Topic
Acetonitrile
About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.
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TL;DR: A simple and efficient electrocarboxylation reaction of aliphatic halides has been developed using silver as cathode, magnesium as anode and CH3CN saturated CO2 as solvent in an undivided cell.
55 citations
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TL;DR: Both experiments and simulations show that the addition of acetonitrile reduces the viscosity of a solution of 1-ethyl-3-methylimidazolium chloride and glucose by more than an order of magnitude.
Abstract: A recently improved ionic liquid force field was used to compute the viscosity for binary and ternary mixtures of 1-ethyl-3-methylimidazolium chloride ([emim][Cl]) with water, acetonitrile, and glucose. For the same systems, experimental viscosity data are provided. The simulation and experimental results were in reasonable agreement. Simulations consistently overestimate the viscosities for the mixtures of [emim][Cl] and glucose while the viscosities of the mixtures of glucose and water are well reproduced. Both experiments and simulations show that the addition of acetonitrile reduces the viscosity of a solution of [emim][Cl] and glucose by more than an order of magnitude.
55 citations
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TL;DR: Cristallisation dans le groupe Pn21a avec a=24,50, b=20,756 and c=8,567 A. Affinement jusqu'a R=0,048 as discussed by the authors.
Abstract: Cristallisation dans le groupe Pn21a avec a=24,50, b=20,756 et c=8,567 A. Affinement jusqu'a R=0,048. Coordination tetraedrique autour des atomes Ag
55 citations
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55 citations