Topic
Coordination polymer
About: Coordination polymer is a research topic. Over the lifetime, 11988 publications have been published within this topic receiving 212219 citations.
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TL;DR: The first terephthalato bis-tridentate bridging cadmium coordination polymer, [(TPT)(py)Cd] 1, with blue fluorescent emission, was synthesized by a hydrothermal reaction between Cd(ClO4)2· 6H2O, 1,4-dicyanobenzene and pyridine (py) as discussed by the authors.
Abstract: The first terephthalato (TPT) bis-tridentate bridging cadmium coordination polymer, [(TPT)(py)Cd] 1, with blue fluorescent emission, was synthesized by a hydrothermal reaction between Cd(ClO4)2· 6H2O, 1,4-dicyanobenzene and pyridine (py).
129 citations
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129 citations
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TL;DR: Two isostructural vanadium(IV) coordination polymers [VO(dod)2]X2 [X=Cl, Br; dod=1,4-diazoniabicyclo[2,2-2] octane-1, 4-diacetate (C10H16N2O4)] have been synthesized solvothermally and determined by single-crystal X-ray analysis as discussed by the authors.
129 citations
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128 citations
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TL;DR: In this paper, a novel coordination compound, {[Cd(BDC)(Bpybc)(1.5)].10H(2)O}(n), was obtained by the reaction of CdCl(2), with 1,1'-bis(4-carboxybenzyl)-4,4'-bipyridinium dichloride (H (2)BpyBCCl (2)) and 1,4-benzenedicarboxylic acid (H( 2)BDC), which contains 1D polymeric chains
Abstract: A novel coordination compound, {[Cd(BDC)(Bpybc)(1.5)].10H(2)O}(n), obtained by the reaction of CdCl(2) with 1,1'-bis(4-carboxybenzyl)-4,4'-bipyridinium dichloride (H(2)BpybcCl(2)) and 1,4-benzenedicarboxylic acid (H(2)BDC), contains 1D polymeric chains that are comprised of alternating rings and rods and dangling lateral arms. These 1D polymeric motifs are interlaced via rotaxane-like mechanical linkages to give 2D armed-polyrotaxane sheets, which are further mutually polythreaded via pseudorotaxane-like mechanical linkages to form a 3D polypseudorotaxane array. Notably, a sandwich-type donor-acceptor-donor stacking is formed within each ring as a consequence of both types of polythreading in this species, and photoinduced and thermal-induced reduction of bipyridinium occurs with a color change from light yellow to blue.
127 citations