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What will effect on Raney nickel catalyst activity of doped with alginate? 

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The results show that yttria doped in nickel catalyst plays a key role in keeping the activity of the catalyst by resisting or postponing the interaction between copper and nickel.
It is shown that the Raney-type Nickel catalyst pretreatment and the impurities present in the reactants have a large impact on the catalyst surface activity.
The decrease in catalytic activity of Raney nickel was likely due to an increase in average nickel crystallite size caused by hydrothermal sintering.
The results obtained from these studies suggest that activity of the catalyst is affected by the oxidation state of the metal, the use of nickel(0) compounds resulting in better catalyst performance overall.
The synthesized catalyst shows a better activity with respect to Raney nickel.
The catalytic properties of nickel Raney (NiR) catalysts may be influenced by the phase composition of the precursors—mechanically alloyed (MA) nickel aluminides.
It is found that chromium-doped Raney nickel is more active than the titanium-doped catalyst.
Non-pyrophoric Raney nickel catalyst is more active than Ni/Al 2 O 3 samples especially in the side reactions.
These results suggest that the activities for hydrogenation and adsorption were enhanced when the content of the residual aluminum in the catalyst was increased, and that the role of the residual aluminum in catalytic reactions can be classified into two types: to provide an increase in active sites due to formation of interstitial lattice defects, and to make a negligible contribution to the formation of active sites because of deposition of Al 2 O 3 n H 2 O on the Raney nickel catalyst.
The enhancing of catalytic activity by Mo in Raney nickel is partly caused by synergetic effects between Ni and Mo, as follows from their electronic structure, and partly by material stabilization as follows from comparison with the Raney nickel (Zn).

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What is the role of alginat Na in electrochemical applications?5 answersSodium alginate, a biopolymer derived from algae, plays a crucial role in various electrochemical applications. In the context of bio-based polymer electrolytes (BBPEs), alginate doped with glycolic acid demonstrated enhanced ionic conductivity and thermal stability, making it a promising electrolyte for electrochemical devices. Additionally, in the synthesis of electrolytic manganese dioxide (EMD) for supercapacitors, alginate acted as a template for binding Mn2+ ions, leading to improved energy storage capabilities. Furthermore, in sodium-ion batteries (SIBs), sodium alginate was found to suppress cracks, reduce charge-transfer resistance, and enhance the performance of cathode materials. Moreover, in the preparation of Na0.67MnO2 electrodes for SIBs, a TBA alginate binder exhibited favorable electrochemical performance, surpassing traditional binders like PVDF. Overall, sodium alginate emerges as a versatile and effective component in enhancing the electrochemical properties of various systems.
What is the effects of the support of Ni catalysts for CO2 methanation?4 answersThe support of Ni catalysts for CO2 methanation has significant effects on their performance. One important aspect is the dispersion of nickel metal particles, which is crucial for high catalytic activity and low carbon deposition. It has been found that an ionic support is necessary to achieve good nickel dispersion and produce small nickel metal particles. Additionally, the use of support and/or surface additives with medium surface basicity can enhance CO2 adsorption and increase the reaction rate. The choice of support material also plays a role in the stability of the catalyst. For example, SiC and polymer-derived ceramics have been investigated as alternative supports due to their high thermal and mechanical stability. Furthermore, the addition of CeO2 to the support has been shown to promote Ni0 dispersion and improve CO2 activation, leading to higher CH4 yields. Overall, the support of Ni catalysts for CO2 methanation is crucial for achieving high catalytic activity, stability, and selectivity towards methane production.
How can the performance of Ni electrocatalyst be improved?5 answersThe performance of Ni electrocatalyst can be improved through various methods. One approach is to fabricate the electrode using a simple electrodeposition technique, which can result in a highly stable binder-free electrode. Another method is to synthesize multiple metal doped nickel nanoparticles, such as FeMnMoV-Ni, which have shown superior oxygen evolution reaction (OER) performance. Heat-treatment temperature can also play a role, as demonstrated by the synthesis of NiO nanosheet arrays on Ni foam, where different temperatures resulted in varying oxygen defect concentrations and Ni3+/Ni2+ ratios, leading to different catalytic activities. Additionally, the use of bimetallic Ni-Ir catalysts, fabricated through electrodeposition, has shown improved hydrogen oxidation reaction (HOR) performance in an alkaline environment. Finally, the synthesis of a nickel-silver nanocomposite has been shown to enhance the electrocatalytic performance and stability of the material for the hydrogen evolution reaction (HER).
What is the mechanism of the effect of nickel on the bone tissue engineering of nanohydroxyapatite?5 answersThe mechanism of the effect of nickel on the bone tissue engineering of nanohydroxyapatite involves the activation of the vascular endothelial growth factor (VEGF) pathway for angiogenesis. Nickel-doped nano-hydroxyapatites (nHAp) were synthesized and characterized, and it was found that Ni2+ doping influenced the cell viability, proliferation, and differentiation of bone cells (MG-63) in a concentration-dependent way. Ni2+ doped nHAp also induced cellular VEGF expression many fold in comparison to control, indicating its role in promoting angiogenesis. Additionally, the involvement of hypoxia-inducible factor 1 alpha (HIF-1α) in cellular VEGF production was observed. These findings suggest that Ni2+ doped nHAp can serve as a proangiogenic-osteogenic biomaterial for bone tissue engineering.
Does Ni enhance the air stability of a substance?4 answersNi enhances the air stability of a substance by improving its electrochemical and mechanical performance. The increased Ni content in Ni-rich cathode materials leads to a more stable surface structure and decreased surface tensile stress, resulting in improved cycling property, rate retention, and safety performance. Additionally, Ni-doping in NbH phases lowers the energy barrier of hydrogen diffusion and enhances the mechanical properties of the material. Ni also improves the carbon gasification kinetics and stability of Fe-Al oxide in chemical looping dry reforming of methane, allowing for complete methane conversion.
What is the effect of CO2 production on alginate beads?3 answersThe effect of CO2 production on alginate beads varies depending on the specific context. In one study, it was found that CO2 can be used as a major attractant for arthropod pests, and alginate beads containing corn starch, amyloglucosidase, and Saccharomyces cerevisiae were developed to release CO2 for pest control purposes. Another study focused on the adsorption of CO2 onto alginate immobilized zeolite beads, which demonstrated higher sorption efficacy compared to plain alginate beads and zeolite alone. Additionally, alginate beads were used in biohydrogen production, where the presence of CO2 influenced the biofilm formation and hydrogen production rate. Furthermore, the production and quality of alginate by Azotobacter vinelandii were evaluated in the presence of different levels of CO2, showing both inhibitory and stimulatory effects on biomass growth and alginate production. Overall, the effect of CO2 production on alginate beads can vary depending on the specific application and context.

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