Topic
Chemisorption
About: Chemisorption is a research topic. Over the lifetime, 16298 publications have been published within this topic receiving 554989 citations.
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TL;DR: In this paper, a new rule for calculating chemisorption energies using the cluster model was proposed, based on the realization that relatively large clusters (50 atoms and more) often need to be prepared for bonding by making an excitation to a proper bonding state (such a state will always be easily accessible in an infinite cluster).
175 citations
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TL;DR: In this article, carbon dioxide chemisorption studies at 0 °C were used to determine the relative basicities of alkali-promoted reduced magnetite catalysts, showing that a higher surface basicity correlates with a lower methane selectivity in the Fischer-Tropsch synthesis.
175 citations
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TL;DR: In this paper, the effect of dissolved ions, pH, particle size, adsorbent mass, and dye initial concentration on adsorption capacity of methylene blue and crystal violet on palygorskite clay is discussed.
174 citations
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TL;DR: In this paper, the authors examined the reactive chemistry of methanol on the Cu(111) surface, both with and without preadsorbed oxygen atoms, between 190 and 700 K.
174 citations
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TL;DR: First-principle calculations based on density functional theory (DFT) were used to elucidate the mercury adsorption and oxidation mechanisms on MnFe2O4 surface and indicate that Hg atom interacts strongly with surface Mn atoms through the orbital hybridization.
174 citations