Topic
Benzoic acid
About: Benzoic acid is a research topic. Over the lifetime, 11832 publications have been published within this topic receiving 167127 citations. The topic is also known as: Retardex & E210.
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282 citations
TL;DR: Pt3Ni octahedral nanoparticles supported on carbon black are prepared from solutions of Pt(acac)2 and Ni(acAC)2 in DMF and benzoic acid as structure directing agent as discussed by the authors.
Abstract: Pt3Ni octahedral nanoparticles supported on carbon black are prepared from solutions of Pt(acac)2 and Ni(acac)2 in DMF and benzoic acid as structure directing agent.
282 citations
280 citations
TL;DR: In the batch reactor system, denitrification was almost complete while the C/N ratio of each of the four different carbon sources (methanol, acetic acid, glucose, benzoic acid) was properly controlled.
277 citations
TL;DR: In this paper, a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co(OAc)2 was developed to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature.
Abstract: A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co(OAc)2 was developed. For instance, the oxidation of toluene was completed by NHPI combined with Co(OAc)2 under an oxygen atmosphere at room temperature to give benzoic acid in 81% yield. Under these conditions, o- and p-xylenes were selectively converted into the corresponding monocarboxylic acids without the formation of the dicarboxylic acids. ESR measurements showed that Co(II) species assists in the formation of phthalimide-N-oxyl (PINO), which is a key species in this oxidation, from NHPI.
274 citations