Showing papers on "Aldose published in 1969"
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TL;DR: Three Mn2+-dependent bacterial aldose-ketose isomerases were examined to determine the stereochemistry of the C-1 proton of the ketose that is abstracted in the formation of the aldehyde, where retention of the substrate proton is complete.
56 citations
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TL;DR: Glucose 6-phosphate, various aldose 1-ph phosphates, and their corresponding sugar nucleotides have been converted into trimethylsilyl ethers and gas chromatographed to yield the TMS ether of the sugar anhydride.
14 citations
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TL;DR: Examination of the NMR proton signals arising from C-1 of D, as it is formed from D in deuterium oxide via the phosphoglucose isomerase reaction verify that the transformation occurs by a combination of C-2 proton exchange with solvent, and intramolecular hydride transfer, and indicates the stereospecific formation of D from D during the interconversion.
3 citations