Chain (algebraic topology)

About: Chain (algebraic topology) is a research topic. Over the lifetime, 6235 publications have been published within this topic receiving 68250 citations.

Topological analysis of polymeric melts: chain-length effects and fast-converging estimators for entanglement length.

Abstract: Primitive path analyses of entanglements are performed over a wide range of chain lengths for both bead spring and atomistic polyethylene polymer melts. Estimators for the entanglement length N_{e} which operate on results for a single chain length N are shown to produce systematic O(1/N) errors. The mathematical roots of these errors are identified as (a) treating chain ends as entanglements and (b) neglecting non-Gaussian corrections to chain and primitive path dimensions. The prefactors for the O(1/N) errors may be large; in general their magnitude depends both on the polymer model and the method used to obtain primitive paths. We propose, derive, and test new estimators which eliminate these systematic errors using information obtainable from the variation in entanglement characteristics with chain length. The new estimators produce accurate results for N_{e} from marginally entangled systems. Formulas based on direct enumeration of entanglements appear to converge faster and are simpler to apply.

Trialgebras and families of polytopes

Abstract: We show that the family of standard simplices and the family of Stasheff polytopes are dual to each other in the following sense. The chain modules of the standard simplices, resp. the Stasheff polytopes, assemble to give an operad. We show that these operads are dual of each other in the operadic sense. The main result of this paper is to show that they are both Koszul operads. As a consequence the generating series of the standard simplices and the generating series of the Stasheff polytopes are inverse to each other. The two operads give rise to new types of algebras with 3 generating operations, 11 relations, respectively 7 relations, that we call {\it associative trialgebras} and {\it dendriform trialgebras} respectively. The free dendriform trialgebra, which is based on planar trees, has an interesting Hopf algebra structure, which will be dealt with in another paper. Similarly the family of cubes gives rise to an operad which happens to be self-dual for Koszul duality.

Integral representations for correlation functions of the XXZ chain at finite temperature

Abstract: We derive a novel multiple integral representation for a generating function of the σz–σz correlation functions of the spin- XXZ chain at finite temperature and finite, longitudinal magnetic field. Our work combines algebraic Bethe ansatz techniques for the calculation of matrix elements with the quantum transfer matrix approach to thermodynamics.