Topic
Aquation
About: Aquation is a research topic. Over the lifetime, 1443 publications have been published within this topic receiving 17507 citations.
Papers published on a yearly basis
Papers
More filters
TL;DR: The syntheses, structures and biological evaluation of a series of cisplatin-like complexes containing bis(imidazole) derivatives - the so-called Joseph ligands - are described and their cytotoxicity is discussed.
17 citations
17 citations
TL;DR: In this article, the aquation of pyridinones when dissolved in water has been examined by NMR spectroscopy and conductivity measurements and the results indicate an equilibrium between chloro and aqua species which is fast on the NMR time-scale.
Abstract: Picolinic acid (pyridine-2-carboxylic acid), pyrones and pyridinones (HL) reacted with [{Rh(C5Me5)Cl2}2] and sodium methoxide to give complexes [Rh(C5Me5)Cl(L)] which are all soluble in water. The structures where HL = picolinic acid or 2-methylpyran-4-one have been determined by X-ray diffraction. The aquation of the complexes when dissolved in water has been examined by NMR spectroscopy and conductivity measurements and the results indicate an equilibrium between chloro and aqua species which is fast on the NMR time-scale.
17 citations
17 citations
TL;DR: In this paper, it was shown that Co(CN)63− photoaquation reaction can be controlled by using appropriate receptor molecules, showing that it may be possible to control and orient the ligand photosubstitution reactions of transition metal complexes.
Abstract: Enclosure of Co(CN)63–into a polyammoniumm macrocyclic ligand partially hinders the CN– photoaquation reaction, showing that it may be possible to control and orient the ligand photosubstitution reactions of transition metal complexes by using appropriate receptor molecules.
17 citations