Topic
Aldose
About: Aldose is a research topic. Over the lifetime, 1270 publications have been published within this topic receiving 27197 citations. The topic is also known as: aldoses.
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26 citations
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TL;DR: In this article, the authors investigated the kinetics of reduction of dodecatungstocobaltate (III) by D-fructose, D-glucose, and D-mannose in aqueous media.
Abstract: The kinetics of reduction of dodecatungstocobaltate (III) by D-fructose, D-glucose, and D-mannose in aqueous media have been investigated. A pseudo-zero-order rate was obtained with the ketose and the reaction was acid-dependent. On the contrary, pseudo-second-order rates were obtained for the aldose reactions. The reactions were catalysed by metal ions in the supporting electrolyte; the cation catalytic order K+ > Na+ Li+ observed for aldose oxidation is explained on the basis of electrostatic considerations. A mechanism for the ketose oxidation is offered based on keto–enol tautomerism; the aldose oxidations are explained in terms of a transition state formed via ion-induced dipole bridging.
26 citations
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TL;DR: A purification scheme for aldose reductase developed using bovine lens tissue including an affinity chromatographic step is presented which is particularly suited for small quantities of lenses.
26 citations
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TL;DR: In this paper, the effects of sugar structure (size, position of carbonyl group, and charge state) on the thermostability of β-lactoglobulin (β-lg) when controlling the glycation extent of reducing sugars to the same level was studied.
26 citations
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TL;DR: In this paper, a single-step approach to the synthesis of aldose sugar phosphonates substituted at C-1, the anomeric carbon, is demonstrated through the example of the isosteric methylene analog of α- D -ribose-1-phosphate.
25 citations