrial gas separation processes. The integration of graphene or GNRs into zeolite frameworks combines the strengths of both materials, suggesting a synergistic approach for enhancing separation performance.
What is the relationship between nano surface roughness and adhesion?
5 answers
Nano surface roughness plays a crucial role in adhesion phenomena across various fields. Studies have shown that reducing the surface roughness of materials such as NiTi wires to nano-levels significantly decreases bacterial adhesion by over 70% to 83.48%. Conversely, the extent of bacterial fouling on hydrophobic surfaces can vary up to 75-fold with changes in surface roughness, with increased roughness enhancing adhesion on certain surfaces. Furthermore, nanoparticle roughness affects suspension stability, where small changes in roughness can significantly impact the phase behavior of suspensions, influencing adhesion forces and gel formation. Additionally, the adhesion hysteresis of Cu thin films is influenced by surface roughness, with smoother surfaces exhibiting more pronounced adhesion hysteresis. These findings collectively highlight the intricate relationship between nano surface roughness and adhesion in various material systems.
Why nitrigen doped graohene is better that graphene for gas sensing?
5 answers
Nitrogen-doped graphene exhibits enhanced gas-sensing capabilities compared to pristine graphene due to several key factors. Firstly, the introduction of nitrogen into the graphene lattice induces a band gap, which is absent in pristine graphene, thereby improving its electrical conductivity and sensitivity to gas molecules. This modification allows for a more pronounced modulation of electrical conductivity in response to gas adsorption, making nitrogen-doped graphene a superior material for detecting various gases. The doping process also generates defects and increases the surface area, which maximizes the interaction between the surface and gas molecules, further enhancing the gas-sensing performance. Density Functional Theory (DFT) studies have shown that nitrogen-doped graphene sheets exhibit selective binding to different gases, such as carbon monoxide, carbon dioxide, and oxygen, which is crucial for the development of selective gas sensors. The electronic structures of these doped graphene sheets are altered in a way that improves their ability to detect specific gases. Additionally, the presence of nitrogen creates special binding sites that are beneficial for near-surface interaction with gas molecules, significantly changing the electronic characteristics of graphene and its derivatives and expanding its potential use as gas sensors. Experimental research has demonstrated that nitrogen-doped graphene sensors are responsive to low concentrations of gases at room temperature, showcasing higher sensitivity and excellent reproducibility compared to their undoped counterparts. Furthermore, the introduction of nitrogen into graphene has been shown to facilitate stronger chemisorption of gas molecules, such as NO2, leading to higher sensitivity and selectivity towards these gases. The codoping of heteroatoms, including nitrogen, in graphene has been explored to further improve gas sensing properties, indicating that nitrogen doping is a key strategy in enhancing the performance of graphene-based gas sensors. In summary, nitrogen doping enhances the gas-sensing capabilities of graphene by introducing a band gap, generating defects, increasing surface area, and creating specific binding sites for gas molecules, which collectively contribute to improved sensitivity, selectivity, and overall performance of gas sensors.
How does the extraction process affect lignin?
4 answers
The extraction process significantly impacts lignin properties. Different extraction methods like supercritical carbon dioxide (scCO2)–ethanol/water composite medium, alkaline extraction, and high-temperature ethanol extraction yield lignin with varying characteristics. For instance, the scCO2-extracted lignin showed enhanced UV-blocking ability and mechanical strength due to its small particle size and unique structural units. Additionally, the choice of extraction method, such as Kraft, Soda, or Organosolv, affects the economic viability of lignin production, with Kraft extraction being more suitable for lignin valorization. Moreover, the addition of stabilizing reagents during extraction can influence lignin's thermal stability and pyrolysis yield. Surfactants, including cationic ones, have been shown to improve lignin dissolution efficiency and extraction yield from biomass residues. Overall, the extraction process plays a crucial role in determining lignin's properties and potential applications.
What are the mathematical formulas used to parameterize Delaunay surfaces?
5 answers
The mathematical formulas used to parameterize Delaunay surfaces involve the utilization of Jacobi elliptic functions and canonical forms of elliptic integrals. Delaunay surfaces can be expressed through explicit parameterizations based on two independent real parameters representing size and shape, encompassing all possible Delaunay surfaces uniformly. Additionally, for constant mean curvature surfaces related to Delaunay surfaces, coordinate functions can be calculated in closed form, especially when the mean curvature is constant, where these functions can be expressed using Jacobi elliptic functions. Furthermore, in the context of constant mean curvature 1 surfaces, a uniform disk exists where surfaces closely resemble the model Delaunay surface, parametrized by the necksize of the model surface.
What are the current advancements in the development of piezoresistive pressure sensors based on poly-silicon?
5 answers
Current advancements in piezoresistive pressure sensors based on poly-silicon include the utilization of silicon nanowires (SiNWs) for enhanced sensing capabilities. SiNWs exhibit unique one-dimensional electronic structures, making them ideal for various applications such as biosensors, FETs, and piezoresistive pressure sensors. Additionally, the development of flexible piezoresistive membranes using polymer solutions has shown promising results, with increased sensitivity and gauge factors for piezoresistive sensing applications. Furthermore, the integration of ultra-thin graphene foam (GRF) with polydimethylsiloxane (PDMS) in piezoresistive pressure sensors has demonstrated sensitivity to pressures ranging from 0 to >100kPa, although not yet comparable to current sensors. These advancements highlight the diverse approaches being explored to enhance the performance and applications of poly-silicon-based piezoresistive pressure sensors.
How does chemical vapor growth of graphene work?
5 answers
Chemical vapor deposition (CVD) for graphene growth involves complex gas-phase surface reactions, mass, momentum, and energy transfer processes. Factors like temperature, pressure, and reactor design play crucial roles in optimizing graphene synthesis. Electric fields applied during CVD can significantly impact graphene growth, enabling selective or rapid growth of clean films. Direct CVD of graphene on specific substrates like 3C-SiC can be challenging due to low carbon atom diffusion, necessitating alternative methods like PECVD for successful growth. A modified CVD method utilizing ceramic plates and defect-rich vertical graphene accelerates graphene growth without increasing nucleation density, enabling rapid millimeter-sized graphene grain production in minutes. Overall, CVD processes involve intricate mechanisms combining chemical reactions, transport phenomena, and reactor optimization to achieve efficient graphene synthesis.
Solid state foaming process PCL possible?
4 answers
The solid-state foaming process of Poly(e-caprolactone) (PCL) is indeed feasible and has been extensively studied in various research papers. Studies have shown that utilizing supercritical carbon dioxide (scCO2) as a physical blowing agent enables the successful foaming of PCL. The incorporation of other materials such as Poly (lactic-co-glycolic acid) (PLGA), hydroxyapatite, nanocellulose, carboxymethylcellulose, and graphene oxide has been explored to enhance the properties of the foamed PCL structures. Optimal process parameters have been identified, including pressure, temperature, and time, to achieve structures suitable for biomedical applications. The biocompatibility of the resulting PCL foams has been confirmed, making them suitable for use in artificial scaffolds for cell culture in biomedical engineering.
Solid state foaming process pure PCL possible?
5 answers
Yes, the solid-state foaming process of pure poly(e-caprolactone) (PCL) is feasible. Research has shown that PCL can be foamed using supercritical carbon dioxide (scCO2) as a physical blowing agent, resulting in porous structures with controllable properties. Additionally, studies have explored the use of non-toxic and environmentally friendly blowing agents, such as supercritical mixtures of carbon dioxide (CO2) and ethyl lactate (EL), to foam PCL at relatively low temperatures. Furthermore, investigations into the foaming behavior of PCL with nitrogen as the foaming agent have provided insights into the correlation between foam structure and processing variables, aiding in the design of PCL foams with desired properties. Therefore, the solid-state foaming of pure PCL is not only possible but can also be tailored to achieve specific characteristics for various applications.
Solid state foaming process pure PCL at -70degree possible?
5 answers
Solid-state foaming of pure PCL at -70 degrees Celsius is not feasible based on the data from the provided contexts. The optimal conditions for foaming PCL-based composites using supercritical CO2 were found to be at a temperature of 70 degrees Celsius. Additionally, studies on PCL foaming with supercritical CO2 and ethyl lactate as blowing agents were conducted at temperatures ranging from 35 to 40 degrees Celsius. Furthermore, investigations into the foaming behavior of PCL with nitrogen as the foaming agent did not mention temperatures as low as -70 degrees Celsius, emphasizing the correlation between foaming temperature and foam structure. Therefore, based on the available data, solid-state foaming of pure PCL at -70 degrees Celsius is not supported by the research findings.