Topic
Acetonitrile
About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.
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TL;DR: In this article, X-ray structures of Pd−acyl complexes with a phosphine−imine (P∼N) bidentate ligand are revealed.
76 citations
76 citations
TL;DR: In this article, copolymerization of pyrrole and indole was achieved electrochemically in acetonitrile containing lithium perchlorate as supporting electrolyte, and the copolymers were characterized by conductivity measurements, cyclic voltammetry, scanning electron microscopy, UV visible and IR spectroscopic techniques.
Abstract: Copolymerization of pyrrole and indole was achieved electrochemically in acetonitrile containing lithium perchlorate as supporting electrolyte. The copolymer compositions can be altered by varying the comonomer feed ratios during preparation. The copolymers were characterized by conductivity measurements, cyclic voltammetry, scanning electron microscopy, UV-visible and IR spectroscopic techniques. A possible scheme for the copolymerization mechanism has been suggested.
76 citations
TL;DR: Interactions between metal ions and added organic ligands became more selective with increasing pH, showing the expected preference of hard and soft ligands for metal ions of the corresponding type.
Abstract: The distribution of metal species in solution was determined using flow injection electrospray ionization mass spectrometry. Complexes formed by selected metal ions with added organic ligands in 50:50 water/acetonitrile and 50:50 water/methanol under acidic, neutral, and basic conditions were detected using electrospray ionization conditions optimized to best represent solution-phase interactions. Metal species containing acetate, nitrate, and solvent molecules predominated in acidic solution but became less abundant at higher pH. Interactions between metal ions and added organic ligands became more selective with increasing pH, showing the expected preference of hard and soft ligands for metal ions of the corresponding type. Species distributions also tended toward larger complexes as pH increased. Overall ion yield was greater for aqueous acetonitrile than for aqueous methanol solutions; however, reduction of copper(II) in aqueous acetonitrile resulted in the detection of copper(I) complexes for certain...
76 citations
TL;DR: In this article, nitrogen-doped single walled carbon nanotubes (SWCNTs) have been synthesized via the thermal decomposition of ferrocene using different ratios of acetonitrile/ethanol feedstock mixtures during the chemical vapor deposition process.
76 citations