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Aldose

About: Aldose is a research topic. Over the lifetime, 1270 publications have been published within this topic receiving 27197 citations. The topic is also known as: aldoses.


Papers
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Journal ArticleDOI
TL;DR: In this article, the authors investigated the kinetics of reduction of dodecatungstocobaltate (III) by D-fructose, D-glucose, and D-mannose in aqueous media.
Abstract: The kinetics of reduction of dodecatungstocobaltate (III) by D-fructose, D-glucose, and D-mannose in aqueous media have been investigated. A pseudo-zero-order rate was obtained with the ketose and the reaction was acid-dependent. On the contrary, pseudo-second-order rates were obtained for the aldose reactions. The reactions were catalysed by metal ions in the supporting electrolyte; the cation catalytic order K+ > Na+ Li+ observed for aldose oxidation is explained on the basis of electrostatic considerations. A mechanism for the ketose oxidation is offered based on keto–enol tautomerism; the aldose oxidations are explained in terms of a transition state formed via ion-induced dipole bridging.

26 citations

Journal ArticleDOI
TL;DR: A purification scheme for aldose reductase developed using bovine lens tissue including an affinity chromatographic step is presented which is particularly suited for small quantities of lenses.

26 citations

Journal ArticleDOI
TL;DR: In this paper, the effects of sugar structure (size, position of carbonyl group, and charge state) on the thermostability of β-lactoglobulin (β-lg) when controlling the glycation extent of reducing sugars to the same level was studied.

26 citations

Journal ArticleDOI
Ronald W. McClard1
TL;DR: In this paper, a single-step approach to the synthesis of aldose sugar phosphonates substituted at C-1, the anomeric carbon, is demonstrated through the example of the isosteric methylene analog of α- D -ribose-1-phosphate.

25 citations


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Performance
Metrics
No. of papers in the topic in previous years
YearPapers
20233
20226
20213
20207
20196
201813