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Showing papers on "Ammonium tetrathiomolybdate published in 1977"


Journal ArticleDOI
TL;DR: By Fourier transform high-resolution NMR spectroscopy, the 95Mo resonance lines of the tetrathiomolybdate species Mo32S42− and Mo 32S334S2− have been resolved in aqueous solutions of potassium-and ammonium tetrathymolebdate.
Abstract: By Fourier transform high resolution NMR spectroscopy the95Mo resonance lines of the tetrathiomolybdate species Mo32S42− and Mo32S334S2− have been resolved in aqueous solutions of potassium- and ammonium tetrathiomolybdate. An isotope effect on the Larmor frequency of (0.09±0.01) ppm to lower frequency was found for the substitution of a32S atom by a34S atom in the MoS42− ion.

14 citations