Topic
Barium permanganate
About: Barium permanganate is a(n) research topic. Over the lifetime, 20 publication(s) have been published within this topic receiving 124 citation(s).
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27 citations
TL;DR: In this article, the authors used barium permanganate in refluxing acetonitrile to perform sulfide oxidation to their sulfoxides, which was performed with barium-peranganate.
Abstract: Oxidation of sulfides to their sulfoxides is performed well with barium permanganate in refluxing acetonitrile.
25 citations
TL;DR: Benzylic oximes are oxidized selectively with barium permanganate in refluxing acetonitrile and produce their corresponding carbonyl compounds in good yields as discussed by the authors.
Abstract: Benzylic oximes are oxidized selectively with barium permanganate in refluxing acetonitrile and produce their corresponding carbonyl compounds in good yields.
20 citations
TL;DR: Barium permanganate is an easily prepared, stable, and a versatile oxidation reagent as discussed by the authors, and it can be used to transform primary and secondary hydroxy compounds to their carbonyl derivatives.
Abstract: Barium Permanganate is an easily prepared, stable, and a versatile oxidation reagent. With this reagent different types of primary and secondary hydroxy compounds are converted to their carbonyl derivatives. Aldehydes could be transformed to their carboxylic acids. Benzylic chloride and bromides are converted to their aldehydes and carboxylic acids. Semicarbazide and 2,4-dinitrophenylhydrazine derivatives of benzylic carbonyl compounds undergo carbon-nitrogen bond cleavage selectively and yield the expected carbonyl compounds. p-Hydroquinone is converted to p-benzoguinone and aromatic amines to their azo compounds. Anthracene and phenanthrene produce their 9,10-quinones. Diphenyl acetylene and trans stilbene give benzil, and styrene produces benzaldehyde. Selective oxidations of secondary benzylic carbon-hydrogen bonds occur and the corres- ponding carbonyl compounds are produced in good yields.
16 citations
TL;DR: In this paper, stoicheiometries have been found for the oxidation of hydrazine in aqueous solution by tricarbonatocobaltate(III), barium permanganate, ethylenediaminetetra-acetatomanganate (III), trispyrophosphatomaganate( III), hexachloroiridate(IV), octacyanomolybdate(V), and sulphite by the last three of these complexes.
Abstract: Stoicheiometries have been found for the oxidation of hydrazine in aqueous solution by tricarbonatocobaltate(III), barium permanganate, ethylenediaminetetra-acetatomanganate(III), trispyrophosphatomanganate(III), hexachloroiridate(IV), octacyanomolybdate(V), and of sulphite by the last three of these complexes. The results are discussed with reference to the lability of the complexes to ligand-substitution.
14 citations