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Acetonitrile

About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.


Papers
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Journal ArticleDOI
TL;DR: In this paper, cyclic voltammetry (CV) was used to obtain poly(3,4-dialkoxythiophene) films with different length of alkyl chain (1, 3 and 8 carbon atoms) on Pt and ITO electrodes from the monomer solutions in acetonitrile by cyclic voltage measurement.

50 citations

Journal ArticleDOI
TL;DR: In this paper, a Fourier transform infrared spectroscopy (FTIR) was used to study the oxidation properties of LiAsF{sub 6}/acetonitrile and LiClO{sub 4}/ACetonitriles solutions containing 0.003-0.05M H{sub 2}O.
Abstract: The oxidation of LiAsF{sub 6}/acetonitrile and LiClO{sub 4}/acetonitrile solutions containing 0.003--0.05M H{sub 2}O was studied on platinum and glassy carbon electrodes by in situ Fourier transform infrared spectroscopy. Both the solvent and the solute are unstable at potentials positive to ca. 2.2 V vs. SCE. The main oxidation product is CO{sub 2}. Other products detected are: via a reaction of acetonitrile with trace water as substantiated by the occurrence of an isotopic shift of the CO{sub 2} stretching vibration when using H{sub 2}{sup 18}O. The rate of the CO{sub 2} formation is increased by the presence of perchlorate anions and the Pt surface.

50 citations

Journal ArticleDOI
TL;DR: In this article, strongly polar molecules such as acetone, nitromethane, and acetonitrile imbedded in an inert gas matrix give rise to characteristic absorption patterns below 150 cm−1.
Abstract: Strongly polar molecules such as acetone, nitromethane, and acetonitrile imbedded in an inert gas matrix give rise to characteristic absorption patterns below 150 cm−1. The bands observed in the case of acetonitrile are due to an activated phonon band, to two vibrations of a monomer molecule within the polarized cage of inert gas atoms, and to two intermolecular vibrations of an antiparallel dimer.

49 citations

Journal ArticleDOI
TL;DR: The new bioglycerol-based carbon catalyst acts as an efficient, readily available, and reusable catalyst for the synthesis of 2,4,5-trisubstituted imidazoles/1,2,4-5-tetrasubstitute imidzoles, when aromatic aldehyde, ammonium acetate/amine, and 1,2-diketone are reacted in acetonitrile.

49 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
2023533
20221,074
2021178
2020172
2019229
2018207