scispace - formally typeset
Search or ask a question
Topic

Annulation

About: Annulation is a research topic. Over the lifetime, 10152 publications have been published within this topic receiving 189701 citations.


Papers
More filters
Journal ArticleDOI
TL;DR: To the authors' knowledge, this is the first example in which the NH unit of indole is used as a directing group for an intramolecular C(sp2)-H bond functionalization to give benzo[a]carbazole derivatives.

114 citations

Journal ArticleDOI
TL;DR: An efficient one-pot synthetic protocol has been proposed for the synthesis of luntonin F from easily available starting materials usingiodination, Kornblum oxidation, and annulation through a rational logical design.

113 citations

Journal ArticleDOI
TL;DR: The first phosphine-catalyzed [4 + 2] annulation of γ-substituted allenoates with 2-arylidene-1H-indenes-1,3(2H)-diones is disclosed, offering a powerful approach to the construction of highly substituted spiro[4.5]dec-6-ene skeletons in excellent yields, and with complete regioselectivity and high diastereoselectivities.

113 citations

Journal ArticleDOI
TL;DR: An enantioselective formal [3+3] annulation reaction of cyclic ketones with enones has been developed and it is shown that the reactions afford bicyclo [3.3.1] adducts in moderate to good yields with good to high enantiOSElectivities under mild conditions.

113 citations

Journal ArticleDOI
TL;DR: A phosphine-catalyzed [4 + 3] annulation of modified allylic carbonates with methyl coumalate was developed and offered a powerful method for the construction of bicyclo[3.2.2]nonadiene skeleton with high stereoselectivity.

113 citations


Network Information
Related Topics (5)
Cycloaddition
39.9K papers, 728.7K citations
97% related
Enantioselective synthesis
58.1K papers, 1.6M citations
97% related
Aryl
95.6K papers, 1.3M citations
96% related
Nucleophile
30.8K papers, 602.8K citations
95% related
Lewis acids and bases
29.5K papers, 631.7K citations
93% related
Performance
Metrics
No. of papers in the topic in previous years
YearPapers
2023468
2022850
2021754
2020618
2019699
2018603