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Showing papers on "Cluster (physics) published in 2010"


Journal ArticleDOI
28 May 2010-Science
TL;DR: It is shown that self-assembled clusters of metal-dielectric spheres are the basis for nanophotonic structures, and plasmon modes exhibiting strong magnetic and Fano-like resonances emerge.
Abstract: The self-assembly of colloids is an alternative to top-down processing that enables the fabrication of nanostructures. We show that self-assembled clusters of metal-dielectric spheres are the basis for nanophotonic structures. By tailoring the number and position of spheres in close-packed clusters, plasmon modes exhibiting strong magnetic and Fano-like resonances emerge. The use of identical spheres simplifies cluster assembly and facilitates the fabrication of highly symmetric structures. Dielectric spacers are used to tailor the interparticle spacing in these clusters to be approximately 2 nanometers. These types of chemically synthesized nanoparticle clusters can be generalized to other two- and three-dimensional structures and can serve as building blocks for new metamaterials.

1,402 citations


Journal ArticleDOI
TL;DR: In this article, the authors used the largest complete sample of 64 galaxy clusters (HIghest X-ray FLUx Galaxy Cluster Sample) with available high-quality Xray data from Chandra, and apply 16 cool-core diagnostics to them, some of them new.
Abstract: We use the largest complete sample of 64 galaxy clusters (HIghest X-ray FLUx Galaxy Cluster Sample) with available high-quality X-ray data from Chandra, and apply 16 cool-core diagnostics to them, some of them new. In order to identify the best parameter for characterizing cool-core clusters and quantify its relation to other parameters, we mainly use very high spatial resolution profiles of central gas density and temperature, and quantities derived from them. We also correlate optical properties of brightest cluster galaxies (BCGs) with X-ray properties. To segregate cool core and non-cool-core clusters, we find that central cooling time, t cool , is the best parameter for low redshift clusters with high quality data, and that cuspiness is the best parameter for high redshift clusters. 72% of clusters in our sample have a cool core (t cool 71 -1/2 Gyr) and 44% have strong cool cores (t cool 71 -1/2 Gyr). We find strong cool-core clusters are characterized as having low central entropy and a systematic central temperature drop. Weak cool-core clusters have enhanced central entropies and temperature profiles that are flat or decrease slightly towards the center. Non-cool-core clusters have high central entropies. For the first time we show quantitatively that the discrepancy in classical and spectroscopic mass deposition rates can not be explained with a recent formation of the cool cores, demonstrating the need for a heating mechanism to explain the cooling flow problem. We find that strong cool-core clusters have a distribution of central temperature drops, centered on 0.4T vir . However, the radius at which the temperature begins to drop varies. This lack of a universal inner temperature profile probably reflects the complex physics in cluster cores not directly related to the cluster as a whole. Our results suggest that the central temperature does not correlate with the mass of the BCGs and weakly correlates with the expected radiative cooling only for strong cool-core clusters. Since 88% of the clusters in our sample have a BCG within a projected distance of 50 h 71 -1 kpc from the X-ray peak, we argue that it is easier to heat the gas (e.g. with mergers or non-gravitational processes) than to separate the dense core from the brightest cluster galaxy. Diffuse, Mpc-scale radio emission, believed to be associated with major mergers, has not been unambiguously detected in any of the strong cool-core clusters in our sample. Of the weak cool-core clusters and non-cool-core clusters, most of the clusters (seven out of eight) that have diffuse, Mpc-scale radio emission have a large (> 50 h 71 -1 kpc) projected separation between their BCG and X-ray peak. In contrast, only two of the 56 clusters with a small separation between the BCG and X-ray peak ( 50 h 71 -1 kpc) show large-scale radio emission. Based on this result, we argue that a large projected separation between the BCG and the X-ray peak is a good indicator of a major merger. The properties of weak cool-core clusters as an intermediate class of objects are discussed. Finally we describe individual properties of all 64 clusters in the sample.

424 citations


Journal ArticleDOI
TL;DR: Gram-scale syntheses of two luminescent silver clusters, protected by small molecules containing thiol groups, with well-defined molecular formulas, by interfacial synthesis are presented, promising in several other areas including semiconductor nanoparticles, two-dimensional superlattices, and 3D structures.
Abstract: Molecular quantum clusters of noble metals are a fascinating area of contemporary interest in nanomaterials. While Au11, [1] Au13, [2] and Au55 [3] have been known for a few decades, several new clusters were discovered recently. These include Au8, [4] Au18, [5] Au25, [6] Au38, [7] and so on. Au11 has also been the subject of recent research. In view of their luminescence, several of these clusters are expected to be important in biolabeling and fluorescence resonance energy transfer as well as for creating luminescent patterns. There are many examples of template-assisted synthesis of water-soluble luminescent silver clusters with cores ranging from Ag2 to Ag8, having characteristic electronic transitions between 400–600 nm. However, unlike the case of gold, there are only limited examples of monolayer-protected silver analogues. Silver clusters protected with aryl, aliphatic, and chiral thiols have been reported, some of which have characteristic optical and mass spectrometric signatures. There is also a family of well-characterized metal-rich silver chalcogenide clusters. Besides single-crystal diffraction, mass spectrometry has also been used for detailed understanding of these clusters. Ag clusters with and without luminescence have also been reported. Herein we present gram-scale syntheses of two luminescent silver clusters, protected by small molecules containing thiol groups, with well-defined molecular formulas, by interfacial synthesis. This new synthetic approach has become promising in several other areas including semiconductor nanoparticles, two-dimensional superlattices, and 3D structures. A crude mixture of redand blue-green-emitting clusters Ag8(H2MSA)8 and Ag7(H2MSA)7 (H2MSA: mercaptosuccinic acid), respectively, was synthesized in gram quantities by an interfacial etching reaction conducted at an aqueous/ organic interface starting from H2MSA-protected silver nanoparticles (Ag@H2MSA) [19] as precursor (for details see the Experimental Section and Figure S1 in the Supporting Information). During the reaction, the optical absorption spectrum of the aqueous phase showed gradual disappearance of the surface plasmon resonance at 400 nm (Figure 1A) of metallic silver nanoparticles. The color of the aqueous phase gradually changed from brown to yellow and finally to orange. The particles of Ag@MSA are polydisperse (Figure 1Ca) and form smaller clusters in the aqueous phase upon etching (Figure 1Cb) with complete disappearance of the nanoparticles. The unetched particles move to the junction of the two phases and form a self-assembled film of monodisperse nanoparticles, resembling two-dimensional superlattices (Figure 1Cc), which appears blue in color. The smaller clusters formed in the reaction upon longer electron-beam irradiation coalesce to form nanoparticles (Figure S2). It is known that such clusters are unstable to high-energy electrons. The peak at 600 nm, which appears at shorter reaction time (60 min) and may be due to interplasmon coupling, disappears slowly, and a new feature is seen at 550 nm after 48 h of reaction (Figure 1A). In accordance with previous studies on silver clusters, we assign this peak to interband Figure 1. A) Time-dependent UV/Vis spectra of the clusters synthesized during interfacial etching at room temperature. B) UV/Vis absorption spectra of the clusters obtained from the two bands in PAGE. The inset shows a photograph of the wet gel after electrophoresis in UV light at room temperature, and the inset to the inset an image of the first band at 273 K. C) HRTEM images of a) assynthesized Ag@(H2MSA), b) the product obtained after interfacial etching, and c) particles in the blue layer at the interface. Individual clusters are not observable by TEM, but aggregates are seen faintly (b, shown in circles). Insets of (a) and (b) are photographs of Ag@MSA and crude cluster samples. d) Photographs of aqueous of cluster solutions of first (cluster 1) and second (cluster 2) PAGE bands at 273 K and room temperature, respectively. D) Luminescence emission of cluster 1 and cluster 2 in water, excited at 550 and 350 nm, respectively.

323 citations


Journal ArticleDOI
TL;DR: The results reveal that the electronic structure of Au(25)(SC(12)H(25))(18) is sensitive to Ag doping and is continuously modulated by incorporation of Ag atoms.

322 citations


Journal ArticleDOI
TL;DR: In this article, the authors derived simultaneous constraints on cosmology and X-ray scaling relations using observations of massive, Xray flux-selected galaxy clusters, and provided a new benchmark for comparison with numerical simulations of cluster formation and evolution.
Abstract: This is the second in a series of papers in which we derive simultaneous constraints on cosmology and X-ray scaling relations using observations of massive, X-ray flux-selected galaxy clusters. The data set consists of 238 clusters with 0.1-2.4keV luminosities >2.5 x 10 44 h -2 70 erg s -1 , and incorporates follow-up observations of 94 of those clusters using the Chandra X-ray Observatory or ROSAT (11 were observed with both). The clusters are drawn from three samples based on the ROSAT All-Sky Survey: the ROSAT Brightest Cluster Sample (78/37 clusters detected/followed-up), the ROSAT-ESO Flux-Limited X-ray sample (126/25) and the bright sub-sample of the Massive Cluster Survey (34/32). Our analysis accounts self-consistently for all selection effects, covariances and systematic uncertainties. Here we describe the reduction of the follow-up X-ray observations, present results on the cluster scaling relations, and discuss their implications. Our constraints on the luminosity-mass and temperature-mass relations, measured within r 500 , lead to three important results. First, the data support the conclusion that excess heating of the intracluster medium (or a combination of heating and condensation of the coldest gas) has altered its thermodynamic state from that expected in a simple, gravitationally dominated system; however, this excess heat is primarily limited to the central regions of clusters (r < 0.15r 500 ). Secondly, the intrinsic scatter in the centre-excised luminosity-mass relation is remarkably small, being bounded at the < 10 per cent level in current data; for the hot, massive clusters under investigation, this scatter is smaller than in either the temperature-mass or Y x -mass relations (10-15 per cent). Thirdly, the evolution with redshift of the scaling relations is consistent with the predictions of simple, self-similar models of gravitational collapse, indicating that the mechanism responsible for heating the central regions of clusters was in operation before redshift 0.5 (the limit of our data) and that its effects on global cluster properties have not evolved strongly since then. Our results provide a new benchmark for comparison with numerical simulations of cluster formation and evolution.

319 citations


Journal ArticleDOI
TL;DR: In this paper, the authors presented the first statistical study based on deep radio data and X-ray observations of a complete sample of galaxy clusters with a complete Xray-selected sample of galaxies and showed that clusters with and without RH can be quantitatively differentiated in terms of their dynamical properties.
Abstract: The frequently observed association between giant radio halos (RHs) and merging galaxy clusters has driven present theoretical models of non-thermal emission from galaxy clusters, which are based on the idea that the energy dissipated during cluster-cluster mergers could power the formation of RHs. To quantitatively test the merger-halo connection, we present the first statistical study based on deep radio data and X-ray observations of a complete X-ray-selected sample of galaxy clusters with X-ray luminosity ≥5 × 1044 erg s–1 and redshift 0.2 ≤ z ≤ 0.32. Using several methods to characterize cluster substructures, namely, the power ratios, centroid shift, and X-ray brightness concentration parameter, we show that clusters with and without RH can be quantitatively differentiated in terms of their dynamical properties. In particular, we confirm that RHs are associated with dynamically disturbed clusters and clusters without RH are more "relaxed," with only a couple of exceptions where a disturbed cluster does not exhibit a halo.

306 citations


Journal ArticleDOI
TL;DR: Experiments on the stability of the cluster showed that Pd(1)@Au(24)(SC(12)H(25))(18) is more stable against degradation in solution and laser dissociation than Au(25)(SC (12) H(25)(18), which indicates that the doping of a central atom is a powerful method to increase the stability beyond the Au( 25)(SR)(18) cluster.
Abstract: A dodecanethiolate-protected Pd1Au24(SC12H25)18 cluster, which is a mono-Pd-doped cluster of the well understood magic gold cluster Au25(SR)18, was isolated in high purity using solvent fractionation and high-performance liquid chromatography (HPLC) after the preparation of dodecanethiolate-protected palladium–gold bimetal clusters. The cluster thus isolated was identified as the neutral [Pd1Au24(SC12H25)18]0 from the retention time in reverse phase columns and by elemental analyses. The LDI mass spectrum of [Pd1Au24(SC12H25)18]0 indicates that [Pd1Au24(SC12H25)18]0 adopts a similar framework structure to Au25(SR)18, in which an icosahedral Au13 core is protected by six [–S–Au–S–Au–S–] oligomers. The optical absorption spectrum of [Pd1Au24(SC12H25)18]0 exhibits peaks at ∼690 and ∼620 nm, which is consistent with calculated results on [Pd1@Au24(SC1H3)18]0 in which the central gold atom of Au25(SC1H3)18 is replaced with Pd. These results strongly indicate that the isolated [Pd1Au24(SC12H25)18]0 has a core–shell [Pd1@Au24(SC12H25)18]0 structure in which the central Pd atom is surrounded by a frame of Au24(SC12H25)18. Experiments on the stability of the cluster showed that Pd1@Au24(SC12H25)18 is more stable against degradation in solution and laser dissociation than Au25(SC12H25)18. These results indicate that the doping of a central atom is a powerful method to increase the stability beyond the Au25(SR)18 cluster.

271 citations


Journal ArticleDOI
TL;DR: In this paper, the authors present comprehensive results on continuous atmospheric cluster and particle measurements in the size range ∼1-42 nm within the European Integrated project on Aerosol Cloud Climate and Air Quality interactions (EUCAARI) project.
Abstract: We present comprehensive results on continuous atmospheric cluster and particle measurements in the size range ∼1-42 nm within the European Integrated project on Aerosol Cloud Climate and Air Quality interactions (EUCAARI) project. We focused on characterizing the spatial and temporal variation of new particle formation events and relevant particle formation parameters across Europe. Different types of air ion and cluster mobility spectrometers were deployed at 12 field sites across Europe from March 2008 to May 2009. The measurements were conducted in a wide variety of environments, including coastal and continental locations as well as sites at different altitudes (both in the boundary layer and the free troposphere). New particle formation events were detected at all of the 12 field sites during the year-long measurement period. From the data, nucleation and growth rates of newly formed particles were determined for each environment. In a case of parallel ion and neutral cluster measurements, we could also estimate the relative contribution of ion-induced and neutral nucleation to the total particle formation. The formation rates of charged particles at 2 nm accounted for 1-30% of the corresponding total particle formation rates. As a significant new result, we found out that the total particle formation rate varied much more between the different sites than the formation rate of charged particles. This work presents, so far, the most comprehensive effort to experimentally characterize nucleation and growth of atmospheric molecular clusters and nanoparticles at ground-based observation sites on a continental scale. © Author(s) 2010.

263 citations


Journal ArticleDOI
TL;DR: An experimental setting is proposed for comparison of different approaches at data generated from Gaussian clusters with the controlled parameters of between- and within-cluster spread to model cluster intermix to evaluate the centroid recovery on par with conventional evaluation of the cluster recovery.
Abstract: The issue of determining “the right number of clusters” in K-Means has attracted considerable interest, especially in the recent years. Cluster intermix appears to be a factor most affecting the clustering results. This paper proposes an experimental setting for comparison of different approaches at data generated from Gaussian clusters with the controlled parameters of between- and within-cluster spread to model cluster intermix. The setting allows for evaluating the centroid recovery on par with conventional evaluation of the cluster recovery. The subjects of our interest are two versions of the “intelligent” K-Means method, ik-Means, that find the “right” number of clusters by extracting “anomalous patterns” from the data one-by-one. We compare them with seven other methods, including Hartigan’s rule, averaged Silhouette width and Gap statistic, under different between- and within-cluster spread-shape conditions. There are several consistent patterns in the results of our experiments, such as that the right K is reproduced best by Hartigan’s rule – but not clusters or their centroids. This leads us to propose an adjusted version of iK-Means, which performs well in the current experiment setting.

262 citations


Journal ArticleDOI
TL;DR: The solid-state route provides nearly pure Ag(9) clusters, and nanoparticle contamination was insignificant for routine studies, and the cluster showed luminescence with a quantum yield of 8 × 10−3 at 5 °C.
Abstract: A silver cluster having the composition Ag9(H2MSA)7 (H2MSA = mercaptosuccinic acid) was synthesized in macroscopic quantities using a solid-state route. The clusters were purified by PAGE and characterized by UV−vis, FTIR, luminescence, and NMR spectroscopy, TEM, XPS, XRD, TG, SEM/EDAX, elemental analysis, and ESI MS. The solid-state route provides nearly pure Ag9 clusters, and nanoparticle contamination was insignificant for routine studies. Formation of various clusters was observed by modifying the conditions. The effect of ligands on the synthesis was checked. The cluster decomposed slowly in water, and the decomposition followed first-order kinetics. However, it could be stabilized in solvent mixtures and in the solid state. Such materials may be important in cluster research because of their characteristic absorption profiles, which are similar to those of Au25 and Au38. The cluster showed luminescence with a quantum yield of 8 × 10−3 at 5 °C.

255 citations


Journal ArticleDOI
TL;DR: In this article, the structural motifs found in manganese coordination clusters are classified using the topological approach for the description of coordination clusters and a means of classifying the structural properties of the motifs.
Abstract: Polynuclear coordination clusters have become of particular interest in recent times as a result of their relevance to bioinorganic chemistry and to the special area of molecule-based magnetic materials where cluster compounds behave as single-molecule magnets (SMMs). In this review we have focused on describing Mn coordination cluster complexes. Adopting our topological approach for the description of coordination clusters we present a means of classifying the structural motifs found in manganese clusters which range in nuclearity from 5 to 84, as well as some representative heterometallic Mn–M (M = K, Na, Ca, Sr, Ln) cluster complexes that have been reported. This sheds new light on the classification of the types of core structure accessible which, in turn, provides a useful means for developing the so-far missing magneto-structural correlation algorithm for these finite 0-D systems (212 references).

Journal ArticleDOI
TL;DR: The distribution of cluster sizes and the optical absorption spectra were markedly different for the two families, suggesting that the Ag:SG clusters are not a simple extension of the Au:SG system, possibly due to differences in Au and Ag chemistry.
Abstract: Magic-number theories, developed to explain the anomalous stability of clusters in the gas phase, are being successfully applied to explain the stability of families of condensed phase Au clusters. To test the generalizability of these theories, we have synthesized a family of magic-numbered Ag clusters. Silver clusters ligated with glutathione (GSH) were synthesized by reduction of silver glutathiolate in water and then separated by polyacrylamide gel electrophoresis (PAGE). The raw synthetic product consisted of a family of discrete Ag:SG clusters, each forming a band in the PAGE gel. Varying reaction conditions changed the relative abundance of the family members but not their positions and colors within the gel, indicating the molecular precision of magic-number clusters. Absorption onsets for the most abundant clusters monotonically decreased with increasing cluster size, and spectra contained a small number of peaks that corresponded to single electron transitions. Although these Ag:SG clusters are related to Au:SG clusters, the distribution of cluster sizes and the optical absorption spectra were markedly different for the two families. This suggests that the Ag:SG clusters are not a simple extension of the Au:SG system, possibly due to differences in Au and Ag chemistry. Alternatively, condensed-phase magic-number cluster theories may need to be more complex than currently believed.

Journal ArticleDOI
TL;DR: This Account surveys the great variety of fullerene-like metal-containing clusters with an emphasis on their synthetic and structural chemistry, and hopes that further study of the bonding interactions and properties of these molecules will lead to the development of new functional materials.
Abstract: The discovery of fullerenes in 1985 opened a new chapter in the chemistry of highly symmetric molecules. Fullerene-like metal clusters, characterized by (multi)shell-like structures, are one rapidly developing class of molecules that share this shape. In addition to creating aesthetically pleasing molecular structures, the ordered arrangement of metal atoms within such frameworks provides the opportunity to develop materials with properties not readily achieved in corresponding mononuclear or lower-nuclearity complexes. In this Account, we survey the great variety of fullerene-like metal-containing clusters with an emphasis on their synthetic and structural chemistry, a first step in the discussion of this fascinating field of cluster chemistry. We group the compounds of interest into three categories based on the atomic composition of the cluster core: those with formal metal−metal bonding, those characterized by ligand participation, and those supported by polyoxometalate building blocks. The number of ...

Journal ArticleDOI
TL;DR: In this paper, the authors used the kinematic Sunyaev-Zel'dovich (SZ) effect produced by the hot gas in moving clusters to estimate large-scale bulk flows of galaxy clusters.
Abstract: We present new measurements of the large-scale bulk flows of galaxy clusters based on five-year WMAP data and a significantly expanded X-ray cluster catalog. Our method probes the flow via measurements of the kinematic Sunyaev-Zel'dovich (SZ) effect produced by the hot gas in moving clusters. It computes the dipole in the cosmic microwave background data at cluster pixels, which preserves the SZ component while integrating down other contributions. Our improved catalog of over 1000 clusters enables us to further investigate possible systematic effects and, thanks to a higher median cluster redshift, allows us to measure the bulk flow to larger scales. We present a corrected error treatment and demonstrate that the more X-ray luminous clusters, while fewer in number, have much larger optical depth, resulting in a higher dipole and thus a more accurate flow measurement. This results in the observed correlation of the dipole derived at the aperture of zero monopole with the monopole measured over the cluster central regions. This correlation is expected if the dipole is produced by the SZ effect and cannot be caused by unidentified systematics (or primary cosmic microwave background anisotropies). We measure that the flow is consistent with approximately constant velocity out to at least [similar, equals]800 Mpc. The significance of the measured signal peaks around 500 h -1 70 Mpc, most likely because the contribution from more distant clusters becomes progressively more diluted by the WMAP beam. However, at present, we cannot rule out that these more distant clusters simply contribute less to the overall motion.

Journal ArticleDOI
TL;DR: In this article, the authors present a statistical analysis of a sample of 20 strong lensing clusters drawn from the Local Cluster Substructure Survey, based on high-resolution Hubble Space Telescope imaging of the cluster cores and follow-up spectroscopic observations using the Keck-I telescope.
Abstract: We present a statistical analysis of a sample of 20 strong lensing clusters drawn from the Local Cluster Substructure Survey, based on high-resolution Hubble Space Telescope imaging of the cluster cores and follow-up spectroscopic observations using the Keck-I telescope. We use detailed parametrized models of the mass distribution in the cluster cores, to measure the total cluster mass and fraction of that mass associated with substructures within R ≤ 250 kpc. These measurements are compared with the distribution of baryons in the cores, as traced by the old stellar populations and the X-ray emitting intracluster medium. Our main results include: (i) the distribution of Einstein radii is lognormal, with a peak and 1σ width of〈log_(10)θ_E(z=2)〉= 1.16 ± 0.28; (ii) we detect an X-ray/lensing mass discrepancy of〈M_(SL)/M_X〉= 1.3 at 3σ significance – clusters with larger substructure fractions displaying greater mass discrepancies, and thus greater departures from hydrostatic equilibrium and (iii) cluster substructure fraction is also correlated with the slope of the gas density profile on small scales, implying a connection between cluster–cluster mergers and gas cooling. Overall our results are consistent with the view that cluster–cluster mergers play a prominent role in shaping the properties of cluster cores, in particular causing departures from hydrostatic equilibrium, and possibly disturbing cool cores. Our results do not support recent claims that large Einstein radius clusters present a challenge to the cold dark matter paradigm.

Journal ArticleDOI
17 Mar 2010-Chaos
TL;DR: In this paper, the authors investigate the relation between cluster synchronization and the unweighted graph topology and propose adaptive feedback algorithms to adapt the weights of the underlying graph, which can synchronize any bi-directed networks satisfying the conditions of common intercluster coupling and intracluster communication.
Abstract: In this paper, we study cluster synchronization in networks of coupled nonidentical dynamical systems. The vertices in the same cluster have the same dynamics of uncoupled node system but the uncoupled node systems in different clusters are different. We present conditions guaranteeing cluster synchronization and investigate the relation between cluster synchronization and the unweighted graph topology. We indicate that two conditions play key roles for cluster synchronization: the common intercluster coupling condition and the intracluster communication. From the latter one, we interpret the two cluster synchronization schemes by whether the edges of communication paths lie in inter- or intracluster. By this way, we classify clusters according to whether the communications between pairs of vertices in the same cluster still hold if the set of edges inter- or intracluster edges is removed. Also, we propose adaptive feedback algorithms to adapting the weights of the underlying graph, which can synchronize any bi-directed networks satisfying the conditions of common intercluster coupling and intracluster communication. We also give several numerical examples to illustrate the theoretical results.

Journal ArticleDOI
TL;DR: This paper proposes a density varied DBSCAN algorithm which is capable to handle local density variation within the cluster and shows that the proposed clustering algorithm gives optimized results.
Abstract: is a base algorithm for density based clustering. It can detect the clusters of different shapes and sizes from the large amount of data which contains noise and outliers. However, it is fail to handle the local density variation that exists within the cluster. In this paper, we propose a density varied DBSCAN algorithm which is capable to handle local density variation within the cluster. It calculates the growing cluster density mean and then the cluster density variance for any core object, which is supposed to be expended further, by considering density of its -neighborhood with respect to cluster density mean. If cluster density variance for a core object is less than or equal to a threshold value and also satisfying the cluster similarity index, then it will allow the core object for expansion. The experimental results show that the proposed clustering algorithm gives optimized results.

Journal ArticleDOI
TL;DR: This work imaged the active sites of iridium catalysts anchored in dealuminated HY zeolite crystals, determined their locations and approximate distance from the crystal surface, and deduced a possible cluster formation mechanism.
Abstract: Zeolites are aluminosilicate materials that contain regular three-dimensional arrays of molecular-scale pores, and they can act as hosts for catalytically active metal clusters. The catalytic properties of such zeolites depend on the sizes and shapes of the clusters, and also on the location of the clusters within the pores. Transmission electron microscopy has been used to image single atoms and nanoclusters on surfaces, but the damage caused by the electron beam has made it difficult to image zeolites. Here, we show that aberration-corrected scanning transmission electron microscopy can be used to determine the locations of individual metal atoms and nanoclusters within the pores of a zeolite. We imaged the active sites of iridium catalysts anchored in dealuminated HY zeolite crystals, determined their locations and approximate distance from the crystal surface, and deduced a possible cluster formation mechanism.

Journal ArticleDOI
TL;DR: In this article, the key factors that govern the growth and distribution of metal on graphene have been studied by scanning tunneling microscopy (STM) based on different behaviors of five transition metals, namely Pt, Rh, Pd, Co, and Au supported on the template of a graphene moire pattern formed on Ru(0001), showing that Pt and Rh form finely dispersed small clusters located at fcc sites on graphene while Pd and Co form large clusters at similar coverages.

Journal ArticleDOI
TL;DR: In this paper, the authors present relations between X-ray luminosity and velocity dispersion (L-sigma) for 62 galaxy clusters in the HIFLUGCS, an Xray flux-limited sample minimizing bias toward any cluster morphology.
Abstract: We present relations between X-ray luminosity and velocity dispersion (L-sigma), X-ray luminosity and gas mass (L-Mgas), and cluster radius and velocity dispersion (r500-sigma) for 62 galaxy clusters in the HIFLUGCS, an X-ray flux-limited sample minimizing bias toward any cluster morphology. Our analysis in total is based on ~1.3Ms of clean X-ray XMM-Newton data and 13439 cluster member galaxies with redshifts. Cool cores are among the major contributors to the scatter in the L-sigma relation. When the cool-core-corrected X-ray luminosity is used the intrinsic scatter decreases to 0.27 dex. Even after the X-ray luminosity is corrected for the cool core, the scatter caused by the presence of cool cores dominates for the low-mass systems. The scatter caused by the non-cool-core clusters does not strongly depend on the mass range, and becomes dominant in the high-mass regime. The observed L-sigma relation agrees with the self-similar prediction, matches that of a simulated sample with AGN feedback disregarding six clusters with <45 cluster members with spectroscopic redshifts, and shows a common trend of increasing scatter toward the low-mass end, i.e., systems with sigma<500km/s. A comparison of observations with simulations indicates an AGN-feedback-driven impact in the low-mass regime. The best fits to the $L-M_{\rm gas}$ relations for the disturbed clusters and undisturbed clusters in the observational sample closely match those of the simulated samples with and without AGN feedback, respectively. This suggests that one main cause of the scatter is AGN activity providing feedback in different phases, e.g., during a feedback cycle. The slope and scatter in the observed r500-sigma relation is similar to that of the simulated sample with AGN feedback except for a small offset but still within the scatter.

Journal ArticleDOI
Stefano Andreon1
TL;DR: In this article, an analysis of 52 clusters with precise and hypothesis-parsimonious measurements of mass, derived from caustics based on about 208 member velocities per cluster on average, shows that low-mass clusters and groups are not simple scaled-down versions of their massive cousins in terms of stellar content: lighter clusters have more stars per unit cluster mass.
Abstract: The analysis of a sample of 52 clusters with precise and hypothesis-parsimonious measurements of mass, derived from caustics based on about 208 member velocities per cluster on average, shows that low-mass clusters and groups are not simple scaled-down versions of their massive cousins in terms of stellar content: lighter clusters have more stars per unit cluster mass. The same analysis also shows that the stellar content of clusters and groups displays an intrinsic spread at a given cluster mass, i.e. clusters are not similar to each other in the amount of stars they contain, not even at a fixed cluster mass. The stellar mass fraction depends on halo mass with (logarithmic) slope −0.55 ± 0.08 and with 0.15 ± 0.02 dex of intrinsic scatter at a fixed cluster mass. These results are confirmed by adopting masses derived from velocity dispersion. The intrinsic scatter at a fixed cluster mass we determine for gas mass fractions taken from literature is smaller, 0.06 ± 0.01 dex. The intrinsic scatter in both the stellar and gas mass fractions is a distinctive signature that individual regions from which clusters and groups collected matter, a few tens of Mpc wide, are not yet representative of the mean gas and baryon content of the Universe. The observed stellar mass fraction values are in marked disagreement with gasdynamics simulations with cooling and star formation of clusters and groups. Instead, the amplitude and cluster mass dependency of observed stellar mass fractions are those required not to need any active galactic nuclei (AGN) feedback to describe gas and stellar mass fractions and X-ray scale relations in simple semi-analytic cluster models. By adding stellar and gas masses and accounting for the intrinsic variance of both quantities, we found that the baryon fraction is fairly constant for clusters and groups with masses between

Journal ArticleDOI
TL;DR: In this paper, the centers of 65 Milky Way globular clusters were determined by fitting ellipses to the density distribution within the inner 2' of the cluster center, and averaging the centers.
Abstract: We present new measurements of the centers for 65 Milky Way globular clusters. Centers were determined by fitting ellipses to the density distribution within the inner 2' of the cluster center, and averaging the centers of these ellipses. The symmetry of clusters was also analyzed by comparing cumulative radial distributions on opposite sides of the cluster across a grid of trial centers. All of the determinations were done with stellar positions derived from a combination of two single-orbit Advanced Camera for Surveys images of the core of the cluster in F606W and F814W. We find that the ellipse-fitting method provides remarkable accuracy over a wide range of core sizes and density distributions, while the symmetry method is difficult to use on clusters with very large cores or low density. The symmetry method requires a larger field or a very sharply peaked density distribution.

Journal ArticleDOI
TL;DR: A graph-based method is presented that can approximate the cluster tree of any density estimate and proposes excess mass as a measure for the size of a branch, reflecting the height of the corresponding peak of the density above the surrounding valley floor as well as its spatial extent.
Abstract: The goal of clustering is to detect the presence of distinct groups in a dataset and assign group labels to the observations. Nonparametric clustering is based on the premise that the observations may be regarded as a sample from some underlying density in feature space and that groups correspond to modes of this density. The goal then is to find the modes and assign each observation to the domain of attraction of a mode. The modal structure of a density is summarized by its cluster tree; modes of the density correspond to leaves of the cluster tree. Estimating the cluster tree is the primary goal of nonparametric cluster analysis. We adopt a plug-in approach to cluster tree estimation: estimate the cluster tree of the feature density by the cluster tree of a density estimate. For some density estimates the cluster tree can be computed exactly; for others we have to be content with an approximation. We present a graph-based method that can approximate the cluster tree of any density estimate. Density esti...

Journal ArticleDOI
TL;DR: In this paper, the substructure statistics of a representative sample of galaxy clusters by means of two currently popular substructure characterisation methods, power ratios and centroid shifts, were studied.
Abstract: We study the substructure statistics of a representative sample of galaxy clusters by means of two currently popular substructure characterisation methods, power ratios and centroid shifts. We use the 31 clusters from the REXCESS sample, compiled from the southern ROSAT All-Sky cluster survey (REFLEX) with a morphologically unbiased selection in X-ray luminosity and redshift, all of which have been reobserved with XMM-Newton. The main goals of this work are to study the relationship between cluster morphology and other bulk properties, and the comparison of the morphology statistics between observations and numerical simulations. We investigate the uncertainties of the substructure parameters via newly-developed Monte Carlo methods, and examine the dependence of the results on projection effects (via the viewing angle of simulated clusters), finding that the uncertainties of the parameters can be quite substantial. Thus while the quantification of the dynamical state of individual clusters with these parameters should be treated with extreme caution, these substructure measures provide powerful statistical tools to characterise trends of properties in large cluster samples. The centre shift parameter, w, is found to be more sensitive in general and offers a larger dynamic range than the power ratios. For the REXCESS sample neither the occurence of substructure nor the presence of cool cores depends on cluster mass; however a weak correlation with X-ray luminosity is present, which is interpreted as selection effect. There is a significant anti-correlation between the existence of substantial substructure and cool cores. The simulated clusters show on average larger substructure parameters than the observed clusters, a trend that is traced to the fact that cool regions are more pronounced in the simulated clusters, leading to stronger substructure measures in merging clusters and clusters with offset cores. Moreover, the frequency of cool regions is higher in the simulations than in the observations, implying that the description of the physical processes shaping cluster formation in the simulations requires further improvement.

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TL;DR: This work shows that considering only the largest cluster suffices to obtain a first-order percolation transition, and discovers that the cluster perimeters are fractal at the transition point, yielding a fractal dimension close to that of watersheds.
Abstract: We show that considering only the largest cluster suffices to obtain a first-order percolation transition. As opposed to previous realizations of explosive percolation, our models obtain Gaussian cluster distributions and compact clusters as one would expect at first-order transitions. We also discover that the cluster perimeters are fractal at the transition point, yielding a fractal dimension of 1.23 ± 0.03, close to that of watersheds.

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TL;DR: In this paper, an atomic picture of highly dispersed palladium and platinum catalysts supported on gamma-alumina is provided, where the interaction energies and the structures of Pd13 and Pt13 clusters are systematically investigated by density functional theory calculations.

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TL;DR: In this paper, the effect of gold atoms in the form of both pointlike charged impurities and clusters on the transport properties of graphene was investigated and it was shown that for a fixed amount of Au impurities, the formation of clusters enhances the mobility and causes the Dirac point to shift back toward zero.
Abstract: We investigate the effect of gold (Au) atoms in the form of both pointlike charged impurities and clusters on the transport properties of graphene. Cryogenic deposition (18 K) of Au decreases the mobility and shifts the Dirac point in a manner that is consistent with scattering from pointlike charged impurities. Increasing the temperature to room temperature promotes the formation of clusters, which is verified with atomic force microscopy. We find that for a fixed amount of Au impurities, the formation of clusters enhances the mobility and causes the Dirac point to shift back toward zero.

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TL;DR: In this article, high-speed video imaging of particle clusters in and above a fluidized bed suggests that clustering is significant for FCC catalyst and polyethylene powders, and the dominant mechanism for clusters in the freeboard appears to be cluster formation in the bed.

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TL;DR: In this article, the authors used a comprehensive set of N-body computations of star clusters on various orbits within a realistic tidal field to study the evolution of these profiles with time, and ongoing cluster dissolution.
Abstract: Based on our recent work on tidal tails of star clusters we investigate star clusters of a few 104 M(circle dot) by means of velocity dispersion profiles and surface density profiles. We use a comprehensive set of N-body computations of star clusters on various orbits within a realistic tidal field to study the evolution of these profiles with time, and ongoing cluster dissolution. From the velocity dispersion profiles we find that the population of potential escapers, i.e. energetically unbound stars inside the Jacobi radius, dominates clusters at radii above about 50 per cent of the Jacobi radius. Beyond 70 per cent of the Jacobi radius nearly all stars are energetically unbound. The velocity dispersion therefore significantly deviates from the predictions of simple equilibrium models in this regime. We furthermore argue that for this reason this part of a cluster cannot be used to detect a dark matter halo or deviations from the Newtonian gravity. By fitting templates to about 104 computed surface density profiles we estimate the accuracy which can be achieved in reconstructing the Jacobi radius of a cluster in this way. We find that the template of King works well for extended clusters on nearly circular orbits, but shows significant flaws in the case of eccentric cluster orbits. This we fix by extending this template with three more free parameters. Our template can reconstruct the tidal radius over all fitted ranges with an accuracy of about 10 per cent, and is especially useful in the case of cluster data with a wide radial coverage and for clusters showing significant extra-tidal stellar populations. No other template that we have tried can yield comparable results over this range of cluster conditions. All templates fail to reconstruct tidal parameters of concentrated clusters, however. Moreover, we find that the bulk of a cluster adjusts to the mean tidal field which it experiences and not to the tidal field at perigalacticon as has often been assumed in other investigations, i.e. a fitted tidal radius is a cluster's time average mean tidal radius and not its perigalactic one. Furthermore, we study the tidal debris in the vicinity of the clusters and find it to be well represented by a power law with a slope of -4 to -5. This steep slope we ascribe to the epicyclic motion of escaped stars in the tidal tails. Star clusters close to apogalacticon show a significantly shallower slope of up to -1, however. We suggest that clusters at apogalacticon can be identified by measuring this slope.

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TL;DR: In this article, the authors used a Bayesian approach to estimate the age-mass-extinction distribution of star clusters in the universe. But their work was restricted to the solar metallicity.
Abstract: Star clusters are studied widely both as benchmarks for stellar evolution models and in their own right. Cluster age and mass distributions within galaxies are probes of star formation histories, and of cluster formation and disruption processes. The vast majority of clusters in the Universe is small, and it is well known that the integrated fluxes and colors have broad probability distributions, due to small numbers of bright stars. This paper goes beyond the description of predicted probability distributions, and presents results of the analysis of cluster energy distributions in an explicitly stochastic context. The method developed is Bayesian. It provides posterior probability distributions in the age-mass-extinction space, using multi-wavelength photometric observations and a large collection of Monte-Carlo simulations of clusters of finite stellar masses. Both UBVI and UBVIK datasets are considered, and the study conducted in this paper is restricted to the solar metallicity. We first reassess and explain errors arising from the use of standard analysis methods, which are based on continuous population synthesis models: systematic errors on ages and random errors on masses are large, while systematic errors on masses tend to be smaller. The age-mass distributions obtained after analysis of a synthetic sample are very similar to those found for real galaxies in the literature. The Bayesian approach on the other hand, is very successful in recovering the input ages and masses. Taking stochastic effects into account is important, more important for instance than the choice of adding or removing near-IR data in many cases. We found no immediately obvious reason to reject priors inspired by previous (standard) analyses of cluster populations in galaxies, i.e. cluster distributions that scale with mass as M^-2 and are uniform on a logarithmic age scale.