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Native palladium occurs as a crystallized component within the Pd-O phase, with microstructural and chemical features suggesting a desiccation process.
The activity of palladium is largely affected by its support.
The method proved to be successful in determination of palladium in the intermetallides and resistor.
In most cases, Pd NPs are not the only form of palladium present in the system, but they contribute in product formation together with other species forming “cocktail of catalysts”.
These results are attributed to the presence of nanoparticles (NPs) which served as a reservoir of palladium species.
The method can be combined with subsequent FAAS determination of palladium.
Such results have been explained by different interactions between palladium and the support.
The results are consistent with a physical mechanism of modification by palladium.