Topic
Coprecipitation
About: Coprecipitation is a research topic. Over the lifetime, 8101 publications have been published within this topic receiving 186355 citations.
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TL;DR: In this paper, gold catalysts were prepared by coprecipitation from an aqueous solution of HAuCl4 and the nitrates of various transition metals, including Auα-Fe2O3, AuCo3O4, and AuNiO.
2,917 citations
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TL;DR: In this article, a variety of gold catalysts are used to catalyze the oxidation of carbon monoxide at temperatures as low as −70 °C and are stable in a moistened gas atmosphere.
Abstract: A variety of gold catalysts can be used to catalyze the oxidation of carbon monoxide at temperatures as low as −70 °C and are stable in a moistened gas atmosphere. The novel catalysts, prepared by coprecipitation, are composed of ultra-fine gold particles and one of the oxides of 3d transition metals of group VIII, namely, Fe, Co, and Ni.
2,753 citations
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TL;DR: In this paper, the effects of Ni content on the electrochemical properties and the structural and thermal stabilities of Li[Ni x Co y Mn z ]O 2 ( x ǫ = 1/3, 0.6, 07, 08 and 0.85) synthesized via a coprecipitation method were reported.
1,524 citations
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TL;DR: In this paper, ultrathin nanoplates of cobalt-manganese layered double hydroxide (CoMn LDH) are a highly active and stable oxygen evolution catalyst.
Abstract: Cost-effective production of solar fuels requires robust and earth-abundant oxygen evolution reaction (OER) catalysts. Herein, we report that ultrathin nanoplates of cobalt–manganese layered double hydroxide (CoMn LDH) are a highly active and stable oxygen evolution catalyst. The catalyst was fabricated by a one-pot coprecipitation method at room temperature, and its turnover frequency (TOF) is more than 20 times higher than the TOFs of Co and Mn oxides and hydroxides, and 9 times higher than the TOF of a precious IrO2 catalyst. The activity of the catalyst was promoted by anodic conditioning, which was proposed to form amorphous regions and reactive Co(IV) species on the surface. The stability of the catalyst was demonstrated by continued electrolysis.
1,010 citations
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TL;DR: In this paper, the α-MnO2 powder was synthesized by a simple coprecipitation technique and tested as active electrode material for an electrochemical supercapacitor, showing that an average capacitance of 166 F/g can be reproducibly obtained within a voltage range −0.4/+0.5 V vs Hg/Hg2SO4 using a sweep rate of 2 mV/s.
Abstract: α-MnO2 was synthesized by a very simple coprecipitation technique and tested as active electrode material for an electrochemical supercapacitor. The powder presents a poorly crystallized cryptomelane phase with a chemical composition of K0.05MnO2H0.10·0.15H2O. Different aqueous electrolytes were tested including 0.1 M Na2SO4, 0.5 M K2HPO4/KH2PO4 buffer solution, 0.3 M H2SO4, and 1 M NaOH, but interesting pseudocapacitance behavior was only observed in the case of 0.1 M Na2SO4. Further testing using this electrolyte showed that an average capacitance of 166 F/g can be reproducibly obtained within a voltage range −0.4/+0.5 V vs Hg/Hg2SO4 using a sweep rate of 2 mV/s. This interesting value is mainly due to the chimisorption of Na+ ions and/or protons at the surface of the α-MnO2 electrode. Nearly all the Mn surface atoms are involved in the pseudocapacitive process. Therefore, the high specific capacitance seems to be related to the high surface area of the MnO2 powder rather than intercalation of Na+ ions ...
912 citations