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Binary system
About: Binary system is a research topic. Over the lifetime, 5788 publications have been published within this topic receiving 97882 citations.
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TL;DR: In this article, new sapphire and diamond anvil cell experiments were conducted in this binary system to constrain the stability of the CO2 hydrates and H2O-ice VI at CO2 saturation in the 250 −330 K and 0 −1.7 GPa temperature and pressure ranges.
55 citations
TL;DR: In this paper, the phase behavior of the binary and ternary CO 2 (1)+methanol (2) and CO 2(1) +soybean methyl esters (biodiesel) was investigated using a variable-volume view cell.
55 citations
54 citations
TL;DR: In this article, a flow-type method was adopted to measure the vapor-liquid equilibria for methanol+methyl laurate and methanhol+methyl myristate systems at 493-543 K, near the critical temperature of methanols (Tc −1.64k), and 2.16-8.49 MPa.
54 citations
TL;DR: In this article, the interaction parameters (CH3−OCOO), (CH2−OCO), and CH2cy−OCOCOO) were determined for their application in the UNIFAC−VISCO method, based on contribution groups, to predict the dynamic viscosities of the binary mixtures.
Abstract: Viscosities have been determined for the binary mixtures dimethyl carbonate (DMC) + hexane, + heptane, + octane, and + cyclohexane and diethyl carbonate (DEC) + hexane, + heptane, + octane, and + cyclohexane at (293.15, 298.15, 303.15, and 313.15) K and atmospheric pressure. Viscosity deviations for the binary systems were fitted to the Redlich−Kister equation. From these experimental data, the interaction parameters (CH3−OCOO), (CH2−OCOO), and (CH2cy−OCOO) have been determined for their application in the UNIFAC−VISCO method, based on contribution groups, to predict the dynamic viscosities of the binary mixtures. Root-mean-square deviations are also gathered.
54 citations