Topic
Benzoic acid
About: Benzoic acid is a research topic. Over the lifetime, 11832 publications have been published within this topic receiving 167127 citations. The topic is also known as: Retardex & E210.
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TL;DR: In this paper, glass raschig rings were coated with different types of TiO 2, namely Evonik P25 (EP), anatase T 2 from Sigma-Aldrich (SA), and TiO2 obtained from a sol-gel procedure.
60 citations
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TL;DR: In this article, the role of nonpolar and polar solvents, some of which contained oxygen, sulfur or nitrogen, were used for the hydrogenation of benzyl alcohol over the Ru/Al2O3 catalyst.
Abstract: Toluene, phenol, benzyl alcohol, and benzoic acid in alcohols were hydrogenated using Ru/Al2O3 and Pt/Al2O3 catalysts at 120 °C under a hydrogen pressure of 6 MPa. The Ru/Al2O3 catalyst exhibited a high activity for hydrogenation of mono-aromatics dissolved in alcohols. The hydrogenation activity of the Pt/Al2O3 catalyst was strongly inhibited by the presence of alcohols. To evaluate the role of solvents, nonpolar and polar solvents, some of which contained oxygen, sulfur or nitrogen, were used for the hydrogenation of benzyl alcohol over the Ru/Al2O3 catalyst. A relationship was found between the hydrogenation reactivity of benzyl alcohol in polar solvents and the δ value of the solvent, as defined by the difference between donor number and acceptor number. Nonpolar solvents had no effect on the hydrogenation reaction of benzyl alcohol. Polar solvents with negative δ values, such as methanol, ethanol, and acetic acid, also had no effect. However, polar solvents with positive δ values, such as acetone, te...
60 citations
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TL;DR: A Rh(III) -catalyzed direct ortho-CH amidation/amination of benzoic acids with N-chlorocarbamates/N-chloromorpholines was achieved, giving anthranilic acids in up to 85 % yields with excellent Ortho-selectivity and functional-group tolerance.
Abstract: A RhIII-catalyzed direct ortho-CH amidation/amination of benzoic acids with N-chlorocarbamates/N-chloromorpholines was achieved, giving anthranilic acids in up to 85 % yields with excellent ortho-selectivity and functional-group tolerance. Successful benzoic acid aminations were achieved with carbamates bearing various amide groups including NHCO2Me, NHCbz, and NHTroc (Cbz=carbobenzyloxy; Troc=trichloroethylchloroformate), as well as secondary amines, such as morpholines, piperizines, and piperidines, furnishing highly functionalized anthranilic acids. A stoichiometric reaction of a cyclometallated rhodium(III) complex of benzo[h]quinoline with a silver salt of N-chlorocarbamate afforded an amido–rhodium(III) complex, which was isolated and structurally characterized by X-ray crystallography. This finding confirmed that the CN bond formation results from the cross-coupling of N-chlorocarbamate with the aryl–rhodium(III) complex. Yet, the mechanistic details regarding the CN bond formation remain unclear; pathways involving 1,2-aryl migration and rhodium(V)– nitrene are plausible.
60 citations
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TL;DR: Chromium was incorporated into the silica matrix extracted from rice husk in basic, neutral and acidic medium, and the prepared catalysts were labeled as RHCr-10,RHCr-7 and RHCr3 according to their pH as mentioned in this paper.
60 citations
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TL;DR: In this paper, a kinetic study by HPLC showed that the first reaction leads to the formation of 4-methoxy-6-methyl-1,3,5-triazin-2-amine and (o-chlorophenylsulfonyl) carbamic acid for chlorsulfuron or (methox-carbonylphenyl sulfonyl sulfonyll) carbamides for metsulfuronmethyl.
Abstract: In acidic media, hydrolysis of chlorsulfuron and metsulfuron-methyl occurs via two consecutive reactions which were followed by ultraviolet spectrophotometry. For these two reactions, the pseudo-first-order rate constants increase proportionally to the concentration of hydronium ion in the more acidic media and to the square of this concentration at higher pH values.
A kinetic study by HPLC shows that the first reaction leads to the formation of 4-methoxy-6-methyl-1,3,5-triazin-2-amine and (o-chlorophenylsulfonyl) carbamic acid for chlorsulfuron or (o-methoxycarbonylphenylsulfonyl) carbamic acid for metsulfuronmethyl. The second reaction is the conversion of these sulfonylcarbamic acids to sulfonamides and carbon dioxide. The complete lack of saccharin and of o-sulfamoyl benzoic acid proves that the ester function of the methoxycarbonyl group is stable.
The lack of general acid-base catalysis and a solvent deuterium isotope effect less than unity are consistent with a rate-determining cleavage of the protonated substrate.
In the basic pH range (10–14) a single reaction occurs, the nucleophilic substitution of the methoxy group on the triazine by a hydroxide group.
60 citations