Alloy

About: Alloy is a research topic. Over the lifetime, 171884 publications have been published within this topic receiving 1719420 citations. The topic is also known as: alloys.

Crystallization of silicon dioxide and compositional evolution of the Earth’s core

Abstract: Melting experiments with liquid Fe–Si–O alloy at the pressure of the Earth’s core reveal that the crystallization of silicon dioxide leads to core convection and a dynamo. The Earth's core contains large amounts of iron (Fe), but its density, about ten per cent less than that of pure iron, indicates the presence of lighter elements in the outer core, potentially including silicon (Si) and oxygen (O). To simulate the early Earth, Kei Hirose and co-authors present melting experiments on liquid Fe–Si–O alloy at the pressures of the Earth's core in a laser-heated diamond-anvil cell. They find that an initial Fe–Si–O core would be able to crystallize silicon dioxide (SiO2) as it cools. The authors conclude that if crystallization proceeds from the top of the core, the sinking of SiO2-depleted Fe–Si–O liquid would have been more than enough to power core convection and a dynamo in the early Earth. The Earth’s core is about ten per cent less dense than pure iron (Fe), suggesting that it contains light elements as well as iron. Modelling of core formation at high pressure (around 40–60 gigapascals) and high temperature (about 3,500 kelvin) in a deep magma ocean1,2,3,4,5 predicts that both silicon (Si) and oxygen (O) are among the impurities in the liquid outer core6,7,8,9. However, only the binary systems Fe–Si and Fe–O have been studied in detail at high pressures, and little is known about the compositional evolution of the Fe–Si–O ternary alloy under core conditions. Here we performed melting experiments on liquid Fe–Si–O alloy at core pressures in a laser-heated diamond-anvil cell. Our results demonstrate that the liquidus field of silicon dioxide (SiO2) is unexpectedly wide at the iron-rich portion of the Fe–Si–O ternary, such that an initial Fe–Si–O core crystallizes SiO2 as it cools. If crystallization proceeds on top of the core, the buoyancy released should have been more than sufficient to power core convection and a dynamo, in spite of high thermal conductivity10,11, from as early on as the Hadean eon12. SiO2 saturation also sets limits on silicon and oxygen concentrations in the present-day outer core.

XRD and XPS Study of Cu−Ni Interactions on Reduced Copper−Nickel−Aluminum Oxide Solid Solution Catalysts

Abstract: Copper−nickel−aluminum oxide solid solutions were reduced in hydrogen to produce alumina-supported copper−nickel alloy catalysts. XRD patterns of reduced oxides showed that the type of active metals which emerged upon reduction were sensitive to the reduction temperature and the copper content. Variations from +0.8 to +1 eV were found in the experimental Ni 2p3/2 binding energy (BE) of nickel in the solid solutions compared to the experimental Ni 2p3/2 BE of bulk nickel, attributed to the Ni−Ni arrangements in the solid solution. Also, when the curve-fitted BE values of Ni 2p3/2 and Cu 2p3/2 of different reduced solid solutions were compared, it was found that copper and nickel were in different chemical states depending on reduction temperature and the amount of the copper. Changes in Ni 2p3/2 BE in the reduced solid solutions were also discussed in terms of the filling of nickel d-hole bands due to nickel−copper d−d band interactions. At both high copper content and reduction temperature, copper had a t...

Structure and Reactivity of Ni−Au Nanoparticle Catalysts

Abstract: We discuss the design of a Ni−Au nanoparticle catalyst system, which is based on the detailed experimental and theoretical understanding of the alloying and the chemical reaction processes on single-crystal surfaces. The alloy formation and structure of Ni−Au catalysts supported on SiO2 and on MgAl2O4 are simulated by Monte Carlo schemes as well as experimentally studied by a combination of in situ X-ray absorption fine structure, transmission electron microscopy, and in situ X-ray powder diffraction. On-line mass spectrometry is used to follow the reactivity of the catalyst and thermogravimetric analysis provided information on the deposition rate of carbon during steam reforming of n-butane. The simulations and the experiments give evidence for the formation of a Ni−Au surface alloy on the Ni particles for both supports. The Ni−Au catalysts exhibiting the surface alloy are active for steam reforming and are more resistant toward carbon formation than the pure Ni catalyst. Blocking of highly reactive Ni ...