Topic
Acetonitrile
About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.
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TL;DR: In this article, the anodic oxidation of methane, butane, and other aliphatic alkanes is clearly observed under steady state conditions at potential up to about 3.8V (Ag+ reference).
Abstract: : The use of ultramicroelectrodes is aprotic solvent containing no purposefully added support electrolyte allows the observed anodic oxidation limit in acetonitrile to be considerable extended. The anodic oxidation of methane, butane, and other aliphatic alkanes is clearly observed under steady state conditions at potential up to about 3.8V (Ag+ reference). The oxidation of the solvent occurs significantly at potentials greater than 4.0V and appears to result in radical coupling reactions forming both soluble and insoluble polymers.
84 citations
TL;DR: In this article, the effects of the bite angle on reductive elimination of dimethyl ether, acetonitrile, vinyl cyanide, and methyl ethanoate from palladium diphosphine complexes were studied by means of a density functional theory method.
84 citations
TL;DR: Reduction chimique de la phenanthrenequinone-9,10 par ajout d'un groupe carbonyle Etude de la reaction par voltammetrie cyclique dans un electrolyte acetonitrile-tetrafluoroborate d'ammonium tetrabutyle as mentioned in this paper.
Abstract: Reduction chimique de la phenanthrenequinone-9,10 par ajout d'un groupe carbonyle Etude de la reaction par voltammetrie cyclique dans un electrolyte acetonitrile-tetrafluoroborate d'ammonium tetrabutyle
84 citations
TL;DR: Generic screening conditions and an initial simple separation strategy allowing the rapid separation of drug enantiomers in polar organic solvent chromatography (POSC) were determined and a screening strategy was proposed.
84 citations
TL;DR: Structural and transport properties of ionic liquid electrolytes (ILEs) with 20 and 40 mol % of organic solvents have been investigated and compared to properties of neat ILEs and the Li(+)-N(Ntf2) residence times were dramatically reduced with addition of Solvents, indicating an increasing contribution from structural diffusion of theLi(+) cations.
Abstract: Molecular dynamics simulations of N-methyl-N-propylpyrrolidinium (pyr13) bis(trifluoromethanesulfonyl)imide (Ntf2) ionic liquid [pyr13][Ntf2] doped with [Li][Ntf2] salt and mixed with acetonitrile (AN) and ethylene carbonate (EC) organic solvents were conducted using polarizable force field. Structural and transport properties of ionic liquid electrolytes (ILEs) with 20 and 40 mol % of organic solvents have been investigated and compared to properties of neat ILEs. Addition of AN and EC solvents to ILEs resulted in the partial displacement of the Ntf2 anions from the Li+ first coordination shell by EC and AN and shifting the Li–Ntf2 coordination from bidentate to monodentate. The presence of organic solvents in ILE has increased the ion mobility, with the largest effect observed for the Li+ cation. The Li+ conductivity has doubled with addition of 40 mol % of AN. The Li+–NNtf2 residence times were dramatically reduced with addition of solvents, indicating an increasing contribution from structural diffusi...
83 citations