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Correlation function (statistical mechanics)

About: Correlation function (statistical mechanics) is a(n) research topic. Over the lifetime, 6670 publication(s) have been published within this topic receiving 162143 citation(s).

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Abstract: The individual spins of the Ising model are assumed to interact with an external agency (e.g., a heat reservoir) which causes them to change their states randomly with time. Coupling between the spins is introduced through the assumption that the transition probabilities for any one spin depend on the values of the neighboring spins. This dependence is determined, in part, by the detailed balancing condition obeyed by the equilibrium state of the model. The Markoff process which describes the spin functions is analyzed in detail for the case of a closed N‐member chain. The expectation values of the individual spins and of the products of pairs of spins, each of the pair evaluated at a different time, are found explicitly. The influence of a uniform, time‐varying magnetic field upon the model is discussed, and the frequency‐dependent magnetic susceptibility is found in the weak‐field limit. Some fluctuation‐dissipation theorems are derived which relate the susceptibility to the Fourier transform of the time‐dependent correlation function of the magnetization at equilibrium.

2,708 citations

Journal ArticleDOI
Abstract: The first order electric field correlation function of laser light scattered by polydisperse solutions of macromolecules can be written as a sum or distribution of exponentials, with decay rates proportional to the diffusion coefficients of the solute molecules. It is shown that the logarithm of this correlation function is formally equivalent to a cumulant generating function. A method is described by which the distribution function of the decay rates (and thus the extent of polydispersity) can be characterized, in a light scattering experiment, by calculation of the moments or cumulants. The systematic and random statistical errors in the calculated cumulants are discussed.

2,539 citations

Journal ArticleDOI
Abstract: The three-dimensional classical many-body system is approximated by the use of collective coordinates, through the assumed knowledge of two-body correlation functions. The resulting approximate statistical state is used to obtain the two-body correlation function. Thus, a self-consistent formulation is available for determining the correlation function. Then, the self-consistent integral equation is solved in virial expansion, and the thermodynamic quantities of the system thereby ascertained. The first three virial coefficients are exactly reproduced, while the fourth is nearly correct, as evidenced by numerical results for the case of hard spheres.

2,240 citations

Journal ArticleDOI
Abstract: A general treatment of the scattering of radiation by an inhomogeneous material is developed. It is shown how scattering measurements can be used to obtain the average square of the fluctuations in refractive index or electron density and a correlation function which measures the degree of correlation between two fluctuations as a function of their distance of separation.The scattering of visible light by Lucite and two glass samples has been investigated. The data are analyzed in terms of the quantities mentioned above. It is found that the extensions in space of the inhomogeneities in the Lucite sample are much greater than those in the optical glass samples investigated. The magnitudes of the fluctuations in refractive index are found to be dependent on the composition of the sample.

1,316 citations

Journal ArticleDOI
Abstract: Based on the conformal algebra approach, a general technique is given for the calculation of multipoint correlation functions in 2D statistical models at the critical point. Particular conformal operator algebras are found for operators of the 2D q-component Potts model (1

1,277 citations

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