Topic
Coordination polymer
About: Coordination polymer is a research topic. Over the lifetime, 11988 publications have been published within this topic receiving 212219 citations.
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TL;DR: A new channel-containing 1D coordination polymer has been prepared by the combination of a linear dimetallic spacer, Cu2(O2CMe)4, and a linear didentate ligand, 1,3-di-4-pyridylpropane; the new material includes methanol, acetic acid and diethylene glycol.
102 citations
TL;DR: The glassy state of a two-dimensional (2D) Cd(2+) coordination polymer crystal was prepared by a solvent-free mechanical milling process and displays superior properties compared to the crystalline state; specifically, it shows anhydrous proton conductivity and a dielectric constant two orders of magnitude greater than the crystallines material.
Abstract: The glassy state of a two-dimensional (2D) Cd(2+) coordination polymer crystal was prepared by a solvent-free mechanical milling process. The glassy state retains the 2D structure of the crystalline material, albeit with significant distortion, as characterized by synchrotron X-ray analyses and solid-state multinuclear NMR spectroscopy. It transforms to its original crystal structure upon heating. Thus, reversible crystal-to-glass transformation is possible using our new processes. The glass state displays superior properties compared to the crystalline state; specifically, it shows anhydrous proton conductivity and a dielectric constant two orders of magnitude greater than the crystalline material. It also shows material flexibility and transparency.
102 citations
TL;DR: A copper(i)/copper(ii)-salen coordination polymer prepared by solvothermal reactions shows prominent bimetallic catalytic activities towards three-component Strecker reactions and photodegradation of organic dyes under visible-light illumination.
102 citations
TL;DR: Instant adsorption of Congo Red by a 1D coordination polymer leads to the formation of a unique dye composite 1·0.75CR·6H2O, which demonstrates a remarkably enhanced photocurrent response compared to that of its precursor.
102 citations