Topic
Benzoic acid
About: Benzoic acid is a research topic. Over the lifetime, 11832 publications have been published within this topic receiving 167127 citations. The topic is also known as: Retardex & E210.
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TL;DR: A simple method of predicting the dissolution rate of an acid or a salt at different pH values has been developed and good correlation was shown between the pHh = 0 values of benzoic acid estimated according to this method and the pHs reported in the literature.
137 citations
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TL;DR: A new multicarboxylate ligand, 3,5-bis-oxyacetate-benzoic acid (H3BOABA), was designed and introduced to construct novel metal−organic framework materials with potential luminescent properties.
Abstract: A new multicarboxylate ligand, 3,5-bis-oxyacetate-benzoic acid (H3BOABA), was designed and introduced to construct novel metal−organic framework materials with potential luminescent properties. Fou...
136 citations
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TL;DR: The right ligand enables the efficient carbonylation of unactivated chloroarenes and a general synthesis of benzoic acid derivatives is possible with the palladium-ferrocenylphosphane catalysts.
Abstract: The right ligand enables the efficient carbonylation of unactivated chloroarenes. A general synthesis of benzoic acid derivatives is possible with the palladium-ferrocenylphosphane catalysts.
136 citations
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TL;DR: In this article, the process of molecular self-assembly has been studied in concentrated solutions using FTIR spectroscopy, and three carboxylic acids, benzoic, tetrolic, and mandelic acids, have been chosen on the basis of their differing crystal chemistries, as reflected in observed hydrogen-bonding motifs.
Abstract: Little is known concerning the precise molecular pathway that links fluid-phase molecules to those in nascent crystal nuclei. In this paper the process of molecular self-assembly has been studied in concentrated solutions using FTIR spectroscopy. Three carboxylic acids, benzoic, tetrolic, and mandelic acids, have been chosen on the basis of their differing crystal chemistries, as reflected in observed hydrogen-bonding motifs. Using the solid-state spectra as a means of unambiguous assignment of carboxyl and hydroxyl vibrations associated with hydrogen bonding, spectroscopic data are reported for solutions as a function of both composition and solvent. In the cases of benzoic acid and tetrolic acid, a link between the growth synthon and the structural synthon is apparent. Mandelic acid, on the other hand, provides a more complex case in which strong solvation effects are evident, leading to the conclusion that significant molecular rearrangement must occur within the developing crystal nuclei.
136 citations
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TL;DR: It is proved that all three key steps in the catalytic cycle of CuAAC can proceed in the presence of carboxylic acids and the latter two steps can be promoted significantly by carboxYlic acids.
Abstract: In this article, we proved that all three key steps in the catalytic cycle of CuAAC can proceed in the presence of carboxylic acids and the latter two steps can be promoted significantly by carboxylic acids. Benzoic acid showed the best promotion activity, and the acids with strong chelating ability to Cu(I) ion could not serve for this purpose. Thus, the first carboxylic acid-promoted highly efficient CuAAC was established.
136 citations