Topic
Acetonitrile
About: Acetonitrile is a research topic. Over the lifetime, 11298 publications have been published within this topic receiving 175275 citations. The topic is also known as: cyanomethane & ethyl nitrile.
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TL;DR: In this paper, the difference in the values of the differential real potential for the anion and cation is identified with the surface potential of the pure solvent, and it is shown that the difference of ‘chemical’ solvation energy of these large alternant hydrocarbon ions should be close to zero.
70 citations
TL;DR: In this paper, the authors used FTIR measurements in the region of the C-N stretching mode of the solvent to reveal bands produced by acetonitrile molecules in the solvation shells and bands of ClO 4, NaClO 4 and ClO 2.
Abstract: The IR spectra of alkaline and alkaline earth metal perchlorate and of lithium bromide solutions in acetonitrile, obtained with the help of FTIR measurements in the region of the C-N stretching mode of the solvent, reveal bands produced by acetonitrile molecules in the solvation shells and bands of ClO
4
−
ions in contact and solvent separated ion pairs The shift and the attenuation of the C-N stretching band of acetonitrile at 2254 cm−1 is used for the calculation of cation solvation numbers for Li+(4), Na+(4), Mg2+(6), Ca2+(6), and Ba2+(6) No solvation is assumed for the contact ion pairs of LiClO4, LiBr, NaClO4, Mg(ClO4)2, Ca(ClO4)2, and Ba(ClO4)2 The association constants of the symmetrical electrolytes are compared to those obtained from other methods
70 citations
TL;DR: The cyclic voltammetry of some fullerene-ferrocene derivatives showed that these compounds possess very interesting electrochemical properties as discussed by the authors, and the properties of these compounds can be found in the literature.
Abstract: The cyclic voltammetry of some fullerene–ferrocene derivatives shows that these compounds possess very interesting electrochemical properties.
70 citations
TL;DR: In this paper, the interaction of p-nitrophenol with triethylamine in various aprotic solvents was studied quantitatively by means of electronic absorption spectroscopy, with special regard to proton transfer.
70 citations
70 citations