Activated alumina

About: Activated alumina is a research topic. Over the lifetime, 1430 publications have been published within this topic receiving 31090 citations.

Simultaneous removal of selenite and selenate from drinking water using mesoporous activated alumina

Abstract: The present study reports detailed evaluation of mesoporous activated alumina (MAA) for simultaneous removal of two hazardous inorganic species of selenium, namely selenite and selanate, from drinking water. MAA was used after washing with deionized water followed by drying at 110 °C for 8 h. The material was characterized using pXRD, FTIR, zeta potential, SEM and BET surface area measurements. Batch adsorption studies were performed, and various adsorption isotherms and kinetic parameters were computed to delineate the mechanism of adsorption. It was observed that Freundlich adsorption isotherm was the best-fit model for both the species of selenium. The adsorption capacity obtained from Freundlich isotherm for selenite and selenate was found to be 9.02 µg g−1 and 5.38 µg g−1, respectively. Kinetics studies revealed that adsorption of selenite follows pseudo-second-order model, whereas selenate adsorption follows pseudo-first-order model. The efficiency of the material was also evaluated at different pH and in the presence of different competitive co-ions, which confirms efficacy of MAA at near-neutral pH and lower concentrations of competitive co-ions. Negligible changes in the pH were observed during the course of adsorption. Further, the saturated adsorbent was subjected to regeneration and reuse studies up to ten cycles, showing insignificant reduction in adsorption efficiency of the adsorbent during few initial cycles. The study infers the effectiveness of MAA as a potential adsorbent for drinking water treatment contaminated with selenium.

Removal of arsenic from drinking water using dual treatment process

Abstract: This paper focuses on determining an efficient and simple method to remove arsenic from groundwater. Arsenic is a naturally occurring element widely distributed in the earth’s crust. Arsenic is very toxic when found in large quantities in drinking water. This report documents the selected treatment method and laboratory experimentation of arsenic removal from drinking water in small water delivery systems and domestic water systems. The objective is to expand upon research of new and existing arsenic removal technologies or promote a new, alternative process. Several treatment technologies have been considered to perform this function, but cost and reliability concerns prompted the decision to analyze small-scale, community-based filtration units, specifically. Based upon initial test data, the use of dual treatment method comprising of oxidation-coagulation-filtration and adsorption by activated alumina has proven to be more economic having more capacity and superior reliability as compared to other arsenic removal processes using various other media.

The role of denitrification on arsenite oxidation and arsenic mobility in an anoxic sediment column model with activated alumina.

Abstract: Arsenite (As(III)) is the predominant arsenic (As) species in reducing environments. As(III) is less strongly adsorbed than As(V) at circumneutral pH conditions by common non-iron metal oxides in sediments such as those of aluminum. Therefore, oxidation of As(III) to As(V) could contribute to an improved immobilization of As and thus help mitigate As contamination in groundwater. Microbial oxidation of As(III) is known to readily under aerobic conditions, however, the dissolved oxygen (O₂) concentration in groundwater may be limited due to the poor solubility of O₂ and its high chemical reactivity with reduced compounds. Nitrate (NO₃⁻), can be considered as an alternative electron acceptor, which can support oxidation of As(III) to As(V) by denitrifying bacteria. In this study, two up-flow sediment columns packed with activated alumina (AA) were utilized to demonstrate the role of denitrification on the oxidation of As(III) to As(V) and its contribution to improved As adsorption onto AA. One column was supplied with NO₃⁻(C1) and its performance was compared with a control column lacking NO₃⁻(C2). During most of the operation when the pH was in the circumneutral range (days 50-250), the release of arsenic was greater from C2 compared to C1. The effluent As concentrations started increasing on days 60 and 100 in C2 and C1, respectively. Complete breakthrough started on day 200 in C2; whereas in C1, complete breakthrough was never achieved. The effluent and solid phase As speciation was dominated by As(V) in C1, indicating the occurrence of As(III) oxidation due to NO₃⁻; whereas in C2, only As(III) was dominant. This study illustrates a bioremediation or natural attenuation process based on anoxic microbial NO₃⁻-dependent oxidation of As(III) to more readily adsorbed As(V) as a means to enhance the immobilization of As on alumina oxide particles in subsurface environments.

Activated alumina and activated carbon compounded material and preparation method thereof

Abstract: The invention provides an activated alumina and activated carbon compounded material and a preparation method thereof. According to a formula, the material comprises the following raw materials in percentage by mass: 40 to 99 percent of aluminum hydroxide, 1 to 60 percent of activated carbon, and 15 to 35 percent of binder. The material is prepared by uniformly mixing, pelleting, ageing, molding, airing, sintering, rinsing, drying and the like. The invention aims to compound the activated carbon with the activated alumina; on the one hand, the material with a certain shape can be processed, the defects of loose shape, low strength, difficult recovery and the like of the activated carbon are overcome, and the material is easy to recycle; and on the other hand, the adsorption property of the activated alumina material is greatly improved. The method has the advantages of simpleness, practicality, readily available raw materials, low cost and suitability for industrial mass production, and can be widely applied to various fields such as industry, agriculture, environmental protection, air purification, water treatment and the like.