Topic
Brillouin zone
About: Brillouin zone is a research topic. Over the lifetime, 13849 publications have been published within this topic receiving 383077 citations.
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TL;DR: In this paper, the cubic-rhombohedral phase transition at 450 degrees C of AlF3 is studied by DSC, X-ray powder diffraction and Raman scattering, and it is demonstrated that the transition is of first order with a hysteresis of about 6 degrees.
Abstract: The cubic-rhombohedral phase transition at 450 degrees C of AlF3 is studied by DSC, X-ray powder diffraction and Raman scattering. It is demonstrated that the transition is of first order with a hysteresis of about 6 degrees. It is established by X-ray powder diffraction patterns that the room temperature space group is R3c. A temperature study of the Raman scattering spectra (that confirms the above conclusion) evidences the presence of two soft modes. It is shown from group theory that the transition can be imputed to the condensation of the R5 mode of the cubic Brillouin zone and the attribution of the Raman lines is deduced on the basis of the compatibility diagram between the cubic and rhombohedral symmetries. The frequencies of the Raman lines are used to adjust the parameters of a rigid ion model and to calculate the phonon spectrum in the cubic phase. The calculated phonon density of states appears to be strongly dependent on the soft phonon frequency.
84 citations
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TL;DR: In this paper, the authors presented a comprehensive multiphonon Raman and complementary infrared analysis for bulk and monolayer MoS2 with the main contributions coming from four phonons.
Abstract: We present a comprehensive multiphonon Raman and complementary infrared analysis for bulk and monolayer MoS2.For the bulk the analysis consists of symmetry assignment from which we obtain a broad set of allowed second order transitions at the high symmetry M,K and gamma Brillouin zone points. The attribution of about 80 transitions of up to fifth order Raman processes are proposed in the low temperature(95K)resonant Raman spectrum measured with the excitation energy of 1.96 eV,which is slightly shifted from the A exciton. We propose that the main contributions come from four phonons:A1g(M),E12g(M2),E22g(M1)(TA'(M))and E22g (M2)(LA'(M)). The last three are single degenerate phonons at M with an origin of the E12g(gamma)and E22g(gamma)phonons. Among the four phonons, we identify in the resonant Raman spectra all(but one) of the second order overtones,combination and difference bands and many of the third order bands. Consistent with the expectation that at the M point only combinations with the same inversion symmetry (g or u)are Raman allowed, the contribution of combinations with the LA(M)phonon can not be considered with the above four phonons. Although minor,contribution from K point and possibly gamma point phonons are also evident. The "2LA band",measured at ~460 cm-1 is reassigned.Supported by the striking similarity between this band, measured under off resonant conditions, and recently published two phonon density of states, we propose that the lower part of the band,previously attributed to 2LA(M),is due to a van Hove singularity between K and M. The higher part,previously attributed exclusively to the A2u(gamma)phonon,is mostly due to the LA and LA' phonons at M. For the monolayer MoS2, the second order phonon processes from M and gamma Brillouin zone points are also analyzed and are discussed within similar framework to that of the bulk.
84 citations
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TL;DR: The results of the numerical simulations reveal that this high-frequency phonon is indeed trapped within the fiber core by the air-hole microstructure, in good agreement with experimental measurements.
Abstract: We experimentally investigate guided acoustic wave Brillouin scattering in several photonic crystal fibers by use of the so-called fiber loop mirror technique and show a completely different dynamics with respect to standard all-silica fibers. In addition to the suppression of most acoustic phonons, we show that forward Brillouin scattering in photonic crystal fibers is substantially enhanced only for the fundamental acoustic phonon because of efficient transverse acousto-optic field overlap. The results of our numerical simulations reveal that this high-frequency phonon is indeed trapped within the fiber core by the air-hole microstructure, in good agreement with experimental measurements.
84 citations
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TL;DR: In two dimensions, a variational trial function is used to predict the occurrence of a variety of finite energy solitary waves associated with the different symmetry points of the crystalline Brillouin zone.
Abstract: It is suggested that solitary wave solutions exist in the gap region of photonic band gap materials with a Kerr nonlinearity. Using a variational trial function we estimate the amplitude, size scale, and the nature of phase modulation of these nonlinear waves. In two dimensions, we predict the occurrence of a variety of finite energy solitary waves associated with the different symmetry points of the crystalline Brillouin zone. Solutions which preserve the symmetry of the crystal exist for both positive and negative Kerr coefficient whereas solutions which break the symmetry occur only for positive nonlinearity. These states are relevant to the bistable switching properties of photonic band gap materials.
84 citations
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TL;DR: In this article, a spin-polarized multiple Dirac ring feature is reported for the first time in an experimentally realized material, and the 3D band structure further reveals that MnF3 possesses rings of Dirac nodes.
Abstract: Spin-polarized materials with Dirac features have sparked great scientific interest due to their potential applications in spintronics. But such a type of structure is very rare and none has been fabricated. Here, we investigate the already experimentally synthesized manganese fluoride (MnF3) as a novel spin-polarized Dirac material by using first-principles calculations. MnF3 exhibits multiple Dirac cones in one spin orientation, while it behaves like a large gap semiconductor in the other spin channel. The estimated Fermi velocity for each cone is of the same order of magnitude as that in graphene. The 3D band structure further reveals that MnF3 possesses rings of Dirac nodes in the Brillouin zone. Such a spin-polarized multiple Dirac ring feature is reported for the first time in an experimentally realized material. Moreover, similar band dispersions can be also found in other transition metal fluorides (e.g., CoF3, CrF3, and FeF3). Our results highlight a new interesting single-spin Dirac material with promising applications in spintronics and information technologies.
84 citations