Topic
Aquation
About: Aquation is a research topic. Over the lifetime, 1443 publications have been published within this topic receiving 17507 citations.
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TL;DR: The kinetics of the one-step aquation of tetrachloro-and tetrabromopalladate anions in aqueous solutions were studied in this paper.
Abstract: 1.
The kinetics of the one-step aquation of tetrachloro- and tetrabromopalladate anions in aqueous solutions were studied.
2.
The rate constants for the forward and reverse reactions at 25–45° were found, and the activation parameters were determined.
1 citations
TL;DR: The second-order rate constants for mercury and thallium-III-induced aquations of trans-Co(DH) 2 (R-py)Cl] have been measured in 40% v/v ethanol solution over a range of temperatures.
1 citations
1 citations
TL;DR: In this paper, rate and equilibrium constants for the interaction of L-cysteine with vitamin B12a have been determined in aqueous solutions in the absence and in the presence of air as functions of pH, buffer concentration, and temperature.
Abstract: Rate and equilibrium constants for the interaction of L-cysteine with vitamin B12a have been determined in aqueous solutions in the absence and in the presence of air as functions of pH, buffer concentration, and temperature. Kinetic treatment of the data has afforded the pH-independent rate constants for the anation of aquo- and hydroxocobalamins by L-cysteine, for the aquation of the vitamin B12–L-cysteine complexes, and for the formation of vitamin B12r from the L-cysteine complex of vitamin B12a. The mechanism of these reactions is discussed.
1 citations