Topic
Aquation
About: Aquation is a research topic. Over the lifetime, 1443 publications have been published within this topic receiving 17507 citations.
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2 citations
TL;DR: In this paper, a trans diastereoisomer of dichloro (meso-5,12-dimethyl-1,4,8,11 -tetraazacyclotetradecane)-cobalt(m) perchlorate has been prepared, and the electronic absorption and infrared spectral data studied.
Abstract: A new trans diastereoisomer of dichloro(meso-5,12-dimethyl-1,4,8,11 -tetraazacyclotetradecane)-cobalt(m) perchlorate has been prepared, and the electronic absorption and infrared spectral data studied. The assignments of the structure of the isomer have been accomplished by thorough stereochemical analysis combined with 1H and 13C NMR spectral data. Aquation kinetics have been studied at various temperatures and activation parameters determined. The results indicate a dissociative activation with retention of configuration and a distorted-square pyramidal activated complex.
2 citations
TL;DR: Cr(II) reagit avec l'iodoacetamide pour donner (H 2 O) 5 CrI 2+, (CCH 3 3+ )CCH 2 CO(NH 2 ) 2+ as discussed by the authors.
Abstract: Cr(II) reagit avec l'iodoacetamide pour donner (H 2 O) 5 CrI 2+ , (H 2 O) 5 CrO(NH 2 )CCH 3 3+ et (H 2 O) 5 CrCH 2 CO(NH 2 ) 2+ . Mesures des vitesses d'equation
2 citations
TL;DR: In this article, the reaction of trans |Ru(NO)(NO 2 ) 4 (OH)| 2− with barbituric acid, does not give barbiturateato complexes but instead leads to the formation of complexes of violurate acid, that is to say the corresponding oxime.
2 citations
2 citations