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Coordination polymer
About: Coordination polymer is a research topic. Over the lifetime, 11988 publications have been published within this topic receiving 212219 citations.
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TL;DR: A novel uranyl-organic compound incorporating citrate linker exhibits a 3D open-framework built up from the connection of infinite chains of uranylcentered polyhedra with citrate ligands, generating layers, which are further linked perpendicularly by isolated uranium tetranuclear motifs, involving uranyl cation-cation interactions.
Abstract: A novel uranyl-organic compound incorporating citrate linker exhibits a 3D open-framework. It is built up from the connection of infinite chains of uranyl-centered polyhedra with citrate ligands, generating layers, which are further linked perpendicularly by isolated uranium tetranuclear motifs, involving uranyl cation-cation interactions.
54 citations
TL;DR: In this article, the hexagonal (6,3) network of the graphene sheet derived by tridentate coordination of 1,3,5-benzenetricarboxylate to octahedral NiII centers is reported.
54 citations
TL;DR: Nano-structures of two new lead(II) two-dimensional coordination polymers, [Pb(2)(2-pyc)(2)(I)(2)](n) (1), {2-Hpyc=2-pyridinecarboxilic acid } were synthesized by a sonochemical method that produce the coordination polymer at nano-size.
54 citations
TL;DR: The three-dimensional coordination polymer [Cd 2 (4,4′-bipy) 2 (H 2 O) 3 (SO 4 ) 2 ]·3 H 2 O (1 ) was synthesized by the hydrothermal reaction of 4, 4′-Bipyridine with CdSO 4 ·8/3H 2O in 1:1 mole ratio in a sealed tube at 120°C as discussed by the authors.
54 citations
TL;DR: In this paper, three supramolecular complexes of Co(II) using SCN/SeCN- in combination with 4,4'dipyridyl-N,N'dioxide (dpyo) have been synthesized and characterized by single-crystal X-ray analysis.
Abstract: Three supramolecular complexes of Co(II) using SCN-/SeCN- in combination with 4,4‘-dipyridyl-N,N‘-dioxide (dpyo), i.e., {[Co(SCN)2(dpyo)2]·(dpyo)}n (1), {[Co(SCN)2(dpyo)(H2O)2]·(H2O)}n (2), {[Co(SeCN)2(dpyo)(H2O)2]·(H2O)}n (3), have been synthesized and characterized by single-crystal X-ray analysis. Complex 1 is a rare example of a dpyo bridged two-dimensional (2D) coordination polymer, and π-stacked dpyo supramolecular rods are generated by the lattice dpyo, passing through the rhombic grid of stacked layers, resulting in a three-dimensional (3D) superstructure. Complexes 2 and 3 are isomorphous one-dimensional (1D) coordination polymers [-Co-dpyo-Co-] that undergo self-assembly leading to a bilayer architecture derived through an (8) H-bonding synthon between coordinated water and dpyo oxygen. A reinvestigation of coordination polymers [Mn(SCN)2(dpyo)(H2O)(MeOH)]n (4) and {[Fe(SCN)2(dpyo)(H2O)2]·(H2O)}n (5) reported recently by our group [Manna et al. Indian J. Chem. 2006, 45A, 1813] reveals brick wall...
54 citations