Showing papers on "Basalt published in 2014"

Mineralogy of the Martian Surface

Abstract: The past fifteen years of orbital infrared spectroscopy and in situ exploration have led to a new understanding of the composition and history of Mars. Globally, Mars has a basaltic upper crust with regionally variable quantities of plagioclase, pyroxene, and olivine associated with distinctive terrains. Enrichments in olivine (>20%) are found around the largest basins and within late Noachian–early Hesperian lavas. Alkali volcanics are also locally present, pointing to regional differences in igneous processes. Many materials from ancient Mars bear the mineralogic fingerprints of interaction with water. Clay minerals, found in exposures of Noachian crust across the globe, preserve widespread evidence for early weathering, hydrothermal, and diagenetic aqueous environments. Noachian and Hesperian sediments include paleolake deposits with clays, carbonates, sulfates, and chlorides that are more localized in extent. The late Hesperian to Amazonian mineralogic record of water is sparser, though sulfates and silica in some locations indicate local availability of ground and surface waters even in the most recent geologic epoch.

4.21 – One View of the Geochemistry of Subduction-Related Magmatic Arcs, with an Emphasis on Primitive Andesite and Lower Crust

Abstract: This chapter has four main aims. Provide a comprehensive picture of the composition of volcanic rocks from subduction-related magmatic arcs. Review evidence in favor of the existence of andesitic, as well as basaltic primary magmas in arcs. Present new data on the composition of arc lower crust, based mainly on our work on the Talkeetna arc section in southcentral Alaska. Summarize evidence from arc lower crustal sections that a substantial proportion of the dense, lower crustal pyroxenites and garnet granulites produced by crystal fractionation are missing.

Elemental Geochemistry of Sedimentary Rocks at Yellowknife Bay, Gale Crater, Mars.

Abstract: Sedimentary rocks examined by the Curiosity rover at Yellowknife Bay, Mars, were derived from sources that evolved from an approximately average martian crustal composition to one influenced by alkaline basalts. No evidence of chemical weathering is preserved, indicating arid, possibly cold, paleoclimates and rapid erosion and deposition. The absence of predicted geochemical variations indicates that magnetite and phyllosilicates formed by diagenesis under low-temperature, circumneutral pH, rock-dominated aqueous conditions. Analyses of diagenetic features (including concretions, raised ridges, and fractures) at high spatial resolution indicate that they are composed of iron- and halogen-rich components, magnesium-iron-chlorine–rich components, and hydrated calcium sulfates, respectively. Composition of a cross-cutting dike-like feature is consistent with sedimentary intrusion. The geochemistry of these sedimentary rocks provides further evidence for diverse depositional and diagenetic sedimentary environments during the early history of Mars.

Distinctive composition of copper-ore-forming arcmagmas

Abstract: Magmatic fertility to generate porphyry- and high-sulfidation copper ore deposits generally develops, not at the scale of individual igneous complexes, but rather at the scale of petrochemical provinces spanning hundreds of kilometres of arc length, and containing many igneous complexes. The extent and duration of copper metallogenic provinces and epochs are apparently controlled by geodynamically imposed compressive stress that commonly lasts ca 5–20 Ma and fosters entrapment of mantle-derived basaltic magmas in chambers near the Moho where they cool very slowly and are likely to last long enough to experience intermittent replenishment during fractional crystallisation of layered ultramafic–mafic cumulate complexes on the chamber floor. Accumulation of dissolved H2O through multiple cycles of replenishment and crystallisation in high-pressure magma chambers can explain the distinguishing chemical features of copper-ore-forming calc-alkalic arc magmas. The distinguishing features include unusually high c...

The Emeishan large igneous province: A synthesis

Abstract: The late Permian Emeishan large igneous province (ELIP) covers ∼0.3 × 106 km2 of the western margin of the Yangtze Block and Tibetan Plateau with displaced, correlative units in northern Vietnam (Song Da zone). The ELIP is of particular interest because it contains numerous world-class base metal deposits and is contemporaneous with the late Capitanian (∼260 Ma) mass extinction. The flood basalts are the signature feature of the ELIP but there are also ultramafic and silicic volcanic rocks and layered mafic-ultramafic and silicic plutonic rocks exposed. The ELIP is divided into three nearly concentric zones (i.e. inner, middle and outer) which correspond to progressively thicker crust from the inner to the outer zone. The eruptive age of the ELIP is constrained by geological, paleomagnetic and geochronological evidence to an interval of ≤3 Ma. The presence of picritic rocks and thick piles of flood basalts testifies to high temperature thermal regime however there is uncertainty as to whether these magmas were derived from the subcontinental lithospheric mantle or sub-lithospheric mantle (i.e. asthenosphere or mantle plume) sources or both. The range of Sr (ISr ≈ 0.7040–0.7132), Nd (ɛNd(t) ≈ −14 to +8), Pb (206Pb/204Pb1 ≈ 17.9–20.6) and Os (γOs ≈ −5 to +11) isotope values of the ultramafic and mafic rocks does not permit a conclusive answer to ultimate source origin of the primitive rocks but it is clear that some rocks were affected by crustal contamination and the presence of near-depleted isotope compositions suggests that there is a sub-lithospheric mantle component in the system. The silicic rocks are derived by basaltic magmas/rocks through fractional crystallization or partial melting, crustal melting or by interactions between mafic and crustal melts. The formation of the Fe-Ti-V oxide-ore deposits is probably due to a combination of fractional crystallization of Ti-rich basalt and fluxing of CO2-rich fluids whereas the Ni-Cu-(PGE) deposits are related to crystallization and crustal contamination of mafic or ultramafic magmas with subsequent segregation of a sulphide-rich portion. The ELIP is considered to be a mantle plume-derived LIP however the primary evidence for such a model is less convincing (e.g. uplift and geochemistry) and is far more complicated than previously suggested but is likely to be derived from a relatively short-lived, plume-like upwelling of mantle-derived magmas. The emplacement of the ELIP may have adversely affected the short-term environmental conditions and contributed to the decline in biota during the late Capitanian.

Paleo‐Pacific subduction‐accretion: Evidence from Geochemical and U‐Pb zircon dating of the Nadanhada accretionary complex, NE China

Abstract: The Nadanhada Terrane, located along the eastern margin of Eurasia, contains a typical accretionary complex related to paleo-Pacific plate subduction-accretion. The Yuejinshan Complex is the first stage accretion complex that consists of meta-clastic rocks and metamafic-ultramafic rocks, whereas the Raohe Complex forms the main parts of the terrane and consists of limestone, bedded chert, and mafic-ultramafic rocks embedded as olistolith blocks in a weakly sheared matrix of clastic meta-sedimentary rocks. Geochemical data indicate that the Yuejinshan metabasalts have normal mid-ocean ridge basalt (N-MORB) affinity, whereas the Raohe basaltic pillow lavas have an affinity to ocean island basalts (OIB). Sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon analyses of gabbro in the Raohe Complex yield a weighted mean 206Pb/238U zircon age of 216 ± 5 Ma, whereas two samples of granite intruded into the complex yield weighted mean 206Pb/238U zircon ages of 128 ± 2 and 129 ± 2 Ma. Laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) U-Pb zircon analyses of basaltic pillow lava in the Raohe Complex define a weighted mean age of 167 ± 1 Ma. Two sandstone samples in the Raohe Complex record younger concordant zircon weighted mean ages of 167 ± 17 and 137 ± 3 Ma. These new data support the view that accretion of the Raohe Complex was between 170 and 137 Ma, and that final emplacement of the Raohe Complex took place at 137–130 Ma. The accretion of the Yuejinshan Complex probably occurred between the 210 and 180 Ma, suggesting that paleo-Pacific plate subduction was initiated in the Late Triassic to Early Jurassic.

Variations in Fe3+/∑Fe of Mariana Arc Basalts and Mantle Wedge fO2

Abstract: Arc basalts are more oxidized than mid-ocean ridge basalts, but it is unclear whether this difference is due to differentiation processes in the Earth’s crust or to a fundamental difference in the oxygen fugacity of their mantle sources. Distinguishing between these two hypotheses is important for understanding redox-sensitive processes related to arc magmatism, and thus more broadly how Earth materials cycle globally. We present major, volatile, and trace element concentrations in combination with Fe^(3+)/∑Fe ratios determined in olivine-hosted glass inclusions and submarine glasses from five Mariana arc volcanoes and two regions of the Mariana Trough. For single eruptions, Fe^(3+)/∑Fe ratios vary along liquid lines of descent that are either slightly oxidizing (olivine + clinopyroxene + plagioclase fractionation, CO_2 ± H_2O degassing) or reducing (olivine + clinopyroxene + plagioclase ± magnetite fractionation, CO_2 + H_2O + S degassing). Mariana samples are consistent with a global relationship between calc-alkaline affinity and both magmatic H_2O and magmatic oxygen fugacity, where wetter, higher oxygen fugacity magmas display greater affinity for calc-alkaline differentiation. We find, however, that low-pressure differentiation cannot explain the majority of variations observed in Fe^(3+)/∑Fe ratios for Mariana arc basalts, requiring primary differences in magmatic oxygen fugacity. Calculated oxygen fugacities of primary mantle melts at the pressures and temperatures of melt segregation are significantly oxidized relative to mid-ocean ridge basalts (∼QFM, where QFM is quartz–fayalite–magnetite buffer), ranging from QFM + 1·0 to QFM + 1·6 for Mariana arc basalts, whereas back-arc related samples record primary oxygen fugacities that range from QFM + 0·1 to QFM + 0·5. This Mariana arc sample suite includes a diversity of subduction influences, from lesser influence of a homogeneous H_2O-rich component in the back-arc, to sediment melt- and fluid-dominated influences along the arc. Primary melt oxygen fugacity does not correlate significantly with sediment melt contributions (e.g. Th/La), nor can it be attributed to previous melt extraction in the back-arc. Primary melt oxygen fugacity correlates strongly with indices of slab fluids (e.g. Ba/La) from the Mariana Trough through the Mariana arc, increasing by 1·5 orders of magnitude as Ba/La increases by a factor of 10 relative to mid-ocean ridge basalts. These results suggest that contributions from the slab to the mantle wedge may be responsible for the elevated oxygen fugacity recorded by Mariana arc basalts and that slab fluids are potentially very oxidized.

4.13 - Composition of the Oceanic Crust

Abstract: Oceanic crust is created as magma rises to fill the gap between diverging tectonic plates and is consumed in subduction zones. It is geologically young, with a mean age of 60 Ma, and is thin, averaging 6.5 km in thickness. Oceanic crust consists almost exclusively of extrusive basalt and its intrusive equivalents. This chapter focuses on the roughly 1.5–2 km thick ‘volcanic layer’ consisting of lava flows that overlie the feeder dikes that make up the sheeted dike complex. The basalts of the oceanic crust, referred to as mid-ocean ridge basalts (MORB), are dominantly tholeiitic and are, on average, depleted in incompatible trace elements compared to basalts erupted in other tectonic environments. Isotopic compositions and incompatible trace element concentrations and ratios suggest that their depleted character is inherited from their mantle source and that this source varies in composition both locally and on the scale of ocean basins. Their major element chemistry appears to be controlled primarily by the temperature of the underlying mantle, which determines the extent and pressure of melting, and, consequently, the thickness of the oceanic crust and the depth of the ridge axis. Basalts erupted at back-arc spreading centers, called back-arc basin basalts, are compositionally similar to MORB, but have some compositional features suggesting incorporation of one or multiple subduction-related components in their source.

Continental Basaltic Rocks

Abstract: The primary goal of this chapter is to illustrate how geochemical data can be used both to assess the origin of continental basaltic rocks and to study the evolution of the continental lithosphere. The scope of the chapter is limited to a discussion of a select group of ultramafic to mafic ‘intraplate’ igneous rocks, consisting primarily of kimberlites, potassic and sodic alkali basalts, and continental flood basalts. Although basaltic magmatism has occurred throughout Earth's history, the majority of the examples presented here are from Mesozoic and Cenozoic volcanic fields due to the more complete preservation of younger continental mafic igneous rocks. While considerable effort has been expended in studying the chemical differentiation of mafic magmas, the present discussion concentrates on the least differentiated basaltic rocks in a given location. Such rocks generally provide the best estimate the compositions of ‘primary’ magmas generated beneath a given volcanic field and primary magmas provide the most direct insights into the nature of the magma source regions.

The Lunar Apatite Paradox

Abstract: Recent discoveries of water-rich lunar apatite are more consistent with the hydrous magmas of Earth than the otherwise volatile-depleted rocks of the Moon. Paradoxically, this requires H-rich minerals to form in rocks that are otherwise nearly anhydrous. We modeled existing data from the literature, finding that nominally anhydrous minerals do not sufficiently fractionate H from F and Cl to generate H-rich apatite. Hydrous apatites are explained as the products of apatite-induced low magmatic fluorine, which increases the H/F ratio in melt and apatite. Mare basalts may contain hydrogen-rich apatite, but lunar magmas were most likely poor in hydrogen, in agreement with the volatile depletion that is both observed in lunar rocks and required for canonical giant-impact models of the formation of the Moon.

Four billion years of ophiolites reveal secular trends in oceanic crust formation

Abstract: We combine a geological, geochemical and tectonic dataset from 118 ophiolite complexes of the major global Phanerozoic orogenic belts with similar datasets of ophiolites from 111 Precambrian greenstone belts to construct an overview of oceanic crust generation over 4 billion years. Geochemical discrimination systematics built on immobile trace elements reveal that the basaltic units of the Phanerozoic ophiolites are dominantly subduction-related (75%), linked to backarc processes and characterized by a strong MORB component, similar to ophiolites in Precambrian greenstone sequences (85%). The remaining 25% Phanerozoic subduction-unrelated ophiolites are mainly (74%) of Mid-Ocean-Ridge type (MORB type), in contrast to the equal proportion of Rift/Continental Margin, Plume, and MORB type ophiolites in the Precambrian greenstone belts. Throughout the Phanerozoic there are large geochemical variations in major and trace elements, but for average element values calculated in 5 bins of 100 million year intervals there are no obvious secular trends. By contrast, basaltic units in the ophiolites of the Precambrian greenstones (calculated in 12 bins of 250 million years intervals), starting in late Paleo- to early Mesoproterozoic (ca. 2.0–1.8 Ga), exhibit an apparent decrease in the average values of incompatible elements such as Ti, P, Zr, Y and Nb, and an increase in the compatible elements Ni and Cr with deeper time to the end of the Archean and into the Hadean. These changes can be attributed to decreasing degrees of partial melting of the upper mantle from Hadean/Archean to Present. The onset of geochemical changes coincide with the timing of detectible changes in the structural architecture of the ophiolites such as greater volumes of gabbro and more common sheeted dyke complexes, and lesser occurrences of ocelli (varioles) in the pillow lavas in ophiolites younger than 2 Ga. The global data from the Precambrian ophiolites, representative of nearly 50% of all known worldwide greenstone belts provide significant clues for the operation of plate tectonic processes in the Archean.

Geophysical and Geochemical Evidence for Deep Temperature Variations Beneath Mid-Ocean Ridges

Abstract: The temperature and composition of Earth’s mantle control fundamental planetary properties, including the vigor of mantle convection and the depths of the ocean basins. Seismic wave velocities, ocean ridge depths, and the composition of mid-ocean ridge basalts can all be used to determine variations in mantle temperature and composition, yet are typically considered in isolation. We show that correlations among these three data sets are consistent with 250°C variation extending to depths >400 kilometers and are inconsistent with variations in mantle composition at constant temperature. Anomalously hot ridge segments are located near hot spots, confirming a deep mantle-plume origin for hot spot volcanism. Chemical heterogeneity may contribute to scatter about the global trend. The coherent temperature signal provides a thermal calibration scale for interpreting seismic velocities located distant from ridges.

Existence of complex spatial zonation in the Galápagos plume for at least 14 m.y.

Abstract: Basalts from intraplate or hotspot ocean islands (e.g., the Hawaiian, Galapagos, and Canary Islands) are believed to be formed by mantle plumes, which emanate from mantle boundary layers such as the coremantle boundary. The long-term chemical structure of mantle plumes, however, remains poorly constrained. Spatial variation in the chemical composition has long been recognized in lavas from the Galapagos Islands: Enriched plume material forms a horseshoe-shaped region with depleted mantle, similar in composition to mid-ocean ridge basalt, in its inner part. The enriched horseshoe-shaped region can be subdivided into three distinct geochemical domains. We show that these same domains occur in the same relative positions with respect to morphology in a geochemical profile across the Galapagos hotspot track off the coast of Costa Rica, indicating that the asymmetrical spatial zonation of the Galapagos hotspot has existed for at least 14 m.y. Combined with published He isotope data, the results of this study imply that plume material can ascend from the lower mantle, possibly from the core-mantle boundary, with little stirring occurring during ascent, and that zonation in hotspot lavas may in some cases reflect spatial heterogeneity within the lower mantle source.

Geochemical diversity in first rocks examined by the Curiosity Rover in Gale Crater: Evidence for and significance of an alkali and volatile‐rich igneous source

Abstract: The first four rocks examined by the Mars Science Laboratory Alpha Particle X-ray Spectrometer indicate that Curiosity landed in a lithologically diverse region of Mars. These rocks, collectively dubbed the Bradbury assemblage, were studied along an eastward traverse (sols 46–102). Compositions range from Na- and Al-rich mugearite Jake_Matijevic to Fe-, Mg-, and Zn-rich alkali-rich basalt/hawaiite Bathurst_Inlet and span nearly the entire range in FeO* and MnO of the data sets from previous Martian missions and Martian meteorites. The Bradbury assemblage is also enriched in K and moderately volatile metals (Zn and Ge). These elements do not correlate with Cl or S, suggesting that they are associated with the rocks themselves and not with salt-rich coatings. Three out of the four Bradbury rocks plot along a line in elemental variation diagrams, suggesting mixing between Al-rich and Fe-rich components. ChemCam analyses give insight to their degree of chemical heterogeneity and grain size. Variations in trace elements detected by ChemCam suggest chemical weathering (Li) and concentration in mineral phases (e.g., Rb and Sr in feldspars). We interpret the Bradbury assemblage to be broadly volcanic and/or volcaniclastic, derived either from near the Gale crater rim and transported by the Peace Vallis fan network, or from a local volcanic source within Gale Crater. High Fe and Fe/Mn in Et_Then likely reflect secondary precipitation of Fe^(3+) oxides as a cement or rind. The K-rich signature of the Bradbury assemblage, if igneous in origin, may have formed by small degrees of partial melting of metasomatized mantle.

Melting of subducted basalt at the core-mantle boundary.

Abstract: The geological materials in Earth9s lowermost mantle control the characteristics and interpretation of seismic ultra–low velocity zones at the base of the core-mantle boundary. Partial melting of the bulk lower mantle is often advocated as the cause, but this does not explain the nonubiquitous character of these regional seismic features. We explored the melting properties of mid-oceanic ridge basalt (MORB), which can reach the lowermost mantle after subduction of oceanic crust. At a pressure representative of the core-mantle boundary (135 gigapascals), the onset of melting occurs at ~3800 kelvin, which is ~350 kelvin below the mantle solidus. The SiO2-rich liquid generated either remains trapped in the MORB material or solidifies after reacting with the surrounding MgO-rich mantle, remixing subducted MORB with the lowermost mantle.

Igneous mineralogy at Bradbury Rise: The first ChemCam campaign at Gale crater

Abstract: Textural and compositional analyses using Chemistry Camera (ChemCam) remote microimager and laser-induced breakdown spectroscopy (LIBS) have been performed on five float rocks and coarse gravels along the first 100 m of the Curiosity traverse at Bradbury Rise. ChemCam, the first LIBS instrument sent to another planet, offers the opportunity to assess mineralogic diversity at grain-size scales (~ 100 µm) and, from this, lithologic diversity. Depth profiling indicates that targets are relatively free of surface coatings. One type of igneous rock is volcanic and includes both aphanitic (Coronation) and porphyritic (Mara) samples. The porphyritic sample shows dark grains that are likely pyroxene megacrysts in a fine-grained mesostasis containing andesine needles. Both types have magnesium-poor basaltic compositions and in this respect are similar to the evolved Jake Matijevic rock analyzed further along the Curiosity traverse both with Alpha-Particle X-ray Spectrometer and ChemCam instruments. The second rock type encountered is a coarse-grained intrusive rock (Thor Lake) showing equigranular texture with millimeter size crystals of feldspars and Fe-Ti oxides. Such a rock is not unique at Gale as the surrounding coarse gravels (such as Beaulieu) and the conglomerate Link are dominated by feldspathic (andesine-bytownite) clasts. Finally, alkali feldspar compositions associated with a silica polymorph have been analyzed in fractured filling material of Preble rock and in Stark, a putative pumice or an impact melt. These observations document magmatic diversity at Gale and describe the first fragments of feldspar-rich lithologies (possibly an anorthosite) that may be ancient crust transported from the crater rim and now forming float rocks, coarse gravel, or conglomerate clasts.

The Global Systematics of Ocean Ridge Basalts and their Origin

Abstract: Tests of models of melt generation and mantle source variations beneath mid-ocean ridges require a definitive set of mid-ocean ridge basalt (MORB) compositions corrected for shallow-level processes. Here we provide such a dataset, with both single sample and segment means for 241 segments from every ocean basin, which span the entire range of spreading rate, axial depth, and MORB chemical composition. Particular attention is paid to methods of fractionation correction. Values corrected to 8 wt % MgO are robust as they are within the range of the data. Extrapolation to equilibrium with mantle olivine is a non-unique procedure that is critically dependent on the MgO content where plagioclase first appears. MORB data, trace element ratios and calculated liquid lines of descent provide consistent evidence that plagioclase fractionation primarily occurs between 8 and 9 wt % MgO, with the exception of hydrous magmas mainly from back-arc segments.Varying the MgO content of plagioclase appearance over large ranges does not produce the observed systematics at 8 wt % MgO, but may contribute to the spread of the data. Data were evaluated individually for each segment to ensure reliable fractionation correction, and segment means are reported normalized both to MgO of 8 wt % and also to a constant Mg/(MgþFe) in equilibrium with Fo90 olivine. Both sets of corrected compositions show large variations in Na2O and FeO, good correlations with segment depth, and systematic relationships among the major elements. A particularly good correlation exists between Al90 and Fe90.These new data are not in agreement with the presentation of Niu & O’Hara (Journal of Petrology 49, 633^664, 2008), whose results relied on an inaccurate fractionation correction procedure, which led them to large errors for highand low-FeO magmas. The entire dataset is provided in both raw and normalized form so as to have a uniform basis for future evaluations. The new data compilation permits tests of competing models for the primary causes of variations in MORB parental magmas: variations in mantle composition, mantle temperature, reactive crystallization or lithospheric thickness. The principal component of chemical variation among segment mean compositions is remarkably consistent with variations in mantle temperature of some 2008C beneath global ocean ridges. Comparisons with experimental data, pMELTS and other calculations show that variations in mantle fertility at constant mantle potential temperature produce trends that are largely orthogonal to the observations. At the same time, there is clear evidence for mantle major element heterogeneity beneath and around some hotspots and beneath back-arc basins. Super slowspreading ridges display a characteristic chemical signature of elevated Na90 and Al90 and lowered Si90 relative to faster-spreading ridges. If this signature were produced by reactive crystallization, Si90 should be higher rather than lower in these environments owing to the thicker lithosphere and lower temperatures of mantle^melt reaction. Instead, the data are consistent with lower extents of mantle melting beneath a thicker lithosphere. Hence, variations in extent of melting appear to be the dominant control on the major element compositions of MORB parental magmas. Trace elements, in contrast, require a large component of mantle heterogeneity, apparent in the factor of 50 variation in K90. Such variations do not correlate with the other major elements, showing that major element and trace