Topic
Coordination polymer
About: Coordination polymer is a research topic. Over the lifetime, 11988 publications have been published within this topic receiving 212219 citations.
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TL;DR: In this article, two new coordination polymers formulated as [Ni(ip)(4,4′-bipy)] (1 ) and [Cd(ip), 4, 4′-Bipy]H 2 O (2 ) have been hydrothermally prepared and structurally characterized.
72 citations
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TL;DR: The magnetic studies and heat capacity measurements reveal that the two-dimensional Gd(III)-based coordination polymer of 2 has the higher magnetic density and exhibits a larger cryogenic magnetocaloric effect (MCE) than previously reported.
Abstract: Two new oxalate-bridged Gd(III) coordination polymers, namely, (choline)[Gd(C2O4)(H2O)3Cl]Cl·H2O (1) and [Gd(C2O4)(H2O)3Cl] (2), were first obtained ionothermally by using a deep eutectic solvent (DES). The magnetic studies and heat capacity measurements reveal that the two-dimensional Gd(III)-based coordination polymer of 2 has the higher magnetic density and exhibits a larger cryogenic magnetocaloric effect (MCE) (ΔSm = 48 J kg–1 K–1 for ΔH = 7 T at 2.2 K).
72 citations
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TL;DR: In this paper, the authors reported the preparation and electrocatalytic performance of silver-containing gas diffusion electrodes (GDEs) derived from a silver coordination polymer (Ag-CP).
Abstract: We report the preparation and electrocatalytic performance of silver-containing gas diffusion electrodes (GDEs) derived from a silver coordination polymer (Ag-CP). Layer-by-layer growth of the Ag-C...
72 citations
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TL;DR: Two homochiral coordination polymers [Mn2(D-cam)2(2-Hpao)4]n (1) and [Co2D-Cam]2(3-abpt) 2(H2O)3]n·5n H2O (2) were prepared with D-(+)-camphoric acid, and 1-D complex 1 featured good temperature-independent piezoelectric properties as mentioned in this paper.
Abstract: Two homochiral coordination polymers [Mn2(D-cam)2(2-Hpao)4]n (1) and [Co2(D-cam)2(3-abpt)2(H2O)3]n·5nH2O (2) were prepared with D-(+)-camphoric acid, and 1-D complex 1 featured good temperature-independent piezoelectric (6.9 pC N−1) and dielectric properties.
72 citations
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TL;DR: Two isostructural 1D compounds were synthesized by the in situ hydrothermal reactions of 2-chloropyrimidine-4,6-dicarboxylic acid with MCl2 and NaOH; the MnII compound shows spin-canted antiferromagnetism, whereas the CoII compound exhibits the coexistence of spin- canting and a two-step field-induced magnetic phase transition.
72 citations