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Coordination polymer
About: Coordination polymer is a research topic. Over the lifetime, 11988 publications have been published within this topic receiving 212219 citations.
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TL;DR: IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3 and is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.
Abstract: A metal−organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal−organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.
124 citations
TL;DR: CuSCN reacts with the angular ligand 2,4-bis(4-pyridyl)-1,3,5-triazine (dpt) to afford rare examples of coordination polymer structural isomers including a non-centrosymmetric three-dimensional framework with Cd(SO4) topology constructed from tetrahedral metal cations.
124 citations
124 citations
TL;DR: In this paper, a semi-solid-state battery-supercapacitor-hybrid (sss-BSH) device with two Fe-based metal-organic framework and one one-dimensional coordination polymer was proposed.
Abstract: One two-dimensional Fe-based metal-organic framework (FeSC1) and one one-dimensional coordination polymer (FeSC2) have been solvothermally prepared through the reaction among FeSO4·7H2O, the tripodal ligand 4,4',4″-s-triazine-2,4,6-triyl-tribenzoate (H3TATB), and flexible secondary building blocks p/m-bis((1H-imidazole-1-yl)methyl)benzene (bib). Given that their abundant interlayer spaces and different coordination modes, two compounds have been employed as battery-type electrodes to understand how void space and different coordination modes affect their performances in three-electrode electrochemical systems. Both materials exhibit outstanding but different electrochemical performances (including distinct capacities and charge-transfer abilities) under three-electrode configurations, where the charge storage for each electrode material is mainly dominated by the diffusion-controlled section (i ∝ v0.5) through power-law equations. Additionally, the partial phase transformations to more stable FeOOH are also detected in the long-term cycling loops. After coupling with the capacitive carbon-based electrode to assemble into the semi-solid-state battery-supercapacitor-hybrid (sss-BSH) devices, the sss-FeSC1//AC BSH device delivers excellent capacitance, superior energy and power density, and longstanding endurance as well as the potential practical property.
124 citations
TL;DR: This method was successfully applied to determine the levels of Tc in milk, which is the first application of coordination polymer as a fluorescent sensor in real sample and could be extended to the preparation of other lanthanide coordination polymer-based fluorescent probes for applications in biosensing, imaging, drug delivery, and so on.
124 citations