BET theory

About: BET theory is a research topic. Over the lifetime, 9046 publications have been published within this topic receiving 286142 citations.

A porous coordination copolymer with over 5000 m2/g BET surface area.

Abstract: New levels of surface area are achieved in a coordination polymer (UMCM-2, University of Michigan Crystalline Material) derived from zinc-mediated coordination copolymerization of a dicarboxylic and tricarboxylic acid In addition to a large micropore contribution to the surface area, mesopores are also present In contrast to the recently reported coordination copolymer UMCM-1, which has a mesoporous channel, UMCM-2 is built from three types of cages In spite of exceptional porosity, both of these coordination polymers are thermally robust Hydrogen uptake performance of UMCM-2 approaches 7 wt% at 77 K

CO2 capture and conversion using Mg-MOF-74 prepared by a sonochemical method

Abstract: Mg-MOF-74 crystals were successfully prepared in 1 h by a sonochemical method (Mg-MOF-74(S)) after triethylamine (TEA) was added as a deprotonating agent. Mg-MOF-74(S) (1640 m2 g−1 BET surface area) displayed similar textural properties to those of a high-quality MOF sample synthesized in 24 h by the solvothermal method (Mg-MOF-74(C), 1525 m2 g−1). However, mesopores were formed, probably due to the competitive binding of TEA to Mg2+ ions, and the average particle size of the former (ca. 0.6 μm) was significantly smaller than that of the latter (ca. 14 μm). The H2O adsorption capacity was 593 mL g−1 at 298 K for Mg-MOF-74(S), displaying higher hydrophilicity than Zeolite 13X. The adsorption isotherms of Mg-MOF-74(S) for CO2 showed high adsorption capacity (350 mg g−1 at 298 K) and high isosteric heats of adsorption for CO2 (42 to 22 kJ mol−1). The breakthrough experiment confirmed excellent selectivity to CO2 over N2 at ambient conditions (saturation capacity of ca. 179 mg g−1). Ten consecutive adsorption–desorption cycles at 298 K established no deterioration of the adsorption capacity, which showed reversible adsorbent regeneration at 323 K under helium flow for a total duration of 1400 min. Mg-MOF-74(S) also demonstrated excellent catalytic performance in cycloaddition of CO2 to styrene oxide under relatively mild reaction conditions (2.0 MPa, 373 K) with close to 100% selectivity to carbonate, which was confirmed by GC-MS, 1H-NMR, and FT-IR. Mg-MOF-74(S) could be reused 3 times without losing catalytic activity and with no structural deterioration.