Showing papers on "Austenite published in 2022"

Refinement mechanism of cerium addition on solidification structure and sigma phase of super austenitic stainless steel S32654

Abstract: The influence of Ce addition on the solidification structure and σ phase of super austenitic stainless steel S32654 was systematically investigated via microstructural characterization and thermodynamic calculation. The results indicate that a small addition of Ce could modify MgO and MnS into Ce-bearing inclusions Ce2O3 and Ce2O2S. Ce addition led to noticeable refinement of both the dendrite structure and σ phase. The refinement mechanism could be attributed to the combined actions of effective Ce-bearing inclusions and solute Ce. Effective Ce-bearing inclusions could serve as heterogeneous nucleation cores of austenite as well as σ phase, which provided a favorable prerequisite for their refinement. Solute Ce significantly enhanced the undercooling degree of the system, further promoting dendrite structure refinement. Meanwhile, solute Ce improved the eutectic precipitation conditions of σ phase and further promoted its nucleation, while the dendrite refinement limited its growth space. Finally, more fine and dispersed σ phase particles formed in S32654 with Ce addition. The refinement of dendrite structure and σ phase will reduce the temperature and time required for high-temperature homogenization, which is beneficial to the hot working of this steel.

Electron beam freeform fabrication of NiTi shape memory alloys: Crystallography, martensitic transformation, and functional response

Abstract: In this work, NiTi shape memory alloys parts were additively manufactured using electron beam freeform fabrication (EBF 3 ) under different processing parameters, including the beam current, travel speed, and wire feeding speed. The forming quality, phase composition, microstructure change, crystallography, martensitic transformation, shape memory and superelastic responses were systematically investigated. All deposits mainly consisted of B2-austenite at room temperature, and a handful of B19′-martensite and submicron-sized Ti 4 Ni 2 O x precipitates were also detected. The martensitic transformation of NiTi alloys prepared by EBF 3 -technique possessed an individual reversible path between B2 and B19′ upon heating/cooling. The optimized deposit possessed the best comprehensive properties, where the values of the relative density, shape memory recovery and superelastic recovery ratios were 99.6%, 98.95%, and 55.78%, respectively. Furthermore, the dependence of the martensitic transformation behavior on the thermomechanical condition and the relationship between plastic deformation and phase transformation during superelastic deformation are discussed in detail. Our work details that the EBF 3 provides a suitable way for the complex fabrication of large-scaled parts based on shape memory alloys. • NiTi shape memory alloys parts were additively manufactured using electron beam freeform fabrication under different processing parameters. • The fabricated NiTi alloys presented a single reversible martensitic transformation (B2 ↔ B19’) upon heating/cooling. • The optimized deposit had shape memory recovery and superelastic recovery ratios of 98.95%, and 55.78%, respectively. • The dependence of the martensitic transformation behavior on the thermomechanical condition is discussed.

Experimental investigation on the effect of gas tungsten arc welding current modes upon the microstructure, mechanical, and fractography properties of welded joints of two grades of AISI 316L and AISI310S alloy metal sheets

Abstract: In this investigation, dissimilar welded joints of AISI 316 L and AISI 310S stainless steels were produced using continuous and pulsed modes current of the gas tungsten arc welding process. A filler metal type ER309L was used to strengthen the welded joints. The fracture mode of the tensile and Charpy impact test samples was studied using a field emission scanning electron microscope (FE-SEM). Results showed that the welded joints were broken in the 316 L steel side during the tensile test due to the presence of lower alloying elements in this steel compared with the AISI 310S stainless steel. As well, microhardness and Charpy impact tests results showed that changing the welding current from continuous to the pulsed one increased the values of these two mentioned attributes. Fractography analysis, performed on the fracture surfaces of both joints, showed a completely ductile fracture under both tensile and Charpy impact tests. Moreover, microstructural observations showed that the weld metal (WM) structure was austenitic-ferritic (AF) and contained columnar and equiaxed dendrites. Changing the welding current from the continuous to the pulsed one led to the transformation of the columnar dendrites to the very fine equiaxed dendrites. This welding current variation reduced the dendrite size of the WM and decreased the area of the unmixed zone (UMZ). Finally, XRD results indicated that austenite was the predominant phase in the welded joints.

Evolution of microstructure and mechanical properties in 2205 duplex stainless steels during additive manufacturing and heat treatment

Abstract: Metal additive manufacturing (AM) offers exceptional design freedom, but its high thermal gradients often generate non-equilibrium microstructures with chemical and interfacial instabilities. Steels that solidify as δ-ferrite often experience a further solid-state phase transformation to austenite during AM. The detailed nature of this phase transformation during AM is yet to be fully understood. Duplex stainless steel, which is known for its unique combination of high corrosion resistance and mechanical properties, is a suitable alloy to further study this phase transformation. The current study aims to gain novel insights into solid-state phase transformations and mechanical properties of duplex stainless steels during laser powder-bed fusion (LPBF). As-printed microstructures exhibit significant deviations when compared to conventionally manufactured counterparts in terms of phase balance and morphology, elemental partitioning, and interface character distribution. During LPBF, only a small fraction of austenite forms, mostly at the ferrite-ferrite grain boundaries, via a phase transformation accompanied by diffusion of interstitials. Austenite/ferrite boundaries are shown to terminate on {100}F//{111}A planes. This is due to the character of parent ferrite-ferrite boundaries which is dictated by the sharp <100> texture and geometry of austenite grains induced by directional solidification and epitaxial growth of ferrite. Benchmarking mechanical properties against a wrought counterpart demonstrates that AM offers high strength but relatively low ductility and impact toughness. A short heat treatment reverts the microstructure back to its equilibrium state resulting in balanced tensile and toughness properties, comparable to or even better than those of wrought counterparts.

Plasma spheroidization of gas-atomized 304L stainless steel powder for laser powder bed fusion process

Abstract: Particles of AISI 304L stainless steel powder were spheroidized by the induction plasma spheroidization process (TekSphero-15 spheroidization system) to assess the effects of the spheroidization process on powder and part properties. The morphology of both as-received and spheroidized powders was characterized by measuring particle size and shape distribution. The chemistry of powders was studied using inductively coupled plasma optical emission spectroscopy for evaluation of composing elements, and the powder’s microstructure was assessed by X-ray diffraction for phase identification and by electron backscattered diffraction patterns for crystallography characterization. The Revolution Powder Analyzer was used to quantify powder flowability. The mechanical properties of parts fabricated with as-received and spheroidized powders using laser powder bed fusion process were measured and compared. Our experimental results showed that the fabricated parts with plasma spheroidized powder have lower tensile strength but higher ductility. Considerable changes in powder chemistry and microstructure were observed due to the change in solidification mode after the spheroidization process. The spheroidized powder solidified in the austenite-to-ferrite solidification mode due to the loss of carbon, nitrogen, and oxygen. In contrast, the as-received powder solidified in the ferrite-to-austenite solidification mode. This change in solidification mode impacted the components made with spheroidized powder to have lower tensile strength but higher ductility.

In-situ SEM investigation on stress-induced microstructure evolution of austenitic stainless steels subjected to cavitation erosion and cavitation erosion-corrosion

Abstract: This study investigated the effect of stress on the microstructure evolution of austenitic stainless steels (316L SS and 304 SS) subjected to cavitation erosion and cavitation erosion-corrosion. Results show that continuous accumulation of stress of austenitic stainless steels at the early stage of cavitation erosion was observed from the samples tested in deionised water (DIW) but not in artificial seawater (ASW), which is due to stress release induced by ASW. In addition, a stress-induced phase transformation from austenite to martensite during the cavitation erosion tests in both DIW and ASW was observed in 304 SS, but not in 316 SS. Furthermore, primary cavitation craters formed during the cavitation erosion were not expanded directly but shrank first and then expanded due to re-accumulation of stress. More importantly, this study reports for the first time that pre-existing pores are not initiation points of cavitation erosion damage, possibly because of the ductility of austenitic stainless steels, which resulted in continuous shrinkage of the pores caused by the accumulated stress. Our findings provide new insights into understanding the failure mechanisms of austenitic stainless steels subjected to cavitation erosion, which will inform the development of high-performance cavitation erosion-resistant materials.