Ammonium perchlorate

About: Ammonium perchlorate is a research topic. Over the lifetime, 2359 publications have been published within this topic receiving 33412 citations. The topic is also known as: AP.

The influence of porosity of ammonium perchlorate (AP) on the thermomechanical and thermal properties of the AP/polyvinylchloride (PVC) composite propellants

Abstract: The influence of porous ammonium perchlorate (POAP) on the thermomechanical and combustion behavior of solid rocket propellants based on polyvinylchloride binder has been investigated. Differential scanning calorimetry, differential thermogravimetry, dynamic mechanical thermal analysis, and scanning electronic microscopy measurements were used for thermomechanical and thermal decomposition properties assessment. The results obtained indicate that lower glass transitions of the propellants and catalytic effect of combustion are obtained with POAP.

Direct Growth of CuO Nanorods on Graphitic Carbon Nitride with Synergistic Effect on Thermal Decomposition of Ammonium Perchlorate

Abstract: Novel graphitic carbon nitride/CuO (g-C₃N₄/CuO) nanocomposite was synthesized through a facile precipitation method. Due to the strong ion-dipole interaction between copper ions and nitrogen atoms of g-C₃N₄, CuO nanorods (length 200-300 nm, diameter 5-10 nm) were directly grown on g-C₃N₄, forming a g-C₃N₄/CuO nanocomposite, which was confirmed via X-ray diffraction (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), and X-ray photoelectron spectroscopy (XPS). Finally, thermal decomposition of ammonium perchlorate (AP) in the absence and presence of the prepared g-C₃N₄/CuO nanocomposite was examined by differential thermal analysis (DTA), and thermal gravimetric analysis (TGA). The g-C₃N₄/CuO nanocomposite showed promising catalytic effects for the thermal decomposition of AP. Upon addition of 2 wt % nanocomposite with the best catalytic performance (g-C₃N₄/20 wt % CuO), the decomposition temperature of AP was decreased by up to 105.5 °C and only one decomposition step was found instead of the two steps commonly reported in other examples, demonstrating the synergistic catalytic activity of the as-synthesized nanocomposite. This study demonstrated a successful example regarding the direct growth of metal oxide on g-C₃N₄ by ion-dipole interaction between metallic ions, and the lone pair electrons on nitrogen atoms, which could provide a novel strategy for the preparation of g-C₃N₄-based nanocomposite.

Experimental and modeling studies of two-dimensional ammonium perchlorate diffusion flames

Abstract: We investigated two-dimensional axisymmetric diffusion flames in which the surface decomposition products of ammonium perchlorate (AP) combustion provided the coflow for a methane fuel stream. The two-dimensional problem was solved using the fully elliptic formulation of the governing equations. By utilizing recent developments in hydrocarbon, chlorine, NO x , and AP kinetics, we formulated a detailed transport, finite rate chemistry system for the temperature, velocities, vorticity, and species mass fractions of the combined flame system. We compared the results of this model with a series of experimental measurements in which the temperature was measured with OH rotational population distribution, and the transient species OH, CN, and NH were measured with planar laser-induced fluorescence and emission spectroscopy. The kinetic mechanism, previously validated in one-dimensional experiments, was found to give good results in the two-dimensional model when compared with the experiments. The two-dimensional model can be used to understand the effects of solid propellant heterogeneity on combustion zone microstructure and the location and structure of heat release zones that control the propellant ballistic properties. It is a first step in developing computer codes that can a priori predict propellant ballistic behavior via modeling, thereby partially supplanting expensive physical formulation and testing.