Showing papers on "Compounds of zinc published in 1959"
TL;DR: A few complex compounds of zinc and cadmium fluoberyllates with organic base were prepared by the addition of a concentrated solution of ethylenediamine to the concentrated solutions of metal fluoberlyates.
Abstract: A few complex compounds of zinc and cadmium fluoberyllates with organic base were prepared. [Zn en3]BeF4 and [Cd en3]BeF4 were prepared by the addition of a concentrated solution of ethylenediamine to the concentrated solution of metal fluoberyllates. [Zn pn3]BeF4 was also isolated. The corresponding cadmium compound, however could not be prepared. ZnBeF4, C6H12N4, 8 H2O and CdBeF4, C6H12N4, 8 H2O were also prepared by following similar methods. In chemical compositions and also in their chemical properties these compounds resembles the corresponding sulphate compounds.
Durch Umsatz von Athylendiamin, Propylendiamin und Hexamethylentetramin mit Zink- bzw. Cadmium-Fluoroberyllat konnten die komplexen Fluoberyllate mit diesen organischen Basen als Liganden dargestellt werden. Die Eigenschaften dieser Verbindungen sind denen der entsprechenden komplexen Sulfate ahnlich.
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