Topic
Alkylation
About: Alkylation is a research topic. Over the lifetime, 29915 publications have been published within this topic receiving 464944 citations. The topic is also known as: alkylation reaction.
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TL;DR: This procedure expands the scope of ortho alkylation to the direct ortho functionalization of aromatic ketones with functionalized alkenes and corresponding ortho-alkylated ketones were obtained after hydrolysis.
106 citations
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TL;DR: The enantioselective alkylation of α,β-unsaturated aldehydes with stabilized carbocations as electrophiles via the activation as dienamine intermediates is described, allowing for the first enantiOSElective γ-alkylation of linear α, β-unsubstituted enals.
106 citations
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TL;DR: Alkylation of enamines and enamine salts followed by a cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds as mentioned in this paper.
Abstract: Alkylation of enamines and enamine salts followed by a cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds
106 citations
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TL;DR: In this paper, a comparison of the isomers produced by toluene disproportionation to produce p -xylene (and benzene) with alkylation to produce ethyltoluene, revealed that with the same catalyst, it is more para-selective than xylene.
106 citations
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TL;DR: In the absence of an external reductant, C3-cycloalkylated indole could be synthesized through reductive alkylation of indole with cyclic ketone using a sulfonyl-functionalized Bronsted acid ionic liquid as a catalyst as mentioned in this paper.
106 citations