Conductance

About: Conductance is a research topic. Over the lifetime, 8088 publications have been published within this topic receiving 235961 citations.

Electrochemical Origin of Voltage-Controlled Molecular Conductance Switching

Abstract: We have studied electron transport in bipyridyl-dinitro oligophenylene-ethynelene dithiol (BPDN) molecules both in an inert environment and in aqueous electrolyte under potential control, using scanning tunneling microscopy. Current-voltage (IV) data obtained in an inert environment were similar to previously reported results showing conductance switching near 1.6 V. Similar measurements taken in electrolyte under potential control showed a linear dependence of the bias for switching on the electrochemical potential. Extrapolation of the potentials to zero switching bias coincided with the potentials of redox processes on these molecules. Thus switching is caused by a change in the oxidation state of the molecules.

Gate-controlled conductance switching in DNA.

Abstract: Extensive evidence has shown that long-range charge transport can occur along double helical DNA, but active control (switching) of single-DNA conductance with an external field has not yet been demonstrated. Here we demonstrate conductance switching in DNA by replacing a DNA base with a redox group. By applying an electrochemical (EC) gate voltage to the molecule, we switch the redox group between the oxidized and reduced states, leading to reversible switching of the DNA conductance between two discrete levels. We further show that monitoring the individual conductance switching allows the study of redox reaction kinetics and thermodynamics at single molecular level using DNA as a probe. Our theoretical calculations suggest that the switch is due to the change in the energy level alignment of the redox states relative to the Fermi level of the electrodes.

Do Molecular Conductances Correlate with Electrochemical Rate Constants? Experimental Insights

Abstract: We measured single-molecule conductances for three different redox systems self-assembled onto gold by the STMBJ method and compared them with electrochemical heterogeneous rate constants determined by ultrafast voltammetry It was observed that fast systems indeed give higher conductance Monotonous dependency of conductance on potential reveals that large molecular fluctuations prevent the molecular redox levels to lie in between the Fermi levels of the electrodes in the nanogap configuration Electronic coupling factors for both experimental approaches were therefore evaluated based on the superexchange mechanism theory The results suggest that coupling is surprisingly on the same order of magnitude or even larger in conductance measurements whereas electron transfer occurs on larger distances than in transient electrochemistry

Theoretical study of transport through a quantum point contact

Abstract: We developed a formalism within the linear-response theory to investigate the transport through a quantum point contact between two electron-gas reservoirs. It is valid for two-terminal conductance through a constriction of a two-dimensional (2D) or 3D potential and has a wide range of applicability covering ballistic as well as tunneling regimes. We studied the quantization of conductance and examined several effects influencing the quantum transmission. Among these effects we found that the simple phase relation results in resonance structures superimposed on the plateaus between two steps of quantized conductance. These resonances are destroyed by the smooth entrance, finite temperature and bias, and variation of the potential. The simulation of adiabatic transmission in constrictions having smoothly varying widths resulted in the conductance with sharp quantum steps without the resonance structure. The quality of quantization is strongly affected by the length of constriction, Fermi-level smearing, the obstacle at the entrance, impurity scattering, nonuniformities of geometry and potential, and in particular by the variation of the longitudinal potential resulting in a sharp saddle-point structure.

Charge transport in conjugated aromatic molecular junctions : Molecular conjugation and molecule-electrode coupling

Abstract: The conductance of a single molecule transport junction is investigated in the Landauer-Imry regime of coherent tunneling transport. Utilizing aromatic systems with thiol end groups, we have calculated using density functional theory the expected conductance of junctions containing molecules with different levels of conjugation and of different lengths. The calculated variations in transport junction conductance are explained in terms of the continuity of the conjugation path between leads. Molecular conjugation describes this continuity within the molecule, and the interfacial terms (spectral densities or imaginary parts of the self-energy) describe its continuity at the molecule/metal interface. We compare the results from junction conductance calculations with isolated molecule electronic structure calculations These density functional theory calculations suggest that for these dithiol molecules, transport occurs mostly through the occupied orbital manifold. The decay of the transport with length is fo...