Topic
Acetonitrile
About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.
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TL;DR: Application of the method has been demonstrated in the analysis of benzaldehyde formed as oxidation product in pharmaceutical preparation where benzyl alcohol is used as preservative, and for a keto drug dexketoprofen.
54 citations
TL;DR: In this article, a reaction of 2,2′-bithiophene with copper(II) perchlorate in acetonitrile achieved polymerization and doping in one step, and yielded polythiophenes, [(C4H2S)(ClO4)x·yH2O]n.r.
54 citations
TL;DR: In this article, a non-aqueous all-cobalt redox flow battery, with a cobalt complex 1,10-phenanthroline cobalt(II) hexafluorophosphate ([Co(phen)3](PF6)2) as the active species, acetonitrile as the solvent and tetraethylammonium hexaphosphate (TEAPF6), as the supporting electrolyte, has been investigated.
54 citations
TL;DR: In this paper, the acceptor numbers for binary mixtures of water with acetonitrile (AN), dioxane, acetone (AC), pyridine (PY), N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), hexamethylphosphoramide (HMPA), methanol, ethanol andi-propyl alcohol were determined both by selective solvation and specific solvent-solvent interactions.
Abstract: Acceptor numbers have been determined for binary mixtures of water with acetonitrile (AN), dioxane, acetone (AC), pyridine (PY), N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), hexamethylphosphoramide (HMPA), methanol, ethanol andi-propyl alcohol. The electrophilic properties of binary aqueous-non aqueous solvent mixtures are determined both by selective solvation and specific solvent-solvent interactions. The variation of the acceptor number as a function of solvent composition is interpreted in terms of the previously determined nucleophilic and electrophilic properties of the pure components and their specific solvent structure.
54 citations