Topic
Acetonitrile
About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.
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TL;DR: Indirect anodic gem-difluorodesulfurization of dithioacetals was successfully carried out using triarylamine mediators to provide gem-diffluoromethylene compounds in moderate to good yields as mentioned in this paper.
57 citations
TL;DR: In this paper, the processus de reduction et d'oxydation is considered, as well as de comportement, dans CH 3 CN, d'une serie de complexes [Ru(HDPA) n (bpy) 3−n ] 2+ (1) (n=0−3), [Ru[Ru(DPA] n (dipyridylamine deprotonee and bpy=bipyridine-2, 2,2] avec HDPA=di-pyridyl-2 am
Abstract: Resultats d'etudes, a temperatures basse et ambiante, par voltammetrie cyclique et spectrometrie, du comportement, dans CH 3 CN, d'une serie de complexes [Ru(HDPA) n (bpy) 3−n ] 2+ (1) (n=0−3), [Ru(DPA) n (bpy) 3−n ] ( 2 −n)u + (2) (n=0−3) et [Ru(HDPA) n (DPA) 3−n ] (N−1)u + (3) (n=0−3) avec HDPA=di-pyridyl-2 amine; DPA − =dipyridylamine deprotonee et bpy=bipyridine-2,2'. Donnees sur les processus de reduction et d'oxydation. Spectres RPE
56 citations
TL;DR: In this article, a simple, convenient and general method has been developed for the synthesis of α-aminonitriles by a one-pot three component condensation of aldehydes, amines and trimethyl silyl cyanide in acetonitrile.
Abstract: A simple, convenient and general method has been developed for the synthesis of α-aminonitriles by a one-pot three component condensation of aldehydes, amines and trimethyl silyl cyanide in acetonitrile in the presence of a catalytic amount of La(NO 3 ) 3 ·6H 2 O or GdCl 3 ·6H 2 O.
56 citations
TL;DR: Differential capacity curves were plotted for renewed crosssections of platinum and palladium electrodes under working solutions of perchlorate of lithium, sodium, tetraethylammonium and tetraborate sodium in acetonitrile.
56 citations
TL;DR: The results indicate that SECM is a very useful technique for studying electron transfer dynamics in ionic liquids in acetonitrile and in an ionic liquid electrolyte.
Abstract: The electrochemical behavior of a redox-active, ferrocene-modified ionic liquid (1-ferrocenylmethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) in acetonitrile and in an ionic liquid electrolyte (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) is reported. Reversible electrochemical behavior was observed in each electrolyte with responses typical of those for unmodified ferrocene observed in each medium. In the ionic liquid electrolyte, the diffusion coefficient of the redox-active ionic liquid increased by a factor of 5 upon increasing the temperature from 27 to 90 °C. The kinetics of electron transfer across the ionic liquid/electrode interface were studied using cyclic voltammetry, and the standard heterogeneous electron transfer rate constant, k0 was determined to be 4.25 × 10−3 cm s−1. Scanning electrochemical microscopy was then also used to probe the heterogeneous kinetics at the interface between the ionic liquid and the solid electrode and conventional kinetic SECM theor...
56 citations