Acetonitrile

About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.

Cation–calixarene interactions: tetraalkylammonium cation binding by calixarene anions

Abstract: Syntheses of a number of tetraalkylammonium derivatives of various calix[n]arenes (n= 4, 6, 8) have been conducted by reacting the tetraalkylammonium hydroxides with the parent calixarenes. 1 H NMR studies in acetone and dimethylsulfoxide (DMSO) solvents have shown that cation inclusion by the anionic calixarenes occurs in some cases for only the tetramethyl- and tetraethyl-ammonium cations, indicating that different forms of ion association must occur in solution. The nature of cation–anion interactions in the solid tetraethylammonium salts of the monoanions of p-tert-butylcalix[4]arene (L2) and its dihomooxa analogue (L3) has been explored by room temperature single-crystal X-ray studies of the two salts and the parent ligand L3, all recrystallised variously solvated from acetonitrile. In both solid salts, columnar arrays of alternating cations and anions are found: in the dihomooxa ligand (L3) salt, the cations are captured within the ligand cup, forming contact ion pairs, the column comprising stacks of these. By contrast, the columnar array found in the parent ligand (L2) salt consists of discrete moieties, with the anion cavity occupied by acetonitrile. The free (neutral) ligand L3, as its acetonitrile monosolvate, contains the acetonitrile within the ligand cavity also. The structure determination of the unsubstituted calix[4]arene ligand, L1, is recorded as its ⅓ acetonitrile solvate, with location of all phenolic hydrogen atoms bridging their associated oxygen atoms; the acetonitrile in this case simply occupies a lattice void, as in the isomorphous acetone solvate.